公开(公告)号：EP3050622A1

公开(公告)日：2016-08-03

申请号：EP14847966.0

申请日：2014-09-25

申请人： Cosmo Oil Co., Ltd.

发明人： OSAKI, Takayuki ,  NAKAJIMA, Nobumasa

IPC分类号： B01J23/88 ,  B01J35/10 ,  C10G45/04

CPC分类号： B01J23/8873 ,  B01J21/04 ,  B01J23/06 ,  B01J23/883 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/847

摘要： The purpose of the present invention is to provide: a hydrogenation catalyst capable of improving the storage stability of hydrogenated heavy hydrocarbon oil without reducing desulfurization activity or demetallization activity; and a method for hydrogenation of heavy hydrocarbon oil by using the hydrogenation catalyst, the present invention provides a hydrogenation catalyst for heavy hydrocarbon oil is provided, characterized by: at least one of metals in Group 6 of the periodic table being held by a zinc-containing alumina carrier containing 1% by mass to 15% by mass of zinc oxide particles having an average particle diameter of 2 µm to 12 µm based on the carrier; the average pore diameter being 18 nm to 35 nm, and the specific surface area being 70 m 2 /g to 150 m 2 /g, and a hydrogenation method for heavy hydrocarbon oil is also provided, characterized by a catalytic reaction of heavy hydrocarbon oil in the presence of the hydrogenation catalyst, under the conditions of a temperature of 300 °C to 420°C, a pressure of 3 MPa to 20 MPa, a hydrogen/oil ratio of 400 m 3 /m 3 to 3,000 m 3 /m 3 , and a liquid space velocity of 0.1 h -1 to 3 h -1 .

摘要翻译： 本发明的目的在于提供：能够提高氢化重质烃油的储存稳定性，而不会降低脱硫活性或脱金属活性的加氢催化剂; 并且通过使用氢化催化剂的重质烃油加氢方法中，本发明提供了一种重质烃油的加氢催化剂提供，其特点：金属中的至少一种在第6组被保持由一种锌元素周期表 含有氧化铝载体含有1质量％至15％的具有上的2微米至12基于载体微米平均粒径的氧化锌颗粒的质量; 因此，平均孔直径为18纳米至35纳米，且比表面积为70米2 /克至150米2 /克，而对于重质烃油的加氢方法被提供，由重质烃油的催化反应为特征的 在氢化催化剂的存在下，在300℃的温度的条件下，以420℃，3MPa的至20MPa，400米3 /米3至3000米3 / m的氢/油比的压力 3，和0.1小时-1至3小时-1的液时空速。