公开(公告)号：EP0204513B1

公开(公告)日：1991-07-17

申请号：EP86304075.4

申请日：1986-05-29

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George

IPC分类号： A01N47/36 ,  C07D403/12 ,  C07D401/12

CPC分类号： C07D257/04 ,  A01N47/36 ,  C07D403/04 ,  C07D521/00

公开(公告)号：EP0039239B1

公开(公告)日：1986-02-26

申请号：EP81301874.4

申请日：1981-04-28

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Budzinski, John Charles ,  Zimmerman, Donna Frieze ,  Levitt, George

IPC分类号： A01N47/36 ,  C07D403/12

CPC分类号： C07D521/00 ,  A01N47/36

公开(公告)号：EP0023141B1

公开(公告)日：1984-04-11

申请号：EP80302433.0

申请日：1980-07-18

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George ,  Sauers, Richard Frank

IPC分类号： A01N47/36 ,  C07D239/46 ,  C07D239/42 ,  C07D251/16 ,  C07D251/42 ,  C07D251/46 ,  C07D253/06 ,  C07C143/828

CPC分类号： C07C311/65 ,  A01N47/36 ,  A01N47/42 ,  C07C309/00 ,  C07C323/00 ,  C07C2601/02 ,  C07C2601/14 ,  C07D239/47 ,  C07D253/07 ,  C07D521/00

公开(公告)号：EP0094260A2

公开(公告)日：1983-11-16

申请号：EP83302681.8

申请日：1983-05-11

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George

IPC分类号： C07D239/52 ,  C07D239/26 ,  C07D239/34 ,  C07D251/20 ,  A01N47/28

CPC分类号： C07D521/00 ,  A01N47/34 ,  C07D239/34 ,  C07D239/47 ,  C07D251/20 ,  C07D251/26 ,  C07D251/46

摘要： Compounds of the formula
wherein J is selected from substituted phenyl, substituted pyridyl or various heterocyclic groups;

R 4 and R 5 are independently H or CH 3 ;
m is 0 or 1;
Z is CH or N;
X is CH 3 or OCH 3 ;
Y is selected from various organic groups;

and their agriculturally suitable salts, possess pre-emergence and/or post-emergence herbicidal activity. Some also exhibit plant growth regulant activity. The novel compounds may be formulated into herbicidal compositions in conventional manner.
The compounds may be prepared by reacting an appropriate sulfonyl isocyanate of formula JS0 2 NCO with an appropriate heterocyclic amine, also novel per se.

摘要翻译： 其中J选自取代的苯基，取代的吡啶基或各种杂环基; R4和R5独立地为H或CH3; ... m为0或1; Z为CH或N; ... X 是CH3或OCH3; ... Y选自各种有机基团; ...及其农业上合适的盐，具有出苗前和/或芽后除草活性。 一些还表现出植物生长调节活性。 新化合物可以以常规方式配制成除草组合物。 化合物可以通过使式JSO 2 NCO的合适的磺酰基异氰酸酯与本身也是新颖的合适的杂环胺反应来制备。

公开(公告)号：EP0051465A1

公开(公告)日：1982-05-12

申请号：EP81305159.6

申请日：1981-10-30

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Budzinski, John Charles ,  Levitt, George ,  Yeh, Chin-Lung

