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    IMPROVED PROCESSES BASED ON ATOM (OR GROUP) TRANSFER RADICAL POLYMERIZATION AND NOVEL (CO) POLYMERS HAVING USEFUL STRUCTURES AND PROPERTIES
    1.
    发明公开
    IMPROVED PROCESSES BASED ON ATOM (OR GROUP) TRANSFER RADICAL POLYMERIZATION AND NOVEL (CO) POLYMERS HAVING USEFUL STRUCTURES AND PROPERTIES 失效
    基于ATOM（或组）的改进方法。原子转移自由基和新（共）有用的结构与性能的聚合物

    公开(公告)号：EP1555273A1

    公开(公告)日：2005-07-20

    申请号：EP05102361.2

    申请日：1996-11-15

    申请人： CARNEGIE MELLON UNIVERSITY

    发明人： Matyjaszewski, Krzysztof ,  Coca, Simion ,  Gaynor, Scott G. ,  Greszta, Dorota ,  Patten, Timothy E. ,  Wang, Jin-Shan ,  Xia, Jianhui

    IPC分类号： C08F4/40 ,  C08F4/44 ,  C08F4/50

    CPC分类号： C08F271/02 ,  C08F4/00 ,  C08F4/40 ,  C08F110/10 ,  C08F257/02 ,  C08F265/00 ,  C08F265/04 ,  C08F291/00 ,  C08F293/005 ,  C08F2438/01

    摘要： Improved processes have been developed for atom (or group) transfer radical polymerization (ATRP). In one improvement, the ATRP process involves polymerizing in the presence of a (partially) free radical-deactivating amount of the corresponding reduced or oxidized transition metal compound. In a further improvement, the ATRP process involves polymerizing in a homogeneous system or in the presence of a solubilized initiating/catalytic system. The present invention also concerns end-functional, site-specific functional and telechelic homopolymers and copolymers; block, random, graft, alternating and tapered (or "gradient") copolymers which may have certain properties or a certain novel structure; star, comb and "hyperbranched" polymers and copolymers; multi-functional hyperbranched, end-functional polymers; cross-linked polymers and gels; water-soluble polymers and hydrogels (e.g., a copolymer prepared by radical copolymerization of a water-soluble monomer and a divinyl monomer); and an ATRP process using water as a medium.

    摘要翻译： 改进的方法已经开发了用于原子（或基团）转移自由基聚合（ATRP）。 在一个改进中，ATRP方法涉及聚合在相应的还原或氧化的过渡金属化合物的（部分）自由基减活量的存在。 在进一步的改进中，ATRP方法涉及在均相体系或在溶解的引发/催化体系的存在下，本发明因此担心最终功能性的，位点特异性的功能和远螯聚物和共聚物的聚合。 嵌段，无规，接枝，交替和锥形（或“梯度”），其可以具有某些特性或特定结构新颖共聚物; 星形，梳形和“超支化”聚合物和共聚物; 多功能超支化的，端基官能聚合物; 交联聚合物和凝胶; 水溶性聚合物和水凝胶（E. G.，通过水溶性单体和二乙烯基单体的自由基共聚制备的共聚物）; 和ATRP过程中使用水作为介质。

    Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby
    5.
    发明公开
    Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby 有权
    催化工艺用于受控聚合自由基共聚IT制成单体和功能聚合物体系

    公开(公告)号：EP1637550A3

    公开(公告)日：2006-11-22

    申请号：EP05026587.5

    申请日：2000-03-23

    申请人： CARNEGIE MELLON UNIVERSITY

    发明人： Matyjaszewski, Krzysztof ,  Pintauer, Tomislav ,  Gaynor, Scott G. ,  Pyun, Jeff ,  Paik, Hyun-jong ,  Qui, Jian ,  Xia, Jianhui ,  Teodorescu, Mircea ,  Zhang, Xuan

    IPC分类号： C08F293/00 ,  C08F4/00 ,  C08F2/38 ,  C08F8/00

    CPC分类号： C08F293/00 ,  C08F293/005 ,  C08F2438/01 ,  Y02P20/584

    摘要： Further improvements have been made in processes for controlled polymerization of free radically (co)polymerizable monomers mediated by a transition metal complex participating in a redox reaction which involves transfer of a radically transferable atom or group to and from an initiator or dormant polymer and the growing active polymer chain ends. Two improvements involve the choice of counterion in the transition metal complex. In one improvement the transition metal is held in close conjunction with a solid support through interaction with a counterion directly attached to the support. This cognition also allows for improvements in catalyst utilization including catalyst recovery and recycle. In another improvement, particularly suitable for controlled polymerization of certain monomers with an expanded range of transition metals, the function of counterion and ligand in the development of the transition metal based catalyst is superseded by use of salt containing a soluable organic counterion. These and other process improvements have been employed to prepare and extended range of novel polymeric materials and novel processes for the preparation of functional polymers including a novel catalytic Atom Transfer Coupling Reaction.

