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1.发明公开A METHOD FOR REGENERATING LEWIS ACID-PROMOTED TRANSITION ALUMINA CATALYSTS USED FOR ISOPARAFFIN ALKYLATION BY CALCINATION. 失效一种通过焙烧再生刘易斯酸活化过渡铝氧化物催化剂ISOPARAFFIN烷基化。
公开(公告)号：EP0641253A4
公开(公告)日：1994-06-01
申请号：EP92914739
申请日：1992-06-18
申请人： CATALYTICA INC
发明人： KING DAVID L , RAO PRADIP , COOPER MICHAEL D , SAY JEROME E
IPC分类号： B01J21/04 , B01J27/08 , B01J27/128 , B01J27/135 , B01J27/32 , B01J38/12 , C07B61/00 , C07C2/60 , C07C9/16 , C10G35/06 , B01J20/34 , B01J21/20 , C07C2/58
CPC分类号： B01J21/04 , B01J27/08 , B01J27/128 , B01J27/135 , B01J27/32 , B01J38/12 , C07C2/60 , C07C2521/04 , C07C2527/08 , C07C2527/10 , C07C2527/1213 , C07C2527/125 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/14 , Y02P20/584 , Y10S585/906
摘要： This invention is a process for the regeneration of a catalyst system component comprising certain transition aluminas promoted with a Lewis acid (preferably BF3) which have been used in the alkylation of isoparaffin with olefins. The process involves the calcination of the catalyst system component to volatilize and to oxidize the reaction product residue adhering to the solid catalyst. The process may include recovery and recycle of the involved Lewis acid.
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2.发明公开IMPROVED LEWIS ACID PROMOTED TRANSITION ALUMINA CATALYSTS AND ISOPARAFFIN ALKYLATION PROCESSES USING THOSE CATALYSTS. 失效改进刘易斯酸活化和方法ISOPARAFFIN过渡ALUMINIUMOXYDKATALYSATOREN烷基化使用本催化剂。
公开(公告)号：EP0650394A4
公开(公告)日：1995-12-27
申请号：EP93917235
申请日：1993-07-16
申请人： CATALYTICA INC
CPC分类号： B01J27/12 , B01J27/125 , C07C2/60 , C07C2521/04 , C07C2527/1213
摘要： This invention is directed to a catalyst system for use in the alkylation of isoparaffin with olefins. More specifically, this invention is directed to an improved catalyst system containing specified amounts of water and a component of that system comprising certain transition aluminas promoted with a Lewis acid (preferably BF3). In addition, this invention is a catalytic process for the alkylation of isoparaffin with olefins. The catalyst component is produced by contacting the transition alumina with the Lewis acid at relatively low temperatures. The catalyst system comprises that component and an additional amount of free Lewis acid. The process entails isoparaffin alkylation with olefins using the catalyst component and its allied catalyst system.
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3.发明公开METHOD FOR REGENERATING CERTAIN ACIDIC HYDROCARBON CONVERSION CATALYSTS BY SOLVENT EXTRACTION. 失效方法再生某些酸催化剂用于烃转化溶剂萃取。
公开(公告)号：EP0625133A4
公开(公告)日：1995-04-05
申请号：EP93900631
申请日：1992-11-23
申请人： CATALYTICA INC
发明人： COOPER MICHAEL D , RAO PRADIP , KING DAVID L , LOPEZ RONALD R
IPC分类号： B01J21/04 , B01J27/08 , B01J27/128 , B01J27/135 , B01J27/32 , B01J29/90 , B01J38/48 , B01J38/50 , B01J38/52 , C07B61/00 , C07C2/58 , C07C2/60 , C07C9/16 , C10G35/06 , C10G50/00 , C10L1/04 , C07C2/56 , B01J20/34
CPC分类号： B01J21/04 , B01J27/08 , B01J27/128 , B01J27/135 , B01J27/32 , B01J29/90 , B01J38/48 , B01J38/50 , C07C2/60 , C07C2521/04 , C07C2527/08 , C07C2527/10 , C07C2527/1213 , C07C2527/125 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/14 , Y02P20/584
摘要： This invention is a process for the regeneration of solid acidic hydrocarbon conversion catalysts, but particularly certain transition aluminas and zeolites promoted with Lewis acids (preferably BF3) which have been used in the alkylation of isoparaffins with olefins. The process involves the removal of some portion of the reaction product residue adhering to the solid catalyst by contact with a solvent to partially recover the catalyst's initial activity.
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