IPC分类号： C07D401/12 ,  A01N47/36

CPC分类号： C07D239/47 ,  A01N47/36 ,  A01N47/42 ,  C07D215/36 ,  C07D521/00

摘要： Compounds of the formula
wherein A is


R 1 is H, F. Cl, Br, OCH 3 , CH 3 , NO 2 , CO 2 R 2 , S(O) n R 3 , SO 2 NR 4 R 5 , SO 2 N(OCH 3 )CH 3 or OSO 2 R 6 :
R 2 is C 1 -C 4 alkyl, C 3 -C 4 alkenyl, CH 2 CH 2 CI or CH 2 CH 2 0CH 3 ;
R 3 is C 1 -C 4 alkyl;
R 4 and R 5 are independently C 1 -C 4 alkyl;
R6 is C 1 -C4 alkyl or CF3;
n is 0, 1 or 2;
X is C 1 -C 2 alkyl, C 1 -C 2 alkyi substituted with OCH 3 , CF 3 ,
C 1 -C 3 alkoxy, N(CH 3 ) 2 , NHCH 3 , NH 2 , or SCH 3 ;
Y is CH 3 , OCH 3 or Cl;
Z is CH or N; and
W is 0 or S;
and their agricultural salts;
exhibit herbicidal activity. They may be formulated for use in conventional manner. The compounds may be made by reacting novel herbicidally active compounds of formula

wherein X' and Y 1 are chlorine or bromine.
with an alkali metal methoxide; or by reacting the appropriate quinolinesulfonamide with the appropriate heterocyclic isocyanate.

摘要翻译： R 1是C 1 -C 4烷基，C 1 -C 4烷基，C 1 -C 4烷基， ，C 3 -C 4烯基，CH 2 CH 2 Cl或CH 2 CH 2 OCH 3; ... R3是C1-C4烷基; R4和R5独立地是C1-C4烷基; R6是C1-C4烷基或CF3; ... n是0,1或2; ... X 是C 1 -C 2烷基，被OCH 3，CF 3，C 1 -C 3烷氧基，N（CH 3）2，NHCH 3，NH 2或SCH 3取代的C 1 -C 2烷基; Y是CH 3，OCH 3或Cl; Z是CH或N; 和... W是O或S; ...及其农用盐; ...表现出除草活性。 它们可以以常规方式制备。 这些化合物可以通过使新的除草活性化合物的化学式反应制备，其中X min和Y min是氯或溴，...与碱金属甲醇盐反应; 或通过使适当的喹啉磺酰胺与适当的杂环异氰酸酯反应。

公开(公告)号：EP0048143A1

公开(公告)日：1982-03-24

申请号：EP81304170.4

申请日：1981-09-11

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George

IPC分类号： C07D239/42 ,  C07D239/46 ,  C07D251/16 ,  C07D251/22 ,  C07D251/46 ,  A01N47/36

CPC分类号： C07D521/00 ,  A01N47/36 ,  C07D239/76

摘要： Compounds of the formula
wherein

R, is H, C 1 -C 3 alkyl or OCH 3 ;
R 2 is H or C 1 -C 3 alkyl;
R 3 is

R 4 is C 1 -C 3 alkyl;
R 5 is H, F, Cl, Br, NO 2 , CH 3 , OCH 3 or CF 3 ;
X is CH 3 , C 2 H 5 , CH 2 0CH 3 , C, 1-3 alkoxy, OCH 2 CH 2 0CH 3 , CF 3 or SCH 3 ;
Y is CH 3 or OCH 3 ; and
Z is CH orN;
and their agriculturally suitable salts, provided that R 1 and R 2 are not both H, exhibit activity as general and selective herbicides and as plant growth regulants. For such uses the compounds may be formulated into compositions in conventional manner.

The novel compounds may be made by reacting together corresponding compounds of formulae R 3 SO 2 NCO and
wherein R 1 , R 3 , X, Y and Z are as defined above.

