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    IMPROVED PROCESSES BASED ON ATOM (OR GROUP) TRANSFER RADICAL POLYMERIZATION AND NOVEL (CO) POLYMERS HAVING USEFUL STRUCTURES AND PROPERTIES
    1.
    发明公开
    IMPROVED PROCESSES BASED ON ATOM (OR GROUP) TRANSFER RADICAL POLYMERIZATION AND NOVEL (CO) POLYMERS HAVING USEFUL STRUCTURES AND PROPERTIES 失效
    基于ATOM（或组）的改进方法。原子转移自由基和新（共）有用的结构与性能的聚合物

    公开(公告)号：EP1555273A1

    公开(公告)日：2005-07-20

    申请号：EP05102361.2

    申请日：1996-11-15

    申请人： CARNEGIE MELLON UNIVERSITY

    发明人： Matyjaszewski, Krzysztof ,  Coca, Simion ,  Gaynor, Scott G. ,  Greszta, Dorota ,  Patten, Timothy E. ,  Wang, Jin-Shan ,  Xia, Jianhui

    IPC分类号： C08F4/40 ,  C08F4/44 ,  C08F4/50

    CPC分类号： C08F271/02 ,  C08F4/00 ,  C08F4/40 ,  C08F110/10 ,  C08F257/02 ,  C08F265/00 ,  C08F265/04 ,  C08F291/00 ,  C08F293/005 ,  C08F2438/01

    摘要： Improved processes have been developed for atom (or group) transfer radical polymerization (ATRP). In one improvement, the ATRP process involves polymerizing in the presence of a (partially) free radical-deactivating amount of the corresponding reduced or oxidized transition metal compound. In a further improvement, the ATRP process involves polymerizing in a homogeneous system or in the presence of a solubilized initiating/catalytic system. The present invention also concerns end-functional, site-specific functional and telechelic homopolymers and copolymers; block, random, graft, alternating and tapered (or "gradient") copolymers which may have certain properties or a certain novel structure; star, comb and "hyperbranched" polymers and copolymers; multi-functional hyperbranched, end-functional polymers; cross-linked polymers and gels; water-soluble polymers and hydrogels (e.g., a copolymer prepared by radical copolymerization of a water-soluble monomer and a divinyl monomer); and an ATRP process using water as a medium.

    摘要翻译： 改进的方法已经开发了用于原子（或基团）转移自由基聚合（ATRP）。 在一个改进中，ATRP方法涉及聚合在相应的还原或氧化的过渡金属化合物的（部分）自由基减活量的存在。 在进一步的改进中，ATRP方法涉及在均相体系或在溶解的引发/催化体系的存在下，本发明因此担心最终功能性的，位点特异性的功能和远螯聚物和共聚物的聚合。 嵌段，无规，接枝，交替和锥形（或“梯度”），其可以具有某些特性或特定结构新颖共聚物; 星形，梳形和“超支化”聚合物和共聚物; 多功能超支化的，端基官能聚合物; 交联聚合物和凝胶; 水溶性聚合物和水凝胶（E. G.，通过水溶性单体和二乙烯基单体的自由基共聚制备的共聚物）; 和ATRP过程中使用水作为介质。