摘要:
The present invention provides a method for revamping an HF or sulphuric acid alkylation unit to an ionic liquid alkylation unit, wherein the HF or sulphuric acid alkylation unit comprise at least: -a reactor unit for contacting catalyst and hydrocarbon reactants; -a separator unit for separating a reactor effluent into a catalyst phase and an alkylate-comprising hydrocarbon phase; -a fractionator unit for fractionating the alkylate- comprising hydrocarbon phase into at least one stream comprising alkylate; -a catalyst phase recycle means to recycle at least part of the catalyst phase from the separator unit to the reactor unit; which method includes: -adapting the catalyst phase recycle means by providing a means for acid injection and/or a means for halohydrocarbon injection into the catalyst recycle means. The invention further provides a method for the production of alkylate.
摘要:
The present invention relates to a process for oligomerization/polymerization of ethylene and/or alpha-olefins, comprising the steps of oligomerizing/polymerizing ethylene and/or alpha-olefins, separating the product obtained into at least one marketable product and one or more non-marketable fractions and routing one or more of the non-marketable fractions to a steam cracking furnace for steam cracking thereof.
摘要:
A method for producing light alpha olefins having improved purity by ethylene oligomerisation, wherein ethylene is contacted with a catalyst prepared by mixing a zirconium compound with an organic compound selected from the class of acetals and ketals, and with a chlorinated or brominated aluminium hydrocarbyl compound, and the raw oligomerisation effluent is first treated with an amine then subjected to evaporation to recover the alpha olefins in the evaporated fraction.
摘要:
This invention is a process for the regeneration of a catalyst system component comprising certain transition aluminas promoted with a Lewis acid (preferably BF3) which have been used in the alkylation of isoparaffin with olefins. The process involves the calcination of the catalyst system component to volatilize and to oxidize the reaction product residue adhering to the solid catalyst. The process may include recovery and recycle of the involved Lewis acid.
摘要:
Process for converting heterosubstituted methanes, such as methyl alcohol, methyl ether, methyl mercaptan, dimethyl sulfide, methyl halides, methylal, methylamine and the like, by contacting such methanes with bifunctional acid-base catalysts at elevated temperatures, between 200 and 450 C, preferably between 250 and 375 C, to produce predominantly lower olefins, preferably ethylene and propylene. The catalysts of preference are those derived from halides, oxyhalides, oxides, sulfides or oxysulfides of transition metals of Groups IV, V, VI, VIII of the Periodic Table, such as tantalum, niobium, zirconium, tungsten, titanium, chromium and the like, deposited on acidic oxides and sulfides such as alumina, silica, zirconia or silica-alumina.
摘要:
A process for forming non-polymeric disproportionation products of non-conjugated olefins using catalysts comprising (1) at least one of certain neutral carbene complexes, and (2) at least one of certain compounds of Groups IVa, IVb, Vb, VIb, Vllb, VIII, and Ib of the Periodic Table of the Elements.
摘要:
The present disclosure provides methods to produce para-xylene, toluene, and other compounds from renewable sources (e.g., cellulose, hemicellulose) and ethylene in the presence of an acid, such as a Lewis acid. For example, cellulose and/or hemicellulose may be converted into 2,5-dimethylfuran (DMF) and 2-methylfuran, which may be converted into para-xylene and toluene, respectively. In particular, para-xylene can then be oxidized to form terephthalic acid.