摘要翻译： 下式的化合物：其中R1是H，C1-C3烷基或OCH3; R2是H或C1-C3烷基; R3是R4是C1-C3烷基; R5是H，F，Cl，Br，NO2，CH3，OCH3或CF3; X是CH 3，C 2 H 5，CH 2 OCH 3，C 1-3烷氧基，OCH 2 CH 2 OCH 3，CF 3或SCH 3; Y是CH3或OCH3; Z是CH或N; 以及它们的农业上合适的盐，条件是R1和R2不都是H，表现出作为一般和选择性除草剂以及植物生长调节剂的活性。 对于这种用途，化合物可以以常规方式配制成组合物。 该新化合物可以通过使式R 3 SO 2 NCO的相应化合物一起反应来制备，并且其中R 1，R 3，X，Y和Z如上所定义。

公开(公告)号：EP0044211A1

公开(公告)日：1982-01-20

申请号：EP81303178.8

申请日：1981-07-10

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George

IPC分类号： C07D239/42 ,  C07D251/12 ,  C07D491/048 ,  A01N47/36 ,  C07D251/46 ,  C07D239/47 ,  C07D239/70 ,  C07D491/052

CPC分类号： C07C309/81 ,  A01N47/36 ,  C07C311/65 ,  C07D521/00

摘要： The invention relates to compounds of formula I
(wherein
having a total of no more than nine carbon atoms;

n is 0 or 1;
R, is H, F, Cl, Br, NO 2 , CF 3 , C,-C 3 alkyl, OCF 3 or C 1 -C 4 alkoxy;
R 2 and R 3 are selected independently from H and CH 3 ;
R 4 is H, C 1 -C 3 alkyl, F, Cl, Br, CF 3 , OCF 3 or C 1 -C 3 alkoxy;
R 5 is CH 3 , Cl, Br or H;
A is

X is H, CH 3 , OCH 3 , OCH 2 CH 3 , OCH 2 CF 3 , CH 2 OCH 3 or Cl;
Y is CH 3 , OCH 3 or OCH 2 CH 3 ;
Z is N, CH, CCI, C-Br, C-CN, CCH 3 , C-CH 2 CH 3 , C-CH 2 CH 2 CI or C-CH 2 CH=CH 2 ;
Y' is H, CH 3 , OCH 3 or Cl; and
Q is CH 2 or 0) and salts thereof.

These compounds have been found to posess herbicidal activity and the invention further relates to compositions containing them and to a method for their use in controlling the growth of undesired vegetation.

摘要翻译： 本发明涉及式I化合物（其中总共不超过9个碳原子; n是0或1; R 1是H，F，Cl，Br，NO 2，CF 3，C 1 -C 3烷基，OCF 3或 C1-C4烷氧基; R2和R3独立地选自H和CH3; R4为H，C1-C3烷基，F，Cl，Br，CF3，OCF3或C1-C3烷氧基; R5为CH3，Cl，Br或H; A是X是H，CH 3，OCH 3，OCH 2 CH 3，OCH 2 CF 3，CH 2 OCH 3或Cl; Y是CH 3，OCH 3或OCH 2 CH 3; Z是N，CH，CCl，C-Br，C-CN，CCH 3，C-CH 2 CH 3，C- CH 2 CH 2 Cl或C-CH 2 CH = CH 2; Y'是H，CH 3，OCH 3或Cl;且Q是CH 2或O）及其盐。 已经发现这些化合物具有除草活性，并且本发明进一步涉及含有它们的组合物以及它们用于控制不希望的植物生长的方法。

公开(公告)号：EP0041404A3

公开(公告)日：1982-01-13

申请号：EP81302461

申请日：1981-06-03

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George

IPC分类号： A01N47/36 ,  C07D409/12

CPC分类号： C07D521/00 ,  A01N47/36 ,  C07D333/28 ,  C07D333/34

摘要： Compounds of the formula
wherein
A is SO 2 N(R 3 IC(O)N(R 4 )R 5 ; R is C 1 -C 4 alkyl, C 3 alkenyl, OCH 3 , NO 2 , CI, Br, SO 2 NR 1 R 2 and SO 2 N(OCH 3 )CH 3 ; R 1 and R 2 are independently C 1 -C 3 alkyl; R 3 is H or CH 3 ; R 4 is H, CH 3 or OCH 3 ; R 5 is
X,X 2 , Y, Y 1 and Y 2 are selected from various substituents; Z is N, methine or substituted methine; Q is O or CH 2 ; and their agricultural salts; possess herbicidal activity, especially against broad-leaf weeds. They are also of interest as plant growth regulants. The compounds may be formulated for use in conventional manner. The compounds may be made by a variety of routes, e.g. by reacting an appropriately substituted thiophenesulfonyl isocyanate
with an appropriate amine NHR 4 R 6 . The substituted thiophenesulfonyl isocyanates are novel intermediates. Other novel intermediates are analogues of the thiophenesulfonamides wherein X and Y are both chlorine.

