STEREOLITHOGRAPHIC METHOD AND COMPOSITION
    8.
    发明公开
    STEREOLITHOGRAPHIC METHOD AND COMPOSITION 审中-公开
    立体成像方法及组合

    公开(公告)号:EP3215353A1

    公开(公告)日:2017-09-13

    申请号:EP15805279.5

    申请日:2015-10-30

    Applicant: DWS S.R.L.

    Abstract: The invention concerns a method for producing a three-dimensional object, in particular an artificial tooth, by stereolithography wherein a liquid photocurable resin composition is cured by light. Said photocurable resin composition contains, based on the total weight of the photocurable resin composition, (i) from 90 to 99.9% by weight of a radical polymerizable organic compound (A) selected from radical polymerizable monomers, oligomers, pre-polymers and mixtures thereof; and (ii) from 0.1 to 10% by weight of a photosensitive radical polymerization initiator (B). Said radical polymerizable organic compound (A) comprises, based on the weight of the radical polymerizable organic compound (A), from 0.5 to 20% by weight of a polyrotaxane compound comprising a polymer chain selected from polyethylene glycol (PEG), polypropylene glycol (PPG), polyethylene glycol - polypropylene glycol (PEG- PPG) block copolymer or polydimethylsiloxane (PDMS), onto which the cyclodextrin ring(s) is/are slipped and wherein the cyclodextrin is derivatized with at least a radical polymerizable group. The invention also concerns a relative liquid photocurable resin composition and articles produced thereby.

    Abstract translation: 本发明涉及一种通过立体光刻制造三维物体,特别是人造牙齿的方法,其中液体光固化树脂组合物通过光固化。 基于光固化树脂组合物的总重量,所述光固化树脂组合物含有(i)90-99.9重量%的自由基可聚合有机化合物(A),其选自可自由基聚合的单体,低聚物,预聚物及其混合物 ; 和(ii)0.1-10重量%的光敏自由基聚合引发剂(B)。 基于自由基可聚合有机化合物(A)的重量,所述自由基可聚合有机化合物(A)包含0.5-20重量%的聚轮烷化合物,所述聚轮烷化合物包含选自聚乙二醇(PEG),聚丙二醇 PPG),聚乙二醇 - 聚丙二醇(PEG-PPG)嵌段共聚物或聚二甲基硅氧烷(PDMS),环糊精环在其上滑动,并且其中环糊精用至少可自由基聚合的基团衍生化。 本发明还涉及一种相对液体光固化树脂组合物及由此制得的制品。

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