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公开(公告)号：EP3090027A4
公开(公告)日：2017-05-17
申请号：EP15733279
申请日：2015-01-02
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY , ROTH STEVEN D , HATCHER ERIC
CPC classification number: C08K5/11 , C07C67/08 , C07C69/78 , C08G63/12 , C08G63/20 , C08K5/0016 , C09J7/0278 , C09J7/245 , C09J11/06 , C09J2201/606 , C09J2203/334 , C09J2205/106 , C09J2427/006 , C09K3/1012 , C08L27/06
Abstract: Polyester plasticizer compositions for adhesives, caulk, sealants, vinyl and other polymeric compositions comprising low molecular weight oligomeric dibenzoates prepared by end-capping a polyester plasticizer, having alternating units of glycols or diols and dibasic acids, with benzoic acid. Methods for preparing oligomeric dibenzoates include steps to reduce or eliminate residual hydroxyl content and improve plasticizer performance by adding acetic anhydride are also disclosed. Propylene glycol adipate and propylene glycol succinate polyesters with benzoic acid end-caps are particularly useful, as are hybrid benzoate/acetate end-capped polyesters formed in the process with acetic anhydride. Caulks, adhesives, sealants, and vinyl compositions comprising the oligomeric end-capped polyesters of the invention are also contemplated.
Abstract translation: 用于粘合剂，填缝剂，密封剂，乙烯基和其它聚合物组合物的聚酯增塑剂组合物，其包含通过用具有交替单元的二醇或二醇和二元酸与苯甲酸封端的聚酯增塑剂制备的低分子量低聚二苯甲酸酯。 还公开了制备低聚二苯甲酸酯的方法，包括通过加入乙酸酐降低或消除残余羟基含量并提高增塑剂性能的步骤。 己二酸丙二醇酯和具有苯甲酸端帽的丙二醇琥珀酸酯聚酯是特别有用的，以及在该方法中用乙酸酐形成的混合苯甲酸酯/乙酸酯封端的聚酯。 还考虑了包含本发明的低聚封端聚酯的填缝剂，粘合剂，密封剂和乙烯基组合物。
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2.发明公开
公开(公告)号：EP2970600A4
公开(公告)日：2016-10-19
申请号：EP14764766
申请日：2014-03-14
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY , HANES REBECCA
CPC classification number: C08K5/103 , C08J3/18 , C08J2300/00 , C08K5/101 , C08K2201/014 , C08L27/06
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公开(公告)号：EP3197948A4
公开(公告)日：2018-05-09
申请号：EP15844357
申请日：2015-09-25
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY , ROTH STEVEN D , ANDREWS JERRY
IPC: C08K5/101 , C08K5/00 , C08L23/08 , C08L27/06 , C08L31/04 , C08L33/00 , C09J11/06 , C09J123/08 , C09J131/04 , C09J133/08
CPC classification number: C08K5/101 , C08K5/0016 , C08K2201/019 , C09J11/06 , C09J123/0853 , C09J131/04 , C09J2205/102 , C09J2423/04 , C09J2431/00 , C08L27/06 , C08L33/00 , C08L31/04 , C08L23/0853
Abstract: Unique 3-PPB monobenzoate analogs useful as plasticizers in polymeric dispersions, such as plastisols, melt compounds, and adhesives among other applications. The analogs are structurally similar to and/or derived from 3-phenylpropyl benzoate and heretofore were not known for use in industrial applications, particularly not as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate analogs include, among other things, excellent solvating properties and rheology, low viscosity and significantly improved viscosity over time, comparable or improved Tg suppression, set and open times, as well as health, safety and environmental advantages, over traditional plasticizers.
