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1.发明授权OPEN-CHAIN ALKOXYAMINES AND THEIR CORRESPONDING NITROXIDES FOR CONTROLLED LOW TEMPERATURE RADICAL POLYMERIZATION 有权开链烷氧基胺及其各自的NITROXYDE受控低温聚合
公开(公告)号：EP1481012B1
公开(公告)日：2006-05-17
申请号：EP03708135.3
申请日：2003-02-25
IPC分类号： C08F4/00 , C07C239/20 , C07D265/32 , C07D265/34
CPC分类号： C08F4/00
摘要： The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.
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2.发明公开CATIONIC ALKOXYAMINES AND THEIR USE IN PRODUCING NANO PARTICLES FROM NATURAL OR SYNTHETIC CLAYS 有权阳离子烷氧基FOR USE纳米粒子天然和合成粘土生产
公开(公告)号：EP1515950A1
公开(公告)日：2005-03-23
申请号：EP03740262.5
申请日：2003-06-17
IPC分类号： C07D211/94 , C07D241/08 , C07F9/38 , C08F2/00
CPC分类号： C08F4/00 , C07D211/94 , C07D241/08 , C07F9/4006 , C07F9/591
摘要： The instant invention relates to cationic alkoxyamines, which are useful as polymerization initiators/regulators in a controlled stable free radical polymerization process to produce intercalated and/or exfoliated nanoparticles from natural or synthetic clays. The invention also relates to improved nanocomposites produced by this process and to the use of these nanocomposite compositions as, for example, coatings, sealants, caulks, adhesives and as plastic additives.
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3.发明授权N-ALKOXY-4,4-DIOXY-POLYALKYL-PIPERIDINE COMPOUNDS, WITH GLYCIDYL OR ALKYLCARBONYL GROUPS AS FUNCTIONAL INITIATORS FOR CONTROLLED RADICAL POLYMERIZATION 有权N-烷氧基-4,4-二氧 - 聚烷基 - 哌啶化合物的缩水甘油基烷氧基羰基或基团作为官能引发剂受控的自由基聚合
公开(公告)号：EP1341763B1
公开(公告)日：2004-06-16
申请号：EP01994648.2
申请日：2001-11-12
IPC分类号： C07D211/94 , C08F2/00 , C07D491/10 , C07D491/22 , C07D519/00 , C07D405/12
CPC分类号： C07D405/12 , C07D211/94 , C07D491/10 , C08F4/00
摘要： The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polaylkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.
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4.发明授权AMINOSILANE SALTS AND SILANAMIDES OF CARBOXYLIC ACIDS AS CORROSION INHIBITORS 失效氨基硅烷盐和羧酸作为缓蚀剂amidosilanes
公开(公告)号：EP0835289B1
公开(公告)日：1999-05-19
申请号：EP96922816.2
申请日：1996-06-17
发明人： KRAMER, Andreas , FREY,Markus , BRAIG, Adalbert
IPC分类号： C09D5/08 , C23F11/14 , C23F11/173 , C08F8/42 , C07F7/18
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公开(公告)号：EP1749032B1
公开(公告)日：2008-02-27
申请号：EP05742775.9
申请日：2005-05-17
IPC分类号： C08F4/00 , C07D211/94 , C07D241/08 , C07F9/40
CPC分类号： C07D241/08 , C07D211/94
摘要： The instant invention relates to novel alkoxyamine initiators/regulators containing an ethylenically unsaturated, radically polymerizable group. The compounds are useful for the preparation of complex polymeric architectures. Further aspects of the invention are a polymerizable composition and a polymerization process comprising the alkoxyamine initiators/regulators, a macroinitiator obtainable by said polymerization process and a process for polymerizing with the macroinitiator.
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6.发明授权MULTIFUNCTIONAL ALKOXYAMINES BASED ON POLYALKYLPIPERIDINES, POLYALKYLPIPERAZINONES AND POLYALKYLMORPHOLINONES AND THEIR USE AS POLYMERIZATION REGULATORS/INITIATORS 有权基于polyalkylpiperidines POLYALKYLPIPERAZINONEN AND POLYALKYLMORPHOLINONEN，以及它们作为聚合调节剂/引发剂的使用烷氧基胺MULTIFUNKTIONALE
公开(公告)号：EP1417171B1
公开(公告)日：2007-11-21
申请号：EP02758282.4
申请日：2002-06-27
发明人： KRAMER, Andreas , MÜHLEBACH, Andreas , NESVADBA, Peter , ZINK, Marie-Odile , HINTERMANN, Tobias
IPC分类号： C07D211/94 , C08F4/00 , C08F2/38 , C08F12/08 , C08F20/18
CPC分类号： C08F4/00 , C07D211/94
摘要： The instant invention relates to multifunctional alkoxyamines based on polyalkylpiperidines, polyalkylpiperazinones and polyalkylmorpholinones and their use as polymerization regulatros/initiators. Further subjects of the invention are a polymerizable composition comprising an ethylenically unsaturated monomer or oligomer and the alkoxyamine compound as well as a process for polymerization and a process for preparation of the compounds.
