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    VINYL ALCOHOL COPOLYMERS FOR USE IN AQUEOUS DISPERSIONS AND MELT EXTRUDED ARTICLES
    3.
    发明公开
    VINYL ALCOHOL COPOLYMERS FOR USE IN AQUEOUS DISPERSIONS AND MELT EXTRUDED ARTICLES 审中-公开
    FOR USE IN水分散体和对象乙烯醇共聚物熔融挤出

    公开(公告)号：EP1888674A1

    公开(公告)日：2008-02-20

    申请号：EP06719908.3

    申请日：2006-01-30

    申请人： Celanese International Corporation

    发明人： VICARI, Richard

    IPC分类号： C08J5/18 ,  C08L29/04 ,  C08F2/00 ,  C08F2/06 ,  C08F216/06 ,  C08F218/08

    CPC分类号： C08F216/06 ,  C08F8/12 ,  C08F218/08 ,  C08F220/58 ,  C08F2800/10 ,  C08J5/18 ,  C08J2329/04 ,  C11D17/042 ,  C08F2220/606

    摘要： In a method of preparing an aqueous dispersion selected from drilling fluids, hydraulic cement compositions, mineral pigment containing coatings, and papermaking furnishes or in a method of preparing a melt extrudate, the improvement comprising: a) producing a copolymer of vinyl alcohol (VOH) and 2-acrylamido-2-methyl propane sulfonic acid or a salt of such acid (AMPS) by steps including continuously feeding with agitation, vinyl acetate (VAM) and AMPS as comonomers, a free radical yielding polymerization initiator, and a solvent for said comonomers, initiator, and copolymer resulting from the copolymerization of said comonomers, maintaining the resulting reaction mass in said first reaction zone under polymerization conditions for a residence time sufficient for a major proportion of AMPS fed to said first reaction zone to polymerize, continuously feeding reaction mass from said first reaction zone with an additional supply of AMPS to a second reaction zone, maintaining the reaction mass in the second reaction zone for a residence time sufficient to polymerize a major proportion of the AMPS added to the second reaction zone, continuously withdrawing reaction mass from the second reaction zone, separating copolymer of VAM and AMPS from the latter reaction mass, and saponifying by hydrolysis and/or alcoholysis a major proportion of the acetate groups in said copolymer to form a copolymer of VOH and AMPS; and b) incorporating the saponified copolymer into the aqueous dispersion or melt extrudate. A product comprising a cold water soluble film wherein: a) the film comprises a copolymer of vinyl alcohol (VOH) with a minor amount of 2-acrylamido-2 -methyl propane sulfonic acid in free acid form or as a salt of the free acid (AMPS); and b) the film has a harsh chemical dissolution time of less than about 80 seconds measured by the harsh chemical dissolution test method after 8 weeks.