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Patent Agency Ranking4.发明公开MONOBENZOATE USEFUL AS A PLASTICIZER IN PLASTISOL COMPOSITIONS 有权ALS WEICHMACHER在PLASTISOLZUSAMMENSETZUNGEN VERWENDBARES MONOBENZOAT
公开(公告)号：EP2814878A4
公开(公告)日：2015-07-29
申请号：EP13748539
申请日：2013-02-14
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY
CPC classification number: C08K5/101 , C08K5/0008 , C08K5/0016 , C08K5/12 , C08L91/00 , C09D7/1233 , C09D7/63 , C09D11/00 , C09J131/04 , C08L27/06 , C08L33/06
Abstract: A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as adhesives, comprising 3-phenyl propyl benzoate, a monobenzoate ester used as a flavor and fragrance additive, but not heretofore utilized as a plasticizer for polymeric dispersions, such as adhesives, caulks and sealants. The inventive monobenzoate provides a suitable non-phthalate, lower VOC alternative plasticizer that is compatible with a wide variety of polymers. Advantages rendered by the use of the inventive monobenzoate include, among other things, excellent viscosity response, low viscosity, viscosity stability, improved rheology, good film formation and comparable or better adhesion, peel strength, set time, open time, chalk point and MFFT, compared with that achieved by traditional plasticizers. The inventive monobenzoate also has an excellent health, safety and environmental profile and provides a viable alternative for adhesives used in food contact applications, such as packaging, where migratory concerns are an issue.
Abstract translation: 可用作聚合物分散体中的增塑剂的独特的单苯甲酸酯，例如粘合剂，其包含苯甲酸3-苯基丙酯，用作调味剂和香料添加剂的单苯甲酸酯，但迄今未被用作聚合物分散体的增塑剂，例如粘合剂，填缝剂和 密封胶。 本发明的单苯甲酸酯提供了与多种聚合物相容的合适的非邻苯二甲酸酯，较低的VOC替代增塑剂。 通过使用本发明的单苯甲酸酯提供的优点包括优异的粘度响应，低粘度，粘度稳定性，改进的流变性，良好的成膜性以及相当或更好的粘附性，剥离强度，凝固时间，开放时间，粉笔点和MFFT ，与传统增塑剂相比。 本发明的单苯甲酸盐也具有优异的健康，安全性和环境特性，并为用于食品接触应用的粘合剂（例如包装）提供可行的替代方案，其中迁移问题是一个问题。
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公开(公告)号：EP2658728A4
公开(公告)日：2014-09-10
申请号：EP11852497
申请日：2011-12-28
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY
IPC: B60C1/00 , C08K5/00 , C08K5/053 , C08K5/06 , C08K5/103 , C08K5/12 , C09D7/12 , C09D11/02 , C09J11/06
CPC classification number: C08K5/12 , C08K5/0016 , C08K5/06 , C08K5/10 , C08K5/103 , C08K2201/014 , C09D7/1233 , C09D7/63 , C09D11/03 , C09J11/06
Abstract: Plasticizer blends comprise a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1,2-propylene glycol dibenzoate, in specified ratios, useful in combination with a multitude of thermoplastic polymers, thermosetting polymers, and elastomeric polymers and numerous applications, including but not limited to plastisols, adhesives, sealants, caulks, architectural coatings, industrial coatings, OEM coatings, inks, overprint varnishes, polishes, and the like. The advantages rendered by the use of the triblend depend on the type of polymer and application in which it is utilized and include among other advantages higher solvating power and lower processing time, low VOC's, reduced plasticizer freeze point, improved gelation and fusion characteristics, higher tensile strength, superior stain and extraction resistance, and improved rheology over traditional diblends of diethylene glycol dibenzoate and dipropylene glycol dibenzoate.
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6.发明公开MONOBENZOATE USEFUL AS A PLASTICIZER/COALESCENT IN POLYMERIC DISPERSIONS 审中-公开MONOBENZOAT ALS WEICHMACHER / KOALESZENZMITTEL IN POLYMERDISPERSIONEN
公开(公告)号：EP2841512A4
公开(公告)日：2016-03-09
申请号：EP13749392
申请日：2013-02-14
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY
CPC classification number: C08K5/101 , C08K5/0008 , C08K5/0016 , C08K5/12 , C08L91/00 , C09D7/1233 , C09D7/63 , C09D11/00 , C09J131/04 , C08L27/06 , C08L33/06
Abstract: A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as adhesives, comprising 3-phenyl propyl benzoate, a monobenzoate ester used as a flavor and fragrance additive, but not heretofore utilized as a plasticizer for polymeric dispersions, such as adhesives, caulks and sealants. The inventive monobenzoate provides a suitable non-phthalate, lower VOC alternative plasticizer that is compatible with a wide variety of polymers. Advantages rendered by the use of the inventive monobenzoate include, among other things, excellent viscosity response, low viscosity, viscosity stability, improved rheology, good film formation and comparable or better adhesion, peel strength, set time, open time, chalk point and MFFT, compared with that achieved by traditional plasticizers. The inventive monobenzoate also has an excellent health, safety and environmental profile and provides a viable alternative for adhesives used in food contact applications, such as packaging, where migratory concerns are an issue.
