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1.发明授权
公开(公告)号：EP2013260B1
公开(公告)日：2016-04-06
申请号：EP07775690.6
申请日：2007-04-18
发明人： MARTIN, Daniel, Lee , KNIGHT, Joseph, Franklin , BARTON, Benjamin, Fredrick , SHACKELFORD, Damon, Bryan
IPC分类号： C08G63/199 , C08G63/78
CPC分类号： C08G63/199 , C08G63/78
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公开(公告)号：EP2736868A1
公开(公告)日：2014-06-04
申请号：EP12743828.1
申请日：2012-07-23
发明人： BARTON, Benjamin, Fredrick , COOK, Steven, Leroy , HOWELL, Jeff, Scott , MCMILLAN, Noah, Glenn , SHACKELFORD, Damon, Bryan , TENNANT, Brent, Alan , TURNER, Phillip, Wayne
IPC分类号： C07C29/149 , C07C67/08 , C07C67/303 , C07C31/27 , C07C69/80 , C07C69/75
CPC分类号： C07C67/08 , C07C29/149 , C07C29/80 , C07C67/303 , C07C2601/14 , Y02P20/582 , C07C69/82 , C07C69/75 , C07C31/276
摘要： Disclosed is a process for the preparation of 1,4-cyclohexanedimethanol from terephthalic acid. Terephthalic acid is esterified with (4-methylcyclohexyl)methanol and the terephthalate ester hydrogenated to 1,4-cyclohexanedimethanol in a 2-stage process. The (4-methylcyclohexyl)methanol that is formed during the hydrogenation step is recycled to the esterification reaction. After removal of the (4- methylcyclohexyl)methanol from the crude hydrogenation product, the 1,4- cyclohexanedimethanol product can be recovered and purified by a phase separation and distillation.
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3.发明公开PROCESS FOR THE PREPARATION OF 1,4-CYCLOHEXANEDIMETHANOL FROM TEREPHTHALIC ACID 有权VERFAHREN ZUR HERSTELLUNG VON 1,4-CYCLOHEXANDIMETHANOL AUSTEREPHTHALSÄURE
公开(公告)号：EP2736866A1
公开(公告)日：2014-06-04
申请号：EP12740274.1
申请日：2012-07-23
发明人： BARTON, Benjamin, Fredrick , COOK, Steven, Leroy , HOWELL, Jeff, Soctt , MCMILLAN, Noah, Glenn , SHACKELFORD, Damon, Bryan , TENNANT, Brent, Alan , TURNER, Phillip, Wayne
IPC分类号： C07C29/149 , C07C67/08 , C07C67/303 , C07C31/27 , C07C69/80 , C07C69/75
CPC分类号： C07C67/08 , C07C29/149 , C07C29/80 , C07C67/303 , C07C2601/14 , Y02P20/582 , C07C31/276 , C07C69/75 , C07C69/82
摘要： Disclosed is a process for the preparation of 1,4-cyclohexanedimethanol from terephthalic acid. Terephthalic acid is esterified with (4-methylcyclohexyl)methanol and the terephthalate ester hydrogenated to 1,4-cyclohexanedimethanol in a 2-stage process. The (4-methylcyclohexyl)methanol that is formed during the hydrogenation step is recycled to the esterification reaction. Also disclosed is a method for purifying and recovering the 1,4-cyclohexanedimethanol product.
摘要翻译： 公开了从对苯二甲酸制备1,4-环己烷二甲醇的方法。 对苯二甲酸用（4-甲基环己基）甲醇酯化，对苯二甲酸酯在2阶段过程中氢化成1,4-环己烷二甲醇。 在氢化步骤中形成的（4-甲基环己基）甲醇被再循环至酯化反应。 还公开了1,4-环己烷二甲醇产物的纯化和回收方法。
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公开(公告)号：EP1023369B1
公开(公告)日：2002-01-16
申请号：EP98953536.4
申请日：1998-10-15
发明人： EKART, Michael, Paul , PELL, Thomas, Michael, Jr. , CORNELL, David, Dunlap , SHACKELFORD, Damon, Bryan
CPC分类号： C08J11/24 , C07C67/03 , C08J2367/02 , Y02W30/706 , C07C69/82
摘要： A process for recovering suitable polyester feedstock material from recycled polyester includes the steps of depolymerizing the polyester into its component ester monomers and half-esters; separating the monomers and half-esters from other secondary materials; and mixing the component ester monomers and half-esters with additional monomers to produce a low molecular weight polyester. In a preferred embodiment of the invention the recycled polyester is contacted with a component monomer or oligomer thereof to liquefy the polyester before the polyester is depolymerized. The invention further provides an apparatus for carrying out the process. The apparatus includes a first reactor for depolymerizing the recycled polyester, a separator for separating ester monomeric components and half-esters from secondary materials produced in the first reactor, and a second reactor for producing a low molecular weight polyester from the liquefied separator products.