公开(公告)号：EP0041404A2

公开(公告)日：1981-12-09

申请号：EP81302461.9

申请日：1981-06-03

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George

IPC分类号： A01N47/36 ,  C07D409/12

CPC分类号： C07D521/00 ,  A01N47/36 ,  C07D333/28 ,  C07D333/34

摘要： Compounds of the formula
wherein

A is SO 2 N(R 3 IC(O)N(R 4 )R 5 ;
R is C 1 -C 4 alkyl, C 3 alkenyl, OCH 3 , NO 2 , CI, Br, SO 2 NR 1 R 2 and SO 2 N(OCH 3 )CH 3 ;
R 1 and R 2 are independently C 1 -C 3 alkyl;
R 3 is H or CH 3 ;
R 4 is H, CH 3 or OCH 3 ;
R 5 is


X,X 2 , Y, Y 1 and Y 2 are selected from various substituents; Z is N, methine or substituted methine;
Q is O or CH 2 ; and their agricultural salts; possess herbicidal activity, especially against broad-leaf weeds. They are also of interest as plant growth regulants. The compounds may be formulated for use in conventional manner.

The compounds may be made by a variety of routes, e.g. by reacting an appropriately substituted thiophenesulfonyl isocyanate
with an appropriate amine NHR 4 R 6 . The substituted thiophenesulfonyl isocyanates are novel intermediates. Other novel intermediates are analogues of the thiophenesulfonamides wherein X and Y are both chlorine.

公开(公告)号：EP0030141A3

公开(公告)日：1981-08-19

申请号：EP80304286

申请日：1980-11-28

申请人： E.I. DU PONT DE NEMOURS AND COMPANY

发明人： Levitt, George

IPC分类号： A01N47/36 ,  C07D239/52 ,  C07D239/42 ,  C07D239/46 ,  C07D251/22 ,  C07D251/46 ,  C07D251/16 ,  C07D491/04 ,  C07C143/828 ,  C07D307/00 ,  C07D239/00

CPC分类号： C07C311/65 ,  C07D521/00

摘要： Compounds of the formula
(wherein A' is H, F, Cl, Br, CH,O or N0 2 ;
A and A 2 are selected independently from Cl, F, Br, NO 2 , CH 3 and alkoxy; from a wide variety of substituted sulfonamide and sulfonate groups; and (with the exception of A) from a wide variety of substituted ester and thioester, alkylcarbonyl and oximated alkylcarbonyl groups; B is
(wherein R 4 is H or CH 3 ; R' is selected from a variety of substituted pyrimidinyl, furopyrimidinyl and triazinyl groups; R 6 is C 1-6 alkyl and W is O or S)) and agriculturally suitable salts thereof exhibit herbicidal activity and also may be of interest as plant growth regulants. Certain of the compounds may be useful for selective weed control in crops such as rice. The compounds can be formulated for use in a conventional manner. They may be prepared by a variety of processes e.g. by reacting a compound of the formula
wherein A, A 1 , A 2 and W 5 are as defined above with an appropriate amine HNR 4 R 5. Some of the intermediate isocyanate or isothiocyanate compounds shown above form further features of the invention. They may be made e.g. by reaction of the corresponding sulfonamides with phosgene. Intermediates having the formulae and
(wherein Z is CH or N) are also within the scope of the invention.