    摘要翻译： 进一步的改进已在工艺已取得用于由过渡金属配合物参与的氧化还原反应涉及可自由基转移的原子或基团的转移和从与引发剂或休眠聚合物和生长介导的自由基（共）聚合性单体的受控聚合 活性聚合物链端。 两个方面的改进包括抗衡的过渡金属配合物的选择。 在一个改进的过渡金属在紧密结合通过相互作用与直接连接到载体上的反离子的固体支持物保持。 因此，这种认识允许与催化剂利用率包括催化剂回收和循环得到改善。 在另一改进，特别适用于单体的受控聚合与过渡金属的某些范围扩大，在过渡金属基催化剂的发展抗衡离子和配体的功能是通过使用盐的含一个可溶性有机抗衡离子替代。 这些和其它的工艺改进已被用于制备和新颖聚合材料和功能性聚合物的包含新型催化原子转移偶联反应的新的制备方法的扩展范围。

    Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby
    6.
    发明公开
    Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby 有权
    KATALYTISCHE PROZESSEFÜRDIE KONTROLLIERTE POLYMERISATION VON

    公开(公告)号：EP1637550A2

    公开(公告)日：2006-03-22

    申请号：EP05026587.5

    申请日：2000-03-23

    申请人： CARNEGIE MELLON UNIVERSITY

    发明人： Matyjaszewski, Krzysztof ,  Pintauer, Tomislav ,  Gaynor, Scott G. ,  Pyun, Jeff ,  Paik, Hyun-jong ,  Qui, Jian ,  Xia, Jianhui ,  Teodorescu, Mircea ,  Zhang, Xuan

    IPC分类号： C08F293/00 ,  C08F4/00 ,  C08F2/38 ,  C08F8/00

    CPC分类号： C08F293/00 ,  C08F293/005 ,  C08F2438/01 ,  Y02P20/584

    摘要： Further improvements have been made in processes for controlled polymerization of free radically (co)polymerizable monomers mediated by a transition metal complex participating in a redox reaction which involves transfer of a radically transferable atom or group to and from an initiator or dormant polymer and the growing active polymer chain ends. Two improvements involve the choice of counterion in the transition metal complex. In one improvement the transition metal is held in close conjunction with a solid support through interaction with a counterion directly attached to the support. This cognition also allows for improvements in catalyst utilization including catalyst recovery and recycle. In another improvement, particularly suitable for controlled polymerization of certain monomers with an expanded range of transition metals, the function of counterion and ligand in the development of the transition metal based catalyst is superseded by use of salt containing a soluable organic counterion. These and other process improvements have been employed to prepare and extended range of novel polymeric materials and novel processes for the preparation of functional polymers including a novel catalytic Atom Transfer Coupling Reaction.

    摘要翻译： 在参与氧化还原反应的过渡金属络合物介导的自由基（共）可聚合单体的控制聚合的方法中进行了进一步的改进，其涉及将可自由基转移的原子或基团转移到引发剂或休眠聚合物上和从引发剂或休眠聚合物转移， 活性聚合物链末端。 两个改进涉及在过渡金属络合物中选择抗衡离子。 在一个改进中，过渡金属通过与直接连接到载体上的抗衡离子的相互作用与固体支持物紧密结合。 这种认知还允许催化剂利用率的改善，包括催化剂回收和再循环。 在另一个改进中，特别适用于具有扩展范围的过渡金属的某些单体的可控聚合，通过使用含有可溶性有机抗衡离子的盐，取代了基于过渡金属的催化剂的开发中的抗衡离子和配体的功能。 已经采用了这些和其它工艺改进来制备和扩展新型聚合物材料的范围以及用于制备功能性聚合物的新方法，包括新的催化原子转移偶联反应。