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1.发明授权Process for the manufacture of powders for superconductive ceramic materials 失效一种用于生产粉末的一种超导陶瓷材料的过程
公开(公告)号：EP0524586B1
公开(公告)日：1997-04-02
申请号：EP92112393.1
申请日：1992-07-20
发明人： Fortunati, Stefano , Tului, Mario , Risso, Luca
CPC分类号： C01G3/006 , C01P2006/80 , C04B35/4508 , Y10S505/78
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2.发明公开PROCESS FOR THERMAL PLASMA SPRAYING OF DOPED SEMICONDUCTOR OXIDE-BASED COATINGS 审中-公开Verfahren zum Aufbringen von Beschichtungen auf dopierten Halbleiteroxydenbasen mittels Plasmaspritzen
公开(公告)号：EP1428899A1
公开(公告)日：2004-06-16
申请号：EP03028411.1
申请日：2003-12-11
发明人： Tului, Mario
摘要： A process for the preparation of a composite multilayer product with selective optical properties comprises the operation of depositing, by thermal plasma spraying of powders, a coating of semiconductor oxides doped with oxides of elements chosen from the group consisting of transition metals and metals in the groups III-A and V-A of the periodic table of elements, in which the coating obtained maintains the composition and doping of the thermal plasma sprayed powders substantially unchanged. The figure shows the X-ray diffraction spectrum of a coating deposited according to the process of the present invention.
摘要翻译： 用于制备具有选择性光学性能的复合多层产品的方法包括通过热等离子体喷涂粉末沉积掺杂有元素氧化物的半导体氧化物的涂层的操作，该组分选自组中的过渡金属和金属 元素周期表的III-A和VA，其中获得的涂层维持热等离子体喷涂粉末的组成和掺杂基本上不变。 该图示出了根据本发明的方法沉积的涂层的X射线衍射光谱。
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3.发明公开
公开(公告)号：EP1428900A1
公开(公告)日：2004-06-16
申请号：EP03028413.7
申请日：2003-12-11
发明人： Tului, Mario , Valente, Teodoro
IPC分类号： C23C4/10 , C04B41/45 , C04B35/565
CPC分类号： C23C4/10 , C01B32/956 , C04B35/565 , C04B35/62665 , C04B2235/3839 , C04B2235/3843 , C04B2235/5436 , C04B2235/5445 , C04B2235/80 , Y10T428/2949 , Y10T428/2982
摘要： A silicon carbide-based thermal spray powder contains at least one boride chosen from zirconium boride, titanium boride and hafnium boride. The powder is prepared by mixing and aggregation of powders containing the compounds in question. Said thermal spray powder is used to deposit, via the plasma spraying technique, a silicon carbide-based coating on a metallic or non-metallic substrate. The figure shows the X-ray crystallogram obtained, for a silicon carbide-based powder, according to the invention, after thermal spraying. The substantial identity of this crystallogram with the one obtained prior to thermal spraying demonstrates that the silicon carbide has been deposited on the substrate without decomposing.
摘要翻译： 基于碳化硅的热喷涂粉末含有至少一种选自硼化锆，硼化钛和硼化铪的硼化物。 通过混合和聚集含有所述化合物的粉末来制备粉末。 所述热喷涂粉末用于通过等离子喷涂技术沉积在金属或非金属基底上的基于碳化硅的涂层。 该图示出了对于根据本发明的碳化硅基粉末在热喷涂之后获得的X射线晶体学图。 这种晶体学与在热喷涂之前获得的晶体学基本相同，表明碳化硅已沉积在基底上而不分解。
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4.发明公开Process for the manufacture of powders for superconductive ceramic materials 失效Verfahren zur Herstellung von Pulvernfürsupraleitende keramische Materialien。
公开(公告)号：EP0524586A1
公开(公告)日：1993-01-27
申请号：EP92112393.1
申请日：1992-07-20
发明人： Fortunati, Stefano , Tului, Mario , Risso, Luca
CPC分类号： C01G3/006 , C01P2006/80 , C04B35/4508 , Y10S505/78
摘要： A process for the pyrolysis of YBCO powders, characterized by the preparation of a clear aqueous solution containing the ions yttrium, barium and copper, in the final proportions desired for the powder, in the form of complex compounds, preferably citric complex compounds, and in the presence of a detonating system, like for instance a combination of ammonium ions and of nitrate ions.
The clear solution is then made to concentrate by means of evaporation, until triggering a violent combustion which is carried out at a high temperature, higher than 250°C and preferably higher than 850°C.摘要翻译： YBCO粉末的热解方法，其特征在于以络合物，优选柠檬酸络合物的形式，以所需粉末的最终比例制备含有离子钇，钡和铜的透明水溶液，并且在 引爆系统的存在，例如铵离子和硝酸根离子的组合。 然后将透明溶液通过蒸发浓缩，直到引发在高于250℃，优选高于850℃的高温下进行的剧烈燃烧。
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