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7.发明公开PROCESS FOR THE PREPARATION OF HYDROXY-VINYL-AROMATIC POLYMERS OR COPOLYMERS BY ANIONIC OR CONTROLLED RADICAL POLYMERIZATION 有权用于生产羟基乙烯基BY阴离子芳香聚合物或共聚物或受控的自由基聚合
公开(公告)号：EP1572758A1
公开(公告)日：2005-09-14
申请号：EP03810997.1
申请日：2003-11-05
CPC分类号： C08F12/22
摘要： The instant invention relates to a process for the preparation of hydroxy-vinyl-aromatic polymers in particular 4-hydroxystyrene polymers or copolymers by anionic or controlled radical polymerization of the respective monomer, wherein the hydroxy functionality is blocked with a protective group which is subsequently removed by reacting it with a halosilane reagent. The resulting (co)polymers have a narrow polydispersity and are useful for manufacturing photoresists.
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8.发明授权MONO AND MULTIFUNCTIONAL ALKOXYAMINES FOR THE PREPARATION OF FUNCTIONALIZED MACROMERS 有权单声道和多用于制备官能大分子功能烷氧基
公开(公告)号：EP1189875B1
公开(公告)日：2004-08-04
申请号：EP00951302.9
申请日：2000-06-26
IPC分类号： C07C239/20 , C07D211/94 , C08F4/00
CPC分类号： C07D295/24 , C07D211/94 , C07F7/1856 , C07F9/4006 , C08F4/00
摘要： The invention pertains to a compound of formula (I), (II) or (III) wherein R1 and R2 are independently of each other hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkinyl or phenyl which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; A is a group capable of forming a stable free nitroxyl radical A., which is bound via its oxygen atom to the carbon atom; Y is O, NR3 or CHR3-Xa, wherein Xa is O, S or NR3; R3 is hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkinyl or phenyl which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; Q1 is an organic or inorganic radical, derived from a compound having at least one functional group being capable of reacting with a hydroxy group; Q2 is an organic radical derived from a mono or polyfunctional alcohol, mono or polyfunctional aminoalcohol, mono or polyfunctional amine mono or polyfunctional mercaptane, mono or polyfunctional phenol or mono or polyfunctional thiophenol; and n is a number from 1 to 20; with the provison that in formula (I) if n is 1, Q1 is not (a), or if n is 2, R1 is H, and R2 is -CH2-O-tert.butyl, A is not 2,2,6,6-tetramethylpiperidine or 2,2,6,6-tetramethylpiperidine-4-carboxylic acid. Further subjects of the invention are a composition comprising above compounds and at least one ethylenically unsaturated monomer, process for polymerization and the (co)polymers obtained therefrom.
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9.发明公开POLYMERIZABLE COMPOSITIONS CONTAINING ALKOXYAMINE COMPOUNDS DERIVED FROM NITROSO- OR NITRONE COMPOUNDS 失效NITRONE-或亚硝基化合物衍生的烷氧基，含有可聚合的组合物
公开(公告)号：EP0996643A1
公开(公告)日：2000-05-03
申请号：EP98935015.2
申请日：1998-07-03
IPC分类号： C08F2/00 , C08F2/38 , C08F4/00 , C07C239/20 , C08F293/00
CPC分类号： C08F293/00 , C07C255/64 , C07C2601/14 , C07D207/09 , C07D207/20 , C08F4/00
摘要： A polymerizable composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, and b) an initiator compound of formula (I) wherein n is 0 or 1. The compounds of formula (I) are prepared from a free radical (a) and a compound of formula R10NO or (b). Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, novel initiator compounds and their use for polymerization, intermediate compounds and also the polymer or copolymer produced by this process.
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10.发明授权PROCESS FOR THE PREPARATION OF HYDROXY-VINYL-AROMATIC POLYMERS OR COPOLYMERS BY ANIONIC OR CONTROLLED RADICAL POLYMERIZATION 有权用于生产羟基乙烯基BY阴离子芳香聚合物或共聚物或受控的自由基聚合
公开(公告)号：EP1572758B1
公开(公告)日：2007-07-18
申请号：EP03810997.1
申请日：2003-11-05
CPC分类号： C08F12/22
摘要： The instant invention relates to a process for the preparation of hydroxy-vinyl-aromatic polymers in particular 4-hydroxystyrene polymers or copolymers by anionic or controlled radical polymerization of the respective monomer, wherein the hydroxy functionality is blocked with a protective group which is subsequently removed by reacting it with a halosilane reagent. The resulting (co)polymers have a narrow polydispersity and are useful for manufacturing photoresists.
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