摘要:
Provided is a method for producing a dicyclopentadiene-modified phenolic resin, in which resin properties and the color tone stabilize when a catalyst is repeatedly used and the catalyst can be repeatedly used enough times. The method for producing a dicyclopentadiene-modified phenolic resin includes reusing a fluorine-based ion-exchange resin as a catalyst in a reaction between a phenol and a dicyclopentadiene, the fluorine-based ion-exchange resin having been used as a catalyst when a phenol and a dicyclopentadiene are allowed to react with each other to produce a dicyclopentadiene-modified phenolic resin. In the method, the fluorine-based ion-exchange resin to be reused, the fluorine-based ion-exchange resin having been washed with an organic solvent, is used at least once when reused. Also provided is a production method including purifying a product, the method being capable of preventing coloring of a resin obtained in the production of a dicyclopentadiene-modified phenolic resin. The dicyclopentadiene-modified phenolic resin obtained by the production method of the present invention has a stable quality and a high purity and is inexpensive.
摘要:
The invention relates to a method for preparing a catalyst from a catalytic precursor including an alumina and/or silica-alumina and/or zeolite support, and including at least one Group VIB element and optionally at least one Group VIII element, said method involving impregnating said precursor with a solution of a C1-C4 dialkyl succinate. The method comprises a step (step 1) of impregnating said dried, calcined or regenerated precursor with at least one solution containing at least one carboxylic acid other than acetic acid, followed by aging and drying at a temperature of less than or equal to 200°C, optionally followed by a heat treatment at a temperature of less than 350°C, step 1 being followed by impregnation (step 2) with a solution containing at least one C1-C4 dialkyl succinate followed by aging, and drying at a temperature of less than 200°C, without a subsequent calcining step. The catalyst is used in hydroprocessing and/or hydroconversion.
摘要:
The invention pertains to a process for activating a used and regenerated hydrotreating catalyst comprising a Group VIII hydrogenation metal oxide and a Group VI hydrogenation metal oxide on a carrier in which the used and regenerated hydrotreating catalyst is contacted with an additive which is at least one compound selected from the group of compounds comprising at least two hydroxyl groups and 2-10 carbon atoms, and the (poly)ethers of these compounds, after which the catalyst is dried under such conditions that at least 50 % of the additive remains in the catalyst. The additive, is preferably at least one compound selected from ethylene glycol, diethylene glycol, and polyethylene glycol, or a saccharide or polysaccharide. The invention additionally pertains to the catalyst obtainable by this process, which shows high activity in hydrodesulphurisation and hydrodenitrogenation reactions, and to the use of the catalyst in hydrotreating.
摘要:
The present invention pertains to a process for regenerating and rejuvenating a used additive-based catalyst comprising the steps of regenerating the catalyst by contacting it with an oxygen-containing gas at a maximum temperature of 500°C, followed by rejuvenating the catalyst by contacting it with an organic additive, if necessary followed by drying at such a temperature that at least 50 % of the additive is maintained in the catalyst. Preferably, the maximum catalyst temperature during the regeneration step is 300-500°C, more preferably 320-475°C, even more preferably 350-425°C. The process according to the invention makes it possible to restore the activity of a used additive-based hydrotreating catalyst to its original level, or even to improve it to above that level.