PROCESS FOR EQUILIBRIUM-LIMITED REACTIONS
    3.
    发明公开
    PROCESS FOR EQUILIBRIUM-LIMITED REACTIONS 有权
    VERFAHRENFÜRGLEICHGEWICHTSBEGRENZTE REAKENEN

    公开(公告)号:EP2991965A2

    公开(公告)日:2016-03-09

    申请号:EP14727342.9

    申请日:2014-05-02

    IPC分类号: C07C67/08 C07C69/14 B01D15/38

    摘要: A process for conducting equilibrium-limited chemical reactions that produce water as a reaction product. Specifically, a process that uses a reactive chromatography unit (RCU) to improve the efficiency of equilibrium-limited reactions, such as a process for reacting glycol ether (GE) and carboxylic acid (CA) to form water and glycol ether ester (GEE). The process includes supplying GE and CA to the RCU, where one of either the CA or the GE is in a stoichiometric deficit relative to the other reactant. The reactant in the stoichiometric deficit reacts in the presence of the catalyst in the RCU to form a mixture of GEE and water. A raffinate is separated from the mixture using the separation media of the RCU contains at least the GEE. An extract separated from the mixture using the separation media of the RCU contains at least the water.

    摘要翻译: 一种产生水作为反应产物的平衡限制化学反应的方法。 具体地,使用反应性色谱单元(RCU)来提高平衡有限反应的效率的方法,例如使二醇醚(GE)和羧酸(CA)反应形成水和二醇醚酯(GEE)的方法, 。 该过程包括向RCU提供GE和CA,其中CA或GE之一相对于其他反应物的化学计量缺乏。 化学计量缺口中的反应物在RCU中的催化剂存在下反应以形成GEE和水的混合物。 使用RCU的分离介质至少含有GEE,将萃余液与混合物分离。 使用RCU的分离介质与混合物分离的提取物至少含有水。

    EXTRACTIVE DEHYDRATION PROCESS
    8.
    发明公开
    EXTRACTIVE DEHYDRATION PROCESS 审中-公开
    提取脱水过程

    公开(公告)号:EP3166919A1

    公开(公告)日:2017-05-17

    申请号:EP15741672.8

    申请日:2015-06-25

    IPC分类号: C07C51/377

    摘要: A process comprising subjecting a composition comprising an alpha- or beta-hydroxycarboxylic acid, water, an extraction solvent, and an acid catalyst to extractive dehydration to form an unsaturated carboxylic acid product.

    摘要翻译: 包括使包含α-羟基羧酸,β-羟基羧酸,水,萃取溶剂和酸催化剂的组合物进行萃取脱水以形成不饱和羧酸产物的方法。