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1.发明公开NOVEL BIS(PHENOLIC-AMINE)QUINONE COMPOUNDS AND POLYOLEFIN COMPOSITIONS STABILIZED THEREWITH 失效BIS（酚醛氨基）-Chinon衍生物，因此稳定的聚烯烃。
公开(公告)号：EP0633876A1
公开(公告)日：1995-01-18
申请号：EP93908535.0
申请日：1993-03-19
CPC分类号： C07C235/34 , C08K5/20 , Y10T428/31692 , C08L23/02
摘要： Disclosed is a class of bis(phenolic-amine)quinone compounds which are useful as stabilizers for polyolefins. The bis(phenolic-amine)quinone compounds inhibit oxidative degradation of polyolefins which is attributable to heat and/or ultraviolet light and is promoted or accelerated by metals, e.g., copper, in contact with the polyolefin. The compounds also exhibit excellent thermal stability.
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2.发明公开
公开(公告)号：EP0684946A1
公开(公告)日：1995-12-06
申请号：EP94910157.0
申请日：1994-02-14
CPC分类号： C07D263/57
摘要： Disclosed is an improved process for the preparation of 4,4'-bis(2-benzoxazolyl)stilbene compounds by the reaction of 4,4'-stilbenedicarboxylic acid with 2-aminophenol compounds in the presence of a tin or titanium catalyst and certain solvents.
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3.发明授权Process for the preparation of esters of stilbenedicarbonic acid and process for the preparation of p-(chloromethyl)-benzoic acid 失效一种制备的二苯乙烯二羧酸和过程酯的制备对 - （氯甲基）苯甲酸过程
公开(公告)号：EP0813515B1
公开(公告)日：2000-06-28
申请号：EP96906610.9
申请日：1996-02-23
IPC分类号： C07C67/343 , C07C69/76
CPC分类号： C07C67/343 , C07C69/76
摘要： Disclosed is a process for the preparation of 4,4'-stilbenedicarboxylate esters by a 3-step process utilizing p-toluic acid, an alkyl p-formylbenzoate and a trialkyl phosphite. The steps comprise: (1) preparing p-(chloromethyl)benzoic acid by chlorinating p-toluic acid with sulfuryl chloride in the presence of a free radical initiator and chlorobenzene or dichlorobenzene; (2) contacting the p-(chloromethyl)benzoic acid of step (1) with a trialkyl phosphite to obtain a phosphonate compound; and (3) contacting the phosphonate ester compound of step (2) with an alkyl p-formylbenzoate in the presence of an alkali metal alkoxide and an inert solvent to obtain the dialkyl 4,4'-stilbenedicarboxylate.
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公开(公告)号：EP0813516B1
公开(公告)日：1999-12-01
申请号：EP96908508.3
申请日：1996-02-23
IPC分类号： C07C67/343 , C07C69/76
CPC分类号： C07C67/343 , C07C69/76
摘要： Disclosed is a process for the preparation of 4,4'-stilbenedicarboxylate esters by a 4-step process starting with an alkyl p-formylbenzoate and utilizing intermediate phosphite and phosphonate compounds. The steps comprise: (1) preparing an alkyl p-(hydroxymethyl)benzoate by hydrogenating an alkyl p-formylbenzoate; (2) contacting the alkyl p-(hydroxymethyl)benzoate of step (1) with a trialkyl phosphite to obtain a phosphite ester compound having formula (IV); (3) contacting the phosphite ester of step (2) with a catalytic amount of iodine to rearrange the phosphite ester to the corresponding phosphonate ester; and (4) contacting the phosphonate ester compound of step (3) with an alkyl p-formylbenzoate in the presence of an alkali metal alkoxide and an inert solvent to obtain the dialkyl 4,4'-stilbenedicarboxylate.
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公开(公告)号：EP0684946B1
公开(公告)日：1997-04-23
申请号：EP94910157.0
申请日：1994-02-14
IPC分类号： C07D263/64
CPC分类号： C07D263/57
摘要： Disclosed is an improved process for the preparation of 4,4'-bis(2-benzoxazolyl)stilbene compounds by the reaction of 4,4'-stilbenedicarboxylic acid with 2-aminophenol compounds in the presence of a tin or titanium catalyst and certain solvents.
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6.发明公开POLYMERS CONTAINING OPTICAL BRIGHTENER COMPOUNDS COPOLYMERIZED THEREIN AND METHODS OF MAKING AND USING THEREFOR 审中-公开聚合物具有聚合光学增白剂CONTAIN PROCESS FOR它们的使用和
公开(公告)号：EP1075497A1
公开(公告)日：2001-02-14
申请号：EP99918661.2
申请日：1999-04-16
发明人： WANG, Richard, Hsu-Shien , KRUTAK, James, John, Sr. , SHARMA, Mahendra, Kumar , JACKSON, Barbara, Crawford
IPC分类号： C08G63/685 , C08G63/688 , C08G69/00 , C08G69/44
CPC分类号： C08G69/44 , C08G63/6856 , C08G63/6886 , C08K5/0041 , C08L67/00
摘要： The invention relates to a polymer prepared from the repeat units of residues of a monomer of at least one dicarboxylic acid or ester; a monomer comprising a diol, diamine or a mixture thereof; a monomer comprising at least one sulfonate group and at least one polyester reactive group, and a monomer comprising an optical brightener agent having at least one polyester reactive group. The invention further relates to a method for preparing a polymer. The invention further relates to a method of marking an article or composition with the polymer. The invention further relates to a method for detecting and separating an article contacted with the polymer. The invention further relates to an article or composition contacted with the polymer. The invention further relates to a method for enhancing the optical brightness of an article or composition, by contacting the article or composition with the polymer.
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7.发明授权NOVEL BIS(PHENOLIC-AMINE)QUINONE COMPOUNDS AND POLYOLEFIN COMPOSITIONS STABILIZED THEREWITH 失效BIS（酚 - 氨基）-Chinon衍生物，因此稳定的聚烯烃
公开(公告)号：EP0633876B1
公开(公告)日：1997-06-18
申请号：EP93908535.3
申请日：1993-03-19
IPC分类号： C07C235/34 , C07C235/36 , C08K5/20 , C08L23/02
CPC分类号： C07C235/34 , C08K5/20 , Y10T428/31692 , C08L23/02
摘要： Disclosed is a class of bis(phenolic-amine)quinone compounds which are useful as stabilizers for polyolefins. The bis(phenolic-amine)quinone compounds inhibit oxidative degradation of polyolefins which is attributable to heat and/or ultraviolet light and is promoted or accelerated by metals, e.g., copper, in contact with the polyolefin. The compounds also exhibit excellent thermal stability.
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