摘要:
A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.
摘要:
A surface treatment agent, which can impart the excellent water- and oil-repellency, soil resistance and feeling to the substrate, is obtained from a fluorine-containing polymer which contains: (A) a monomer which comprises; (A1) a fluorine-containing monomer of the formula: CH2═C(—X)—C(═O)—Y—Z—Rf wherein X is a hydrogen atom, a monovalent organic group, or a halogen atom, Y is —O— or —NH—, Z is a direct bond or a divalent organic group, and Rf is a fluoroalkyl group having 1 to 20 carbon atoms, and (A2) a (meth)acrylate monomer having a cyclic hydrocarbon group, and (B) at least one functional organopolysiloxane selected from the group consisting of a mercapto-functional organopolysiloxane, a vinyl-functional organopolysiloxane, a (meth)acrylamide-functional organopolysiloxane and a (meth)acrylate-functional group.
摘要:
The present invention provides a method for producing a molded article from a molding material wherein the molding material comprises a fluorine-containing graft chain.
摘要:
Disclosed is a fluoropolymer that can impart high anti-water pressure properties and can improve the peel strength of a coating. The fluoropolymer comprises (a) a fluoromonomer and (b) an acrylamide monomer represented by formula:
wherein X represents a hydrogen atom or a methyl group; R 1 represents a hydrogen atom or an alkyl group or alkoxyalkyl group having 1 to 10 carbon atoms; R 2 represents an alkyl group or alkoxyalkyl group having 1 to 10 carbon atoms. The fluoromonomer (a) is preferably a fluoroacrylate. Preferably, the fluoropolymer further comprises (c) a noncrosslinkable monomer or a crosslinkable monomer as another monomer. The noncrosslinkable monomer is preferably an acrylate compound represented by general formula: CH 2 =CA 1 COOA 2 wherein A 1 represents a hydrogen atom or a methyl group, and A 2 represents an alkyl group represented by C n H 2n+1 wherein n is 1 to 30.
摘要翻译:公开了能够赋予高抗水压性能并且可以提高涂层剥离强度的含氟聚合物。 含氟聚合物包含(a)含氟单体和(b)由下式表示的丙烯酰胺单体:其中X表示氢原子或甲基; R 1表示氢原子或碳原子数1〜10的烷基或烷氧基烷基; R 2表示碳原子数1〜10的烷基或烷氧基烷基。 氟单体(a)优选为氟代丙烯酸酯。 优选地,含氟聚合物还包含(c)不可交联单体或可交联单体作为另一单体。 非交联性单体优选为由通式CH 2 = CA 1 COOA 2表示的丙烯酸酯化合物,其中A 1表示氢原子或甲基,A 2表示由C n H 2n + 1表示的烷基,其中n为 1到30。
摘要:
Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general formula (I) CH 2 =C(-X)-C(=O)-Y-[-(CH 2 ) m -Z-] p -(CH2) n -Rf (wherein X represents a hydrogen atom; Y represents -O- or -NH-; Z represents a direct bond, -S- or -SO 2 -; Rf represents a fluoroalkyl group having 1-6 carbon atoms; m is a number of 1-10; n is a number of 0-10; and p is 0 or 1) and (b) an alkoxy group-containing monomer represented by general formula (II) CH 2 =C(X')-C(=O)-O-(RO) q -H (wherein X' represents a hydrogen atom or a methyl group; R represents an alkylene group having 2-4 carbon atoms wherein a part or all of hydrogen atoms may be substituted by a hydroxyl group; and q represent an integer of 1-50). The fluorine-containing polymer does not contain a monomer having an amino group.
摘要:
A treatment for paper, containing (A) a fluorine-containing polymer comprising repeating units derived from a fluorine-containing monomer (a) represented by the general formula (I):
CH 2 =C(-X)-C(=O)-Y-(CH 2 ) m -Z-(CH 2 ) n -Rf (I)
wherein X is hydrogen, methyl, fluoro, chloro, CFX 1 X 2 (wherein X 1 and X 2 are each hydrogen, fluoro, or chloro), or the like; Y is -O- or -NH-; Z is -S-, -SO-, or -SO 2 -; Rf is fluoroalkyl having 1 to 6 carbon atoms; m is 1 to 10; and n is 0 to 10.
摘要:
Provided is a surfactant which has a high surface tension reducing ability and a high solubility in a liquid medium, comprising a fluorine-containing copolymer containing, as essential components, a monomer having a fluoroalkyl group having 1 to 7 carbon atoms, a hydrophilic monomer, and a monomer having an ion donor group. Further provided are a coating composition, an ink composition and a photographic emulsion composition, each comprising the surfactant.