MOLECULAR SIEVES MEDIATED UNSATURATED HYDROCARBON SEPARATION AND RELATED COMPOSITIONS, MATERIALS, METHODS AND SYSTEMS

    公开(公告)号:EP4292707A3

    公开(公告)日:2024-02-21

    申请号:EP23205461.9

    申请日:2016-12-27

    摘要: Described herein is a method of providing a hydrocarbon polymer from a hydrocarbon mixture, the hydrocarbon mixture comprising a cyclic olefin. The method comprises: contacting the hydrocarbon mixture with a 10-ring pore molecular sieve at a temperature of -20°C to 60 °C for a time and under conditions to provide a sieved hydrocarbon mixture comprising the cyclic olefin; contacting the sieved hydrocarbon mixture with a polymerization catalyst for a time and under conditions to polymerize the cyclic olefin, thereby forming the hydrocarbon polymer. The 10-ring pore molecular sieve has a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3Å and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2; a T1/T2 ratio ≥ 20:1, wherein T1 is an element independently selected from Si, Ge and a combination thereof, and T2 is an element independently selected from Al, B, Ga and a combination thereof; and a counterion selected from NH 4 + , Li + , Na + , K + , Ca 2+ and a combination thereof. Also described is a hydrocarbon polymer obtained by the method.

    MOLECULAR SIEVES MEDIATED UNSATURATED HYDROCARBON SEPARATION AND RELATED COMPOSITIONS, MATERIALS, METHODS AND SYSTEMS

    公开(公告)号:EP4292707A2

    公开(公告)日:2023-12-20

    申请号:EP23205461.9

    申请日:2016-12-27

    IPC分类号: B01J31/02

    摘要: Described herein is a method of providing a hydrocarbon polymer from a hydrocarbon mixture, the hydrocarbon mixture comprising a cyclic olefin. The method comprises: contacting the hydrocarbon mixture with a 10-ring pore molecular sieve at a temperature of -20°C to 60 °C for a time and under conditions to provide a sieved hydrocarbon mixture comprising the cyclic olefin; contacting the sieved hydrocarbon mixture with a polymerization catalyst for a time and under conditions to polymerize the cyclic olefin, thereby forming the hydrocarbon polymer. The 10-ring pore molecular sieve has a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3Å and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2; a T1/T2 ratio ≥ 20:1, wherein T1 is an element independently selected from Si, Ge and a combination thereof, and T2 is an element independently selected from Al, B, Ga and a combination thereof; and a counterion selected from NH 4 + , Li + , Na + , K + , Ca 2+ and a combination thereof. Also described is a hydrocarbon polymer obtained by the method.

    CATIONIC MUCIC ACID POLYMER-BASED DELIVERY SYSTEMS

    公开(公告)号:EP3795609A1

    公开(公告)日:2021-03-24

    申请号:EP20186381.8

    申请日:2016-06-13

    摘要: The present disclosure is directed to polymer and polymer conjugate-based nanoparticle delivery systems for delivering biological agents, and methods of making and using these compositions. Certain embodiments of the present disclosure provide a nanoparticle comprising a polymer comprising alternating charged and uncharged segments comprising one or more of the following structural units of Formula (I), Formula (II) or Formula (III):



    wherein A is an uncharged segment comprising polyalkylene glycol; and B is a cationically charged segment comprising at least one polyhydroxy linkage comprising at least one pair of vicinal diols.

    ISOMERIZATION OF GLUCOSE INTO FRUCTOSE BY MEANS OF LEWIS ACID-ZEOLITE CATALYSTS
    10.
    发明公开
    ISOMERIZATION OF GLUCOSE INTO FRUCTOSE BY MEANS OF LEWIS ACID-ZEOLITE CATALYSTS 审中-公开
    ISOMERISIERUNG VON GLUKOSE ZU FRUKTOSE MITTELS LEWISSÄURE-ZEOLITE KATALYSATOREN

    公开(公告)号:EP3067362A1

    公开(公告)日:2016-09-14

    申请号:EP16162989.4

    申请日:2011-01-14

    IPC分类号: C07H1/00 C07H3/02 C07D307/58

    CPC分类号: C07H1/00 C07D307/58 C07H3/02

    摘要: Disclosed are processes for isomerizing saccharides. Also disclosed are processes for converting saccharides to furan derivatives. Also disclosed are processes for converting starch to furan derivatives.
    The isomerization is performed in aqueous medium with a high-silica zeolite containing a metal known to have Lewis acid activity incorporated into the framework of the zeolite, the zeolite being Beta, CIT-1, ZSM-12, SSZ-33, SSZ-26, CIT-5 or high silica FAU type zeolite.

    摘要翻译: 公开了异构化糖的方法。 还公开了将糖转化成呋喃衍生物的方法。 还公开了将淀粉转化成呋喃衍生物的方法。 异构化在具有高分子量沸石的水溶液中进行,该高硅沸石含有已知具有引入沸石骨架中的路易斯酸活性的金属,沸石为β,CIT-1,ZSM-12,SSZ-33,SSZ-26 ,CIT-5或高硅烷FAU型沸石。