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5.发明授权
公开(公告)号：EP1940908B1
公开(公告)日：2010-11-03
申请号：EP06827057.8
申请日：2006-10-27
发明人： CRAWFORD, Emmett, Dudley , PECORINI, Thomas, Joseph , MCWILLIAMS, Douglas, Stephens , PORTER, David, Scott , CONNELL, Gary, Wayne , GERMROTH, Ted, Calvin , BARTON, Benjamin, Fredrick , SHACKELFORD, Damon, Bryan
IPC分类号： C08G63/183 , C08L67/02 , C08J5/18 , C08K5/00 , C08K5/524
CPC分类号： C08G63/183 , C08G63/199 , C08G63/82 , C08G63/85 , C08K5/521 , C08L67/02 , C08L101/00
摘要： Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1 ,3- cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.
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6.发明公开PROCESS FOR THE PREPARATION OF COPOLYESTERS BASED ON 2,2,4,4-TETRAMETHYL-1,3-CYCLOBUTANEDIOL AND 1,4-CYCLOHEXANDIMETHANOL 有权用于生产ON 2,2,4,4-四甲基-1,3-环丁二醇和1,4-环己烷二甲醇的共聚酯基于
公开(公告)号：EP2152777A1
公开(公告)日：2010-02-17
申请号：EP08767590.6
申请日：2008-05-06
IPC分类号： C08G63/78
CPC分类号： C08G63/199 , C08G63/78 , C08G63/85
摘要： Disclosed is a process for the preparation of high molecular weight, thermoplastic copolyesters by reacting a diester composition comprising a dialkyl ester of terephthalic acid with a diol composition comprising a first diol component comprising 2,2,4,4-tetramethyl-l,3-cyclobutanediol and a second diol component comprising 1,4-cyclohexanedimethanol. The diester composition can be reacted with the first diol component to produce a polyester oligomer that can be reacted further with the second diol component to produce a modified polyester oligomer. The modified polyester oligomer can then be heated to form a copolyester. The process reduces the precipitation of polyd,4- cyclohexylene dimethylene) terephthalate in the reaction mixture.
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7.发明公开POLYESTER COMPOSITIONS WHICH COMPRISE CYCLOBUTANEDIOL AND AT LEAST ONE PHOSPHORUS COMPOUND 审中-公开聚酯组合物及丁烷至少一个磷连接包
公开(公告)号：EP1940953A1
公开(公告)日：2008-07-09
申请号：EP06836589.9
申请日：2006-10-27
发明人： GERMROTH, Ted, Calvin , CONNELL, Gary, Wayne , CRAWFORD, Emmett, Dudley , PECORINI, Thomas, Joseph , MCWILLIAMS, Douglas, Stephens , BARTON, Benjamin, Fredrick , SHACKELFORD, Damon, Bryan
CPC分类号： C08G63/00
摘要： Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2 ,4,4-tetramethyl-1,3- cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one phosphorus compound, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %; wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25ºC.
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公开(公告)号：EP1940910A2
公开(公告)日：2008-07-09
申请号：EP06827056.0
申请日：2006-10-27
发明人： CRAWFORD, Emmett, Dudley , PORTER, David, Scott , CONNELL, Gary, Wayne , GERMROTH, Ted, Calvin , BARTON, Benjamin, Fredrick , SHACKELFORD, Damon, Bryan
CPC分类号： C08G63/00
摘要： Described are polyester compositions comprising (a) a dicarboxylicacidcomponent comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; minimal amounts of 2,2,4 ,4-tetramethyl-1 ,3-cyclobutanediol residues; ethylene glycol, and optionally, cyclohexanedimethanol residues.
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9.发明授权PROCESS FOR THE PREPARATION OF 1,4-CYCLOHEXANEDIMETHANOL FROM TEREPHTHALIC ACID 有权用于生产1,4-环己烷OFF对苯二甲酸
公开(公告)号：EP2736866B1
公开(公告)日：2016-08-17
申请号：EP12740274.1
申请日：2012-07-23
发明人： BARTON, Benjamin, Fredrick , COOK, Steven, Leroy , HOWELL, Jeff, Soctt , MCMILLAN, Noah, Glenn , SHACKELFORD, Damon, Bryan , TENNANT, Brent, Alan , TURNER, Phillip, Wayne
IPC分类号： C07C29/149 , C07C67/08 , C07C67/303 , C07C31/27 , C07C69/80 , C07C69/75
CPC分类号： C07C67/08 , C07C29/149 , C07C29/80 , C07C67/303 , C07C2601/14 , Y02P20/582 , C07C31/276 , C07C69/75 , C07C69/82
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公开(公告)号：EP2414426B1
公开(公告)日：2014-12-10
申请号：EP09788747.5
申请日：2009-04-01
发明人： BARTON, Benjamin Frederick , TREECE, Lanny Calvin , ROBINETTE, Lisa Marie , SHACKELFORD, Damon, Bryan
CPC分类号： C08G63/199 , C08G63/82 , C08G63/87
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