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1.发明公开Preparation of monomethylamine from ammonia and methanol using a zeolitic catalyst 失效Herstellung von Monomethylamin aus Ammoniak und Methanol unter Verwendung eines沸石沉淀物。
公开(公告)号：EP0025693A1
公开(公告)日：1981-03-25
申请号：EP80303180.6
申请日：1980-09-10
CPC分类号： C07C209/16 , C07C211/04
摘要： High selectivity in monomethylamine can be achieved by reacting methanol and ammonia, in such amounts as to provide a C/N ratio, from the methanol and ammonia reactants, of 0.5-1.5, in the presence of a catalyst selected from
a) mordenite wherein the primary cation is Li, Na, HNa having at least 2% Na by weight, K, Ca, Sr, Ba, Ce, Zn orCr
b) ferrierite wherein the primary metal cation is Li, Na, K, Ca, Sr, Ba, Ce or Fe
c) erionite ore
d) Calcium erionite and
e) clinoptilolite ore,
at a temperature of 250-475°C, a pressure of 7-7000 kPa, a contact time, normalized to 7 kPa pressure, of 0.1-60 seconds and a methanol conversion of 15-95%.摘要翻译： 通过在选自以下的催化剂存在下，使甲醇和氨在甲醇和氨反应物中提供C / N比为0.5-1.5的量来实现单甲胺的高选择性：a）丝光沸石，其中 主要阳离子为Na，Na，Na，Na，K，Ca，Sr，Ba，Ce，Zn或Cr中的至少2％，b）镁碱沸石，其中一次金属阳离子为Li，Na，K，Ca，Sr ，19a，Ce或Fe ... c）黑质矿石d）钙质闪石和e）斜发沸石矿石，在250-475℃的温度下，压力为7-7000 kPa，接触时间为7 kPa 压力为0.1-60秒，甲醇转化率为15-95％。
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公开(公告)号：EP0285324B1
公开(公告)日：1991-11-27
申请号：EP88302611.4
申请日：1988-03-24
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公开(公告)号：EP0285324A1
公开(公告)日：1988-10-05
申请号：EP88302611.4
申请日：1988-03-24
摘要： Substituted fluorobenzenes are produced by pyrolyzing vinylfluorocyclobutanes at a temperature of 250-450°C in the presence of activated carbon or certain metal oxides selected from oxides of aluminium, titanium, cerium or chromium or mixtures of metal oxides.
摘要翻译： 取代的氟苯通过在活性炭或选自铝，钛，铈或铬的氧化物或金属氧化物的氧化物的某些金属氧化物的存在下，在250-450℃的温度下热解乙烯基氟代环丁烷来制备。
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公开(公告)号：EP0203807B1
公开(公告)日：1988-09-28
申请号：EP86304014.3
申请日：1986-05-27
IPC分类号： C07C17/20
CPC分类号： C07C17/37 , C07C17/202
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5.发明公开Catalytic fluoroolefin transhalogenations 失效Katalytisches Verfahren zur Transhalogenierung von Fluoroolefinen。
公开(公告)号：EP0203807A1
公开(公告)日：1986-12-03
申请号：EP86304014.3
申请日：1986-05-27
IPC分类号： C07C17/20
CPC分类号： C07C17/37 , C07C17/202
摘要： Catalyzed halogen exchange between perhaloolefins to form products of the formulas:
wherein R 1 , R Z , R 3 , R 5 , R 6 and R 7 are independently selected from F, Cl, Br, C 1 to C 4 perfluoroalkyl and pentrafluorophenyl; or R 1 and R 3 together, R 2 and R 3 together, R 5 and R 7 together or R 6 and R 7 together, when both groups are in the cis configuration, may also represent perfluoroalkylene of 2 to 4 carbons or o-C 6 F 4 (-)CF 2 -; R 8 =F; R 4 = Cl or Br; none of the fluoroolefins simultaneously contain both Cl and Br; and R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 may be chosen as to product identical structures for the reactants or for the products.摘要翻译： 在全卤代烯烃之间催化卤素交换以形成下式的产物：R 1 R 2 C = CR 3 R 8和R 5 R 6 C = CR 7 R 4其中 R 1，R 2，R 3，R 5，R 6和R 7独立地选自F，Cl，Br，C 1至C 4全氟烷基和五氟苯基; 或R 1和R 3一起，R 2和R 3一起，R 5和R 7一起或R 6和R 7一起，当两个基团都在 顺式构型也可以表示2至4个碳的全氟亚烷基或o-C 6 F 4（ - ）CF 2 - ; [R <8> = F; R 4 = Cl或Br; 氟烯烃中没有一个同时含有Cl和Br; 可以选择R 1，R 2，R 3，R 4，R 5，R 6和R 7为反应物或产物的产物相同的结构 。