Abstract translation: 可用作聚合物分散体中的增塑剂的独特的单苯甲酸酯，例如粘合剂，其包含苯甲酸3-苯基丙酯，用作调味剂和香料添加剂的单苯甲酸酯，但迄今未被用作聚合物分散体的增塑剂，例如粘合剂，填缝剂和 密封胶。 本发明的单苯甲酸酯提供了与多种聚合物相容的合适的非邻苯二甲酸酯，较低的VOC替代增塑剂。 通过使用本发明的单苯甲酸酯提供的优点包括优异的粘度响应，低粘度，粘度稳定性，改进的流变性，良好的成膜性以及相当或更好的粘附性，剥离强度，凝固时间，开放时间，粉笔点和MFFT ，与传统增塑剂相比。 本发明的单苯甲酸盐也具有优异的健康，安全性和环境特性，并为用于食品接触应用的粘合剂（例如包装）提供可行的替代方案，其中迁移问题是一个问题。
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公开(公告)号：EP2814894A4
公开(公告)日：2016-03-09
申请号：EP13748864
申请日：2013-02-14
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY
CPC classification number: C08K5/101 , C08K5/0008 , C08K5/0016 , C08K5/12 , C08L91/00 , C09D7/1233 , C09D7/63 , C09D11/00 , C09J131/04 , C08L27/06 , C08L33/06
Abstract: A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as adhesives, comprising 3-phenyl propyl benzoate, a monobenzoate ester used as a flavor and fragrance additive, but not heretofore utilized as a plasticizer for polymeric dispersions, such as adhesives, caulks and sealants. The inventive monobenzoate provides a suitable non-phthalate, lower VOC alternative plasticizer that is compatible with a wide variety of polymers. Advantages rendered by the use of the inventive monobenzoate include, among other things, excellent viscosity response, low viscosity, viscosity stability, improved rheology, good film formation and comparable or better adhesion, peel strength, set time, open time, chalk point and MFFT, compared with that achieved by traditional plasticizers. The inventive monobenzoate also has an excellent health, safety and environmental profile and provides a viable alternative for adhesives used in food contact applications, such as packaging, where migratory concerns are an issue.
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8.发明公开NEW DIBENZOATE PLASTICIZER/COALESCENT BLENDS FOR LOW VOC COATINGS 有权NEW DIBENZOATWEICHMACHER- / KOALESZENZMENTELMISCHUNGEN用于低挥发性有机化合物涂层
公开(公告)号：EP2658911A4
公开(公告)日：2015-01-21
申请号：EP11853182
申请日：2011-12-28
Applicant: EMERALD KALAMA CHEMICAL LLC
Inventor： ARENDT WILLIAM D , MCBRIDE EMILY
CPC classification number: C08K5/12 , C08K5/0016 , C08K5/06 , C08K5/10 , C08K5/103 , C08K2201/014 , C09D7/1233 , C09D7/63 , C09D11/03 , C09J11/06
Abstract: Plasticizer blends comprise a triblend of diethylene glycol dibenzoate, dipropylene glycol dibenzoate, and 1,2-propylene glycol dibenzoate, in specified ratios, useful in combination with a multitude of thermoplastic polymers, thermosetting polymers, and elastomeric polymers and numerous applications, including but not limited to plastisols, adhesives, sealants, caulks, architectural coatings, industrial coatings, OEM coatings, inks, overprint varnishes, polishes, and the like. The advantages rendered by the use of the triblend depend on the type of polymer and application in which it is utilized and include among other advantages higher solvating power and lower processing time, low VOC's, reduced plasticizer freeze point, improved gelation and fusion characteristics, higher tensile strength, superior stain and extraction resistance, and improved rheology over traditional diblends of diethylene glycol dibenzoate and dipropylene glycol dibenzoate.
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