摘要:
Process for the contemporaneous production of fuels and lubricating bases from synthetic paraffinic mixtures, which includes a hydrocracking step in the presence of a solid bi-functional catalyst comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm. to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of between 0.05 and 5% by weight with respect to the total weight of the catalyst.
摘要:
A solid catalyst for hydrotreating processes of hydrocarbons, comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of be tween 0.05 and 5% by weight with respect to the total weight of the catalyst. Said catalyst is advantageously used in hydrocracking processes of hydrocarbon mixtures, for obtaining fuels and lubricating bases.
摘要:
Amorphous porous solid of an acidic nature, with a controlled pore size, essentially consisting of a mixed oxide of silicon, aluminum and phosphorous, having a surface area of at least 200 m2/g, which can be used as a catalyst or active carrier of a catalyst for various industrial processes, such as, for example, alkylation, isomerization, hydro-dehydrogenation processes, with an improved activity and selectivity with respect to the traditional amorphous silica-alumina gels.
摘要:
The present invention relates to a catalytic composition comprising at least one lanthanide, at least one metal be longing to group VIII B and a zeolite selected from zeolite Y and zeolite Y modified by the partial or total substitution of Si with Ti or Ge and/or the partial or total substitution of the aluminum with Fe, Ga or B. These catalytic compositions can be used in conversion processes of aromatics into linear alkanes.
摘要:
The present invention relates to solid base catalysts consisting of an amorphous material obtained from a silica or alumina gel containing an alkaline, earth-alkaline or transition metal (M), characterized by a molar ratio between metal (M) and Si or Al ranging from 30:1 to 0.0001:1, a surface area ranging from 100 to 600 m2/g, an overall pore volume ranging from 0.1 to 1.1 ml/g, an average channel diameter ranging from 30 to 150 Å and a density of the base sites ranging from 10 to 900 νmol/g. Said catalysts can be conveniently used in base catalysis reactions.
摘要:
The present invention relates to a process for the separation of gases which comprises putting a mixture of gases in contact with a zeolite of the ESV type to obtain the selective adsorption of at least one of the gases forming the gaseous mixture. The present invention also relates to particular zeolitic compositions suitable as adsorbents.