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6.发明授权Process for disproportionating monomethylamine using zeolitic catalyst to produce dimethylamine 失效使用ZEOLITIC催化剂分解单甲基胺生产二甲基胺的方法
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公开(公告)号：EP0233035A1
公开(公告)日：1987-08-19
申请号：EP87300924.5
申请日：1987-02-03
IPC分类号： C07C17/24 , C07C25/13 , C07C25/18 , C07C25/22 , C07D213/61
CPC分类号： C07C17/202 , C07C17/37 , C07D213/61
摘要： Catalytic transhalogenation of haloaromatics according to the equation:
wherein
when C z is a benzene derivative,
a+b=5; e=0; c+d=5; z=6;
when C z is a pyridine derivative,
a+b=4; e=1; c+d=4; z=5;
when C z is a naphthalene derivative,
a+b=7; e=0; c+d=7; z=10; and
when C z is a biphenyl derivative,
a+b=9; e=0; c+d=9; z=12;
Li and L 2 , alike or different, are selected from F, Cl, Br,
H, CN, C n F 2n+1 , and C 6 F 5 ;
X is Cl, Br, or I when C z is a benzene derivative; and n is 1 to 12摘要翻译： 根据以下方程式进行卤代芳族化合物的卤化催化反应：其中当Cz为苯衍生物时，a + b = 5; E = 0; C + d = 5; Z = 6; 当Cz是吡啶衍生物时，a + b = 4; E = 1; C + d = 4; Z = 5; 当Cz是萘衍生物时，a + b = 7; E = 0; C + d = 7; Z = 10; 当Cz是联苯衍生物时，a + b = 9; E = 0; C + d = 9; Z = 12; Li和L2相同或不同，选自F，Cl，Br，H，CN，CnF2n + 1和C6F5; 当Cz是苯衍生物时，X是Cl，Br或I; 并且n是1至12
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8.发明授权Preparation of monomethylamine from ammonia and methanol using a zeolitic catalyst 失效使用ZEOLITIC催化剂从氨和甲醇制备单甲胺
公开(公告)号：EP0025693B1
公开(公告)日：1983-07-20
申请号：EP80303180.6
申请日：1980-09-10
CPC分类号： C07C209/16 , C07C211/04
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9.发明公开Process for disproportionating monomethylamine using zeolitic catalyst to produce dimethylamine 失效一种用于一甲胺的使用用于生产二甲胺的沸石催化剂进行歧化过程。
公开(公告)号：EP0026071A1
公开(公告)日：1981-04-01
申请号：EP80303181.4
申请日：1980-09-10
CPC分类号： C07C209/64
摘要： Proces for producing dimethylamine by passing monomethylamine over a crystalline aluminosilicate catalyst selected from
a) mordenite wherein the primary cation is Na, HNa having at least 2 % Na, Mg, Ca, Sr or Ba
b) ferrierite wherein the primary metal cation is Na, K, Mg, Ca, Sr or Ba
c) clinoptilolite and
d) phillipsite,
at a temperature of 250-475°C and a pressure of 7-7000 kPa, at a feed rate of 0.1-10 g of monomethylamine/g of catalyst per hour, at a monomethylamine conversion of 15-75% Selectivity is normally in excess of 80%.摘要翻译： 从...一个）丝光沸石worin主阳离子用于通过使单甲胺在结晶硅铝酸盐催化剂生产二甲胺PROCES是Na，HNA具有atleast2％钠，镁，钙，锶或钡... B）镁碱worin主要金属阳离子是Na， 钾，镁，钙，锶或Ba ... C）斜发沸石和... D）菲利普站点，...在25-475℃的温度和7-7000千帕斯卡的压力，在0.1〜10克单甲基胺的进料速率/ 克催化剂每小时，在15-75％的单甲胺的转换。 选择性通常是在过量的80％。
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