公开(公告)号：EP1902116A1

公开(公告)日：2008-03-26

申请号：EP06762434.6

申请日：2006-07-03

申请人： ENI S.p.A. ,  Enitechnologie S.p.A.

发明人： GIARDINO, Roberto ,  CALEMMA, Vincenzo ,  CORNARO, Ugo

IPC分类号： C10G45/62 ,  B01J23/40

CPC分类号： B01J35/1061 ,  B01J21/12 ,  B01J23/40 ,  B01J29/7469 ,  B01J29/7669 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/307 ,  C10G2300/4018 ,  C10G2400/04

摘要： A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, se- lected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.

公开(公告)号：EP1641899B1

公开(公告)日：2013-01-09

申请号：EP04740379.5

申请日：2004-06-28

申请人： ENI S.p.A. ,  Institut Français du Pétrole ,  ENITECNOLOGIE S.p.A.

发明人： CALEMMA, Vincenzo ,  FLEGO, Cristina ,  CARLUCCIO, Luciano, Cosimo ,  PARKER, Wallace ,  GIARDINO, Roberto ,  FARACI, Giovanni

IPC分类号： C10G47/14

CPC分类号： C10G47/14

公开(公告)号：EP1902116B1

公开(公告)日：2010-05-05

申请号：EP06762434.6

申请日：2006-07-03

申请人： ENI S.p.A.

发明人： GIARDINO, Roberto ,  CALEMMA, Vincenzo ,  CORNARO, Ugo

IPC分类号： C10G45/62 ,  B01J23/40

CPC分类号： B01J35/1061 ,  B01J21/12 ,  B01J23/40 ,  B01J29/7469 ,  B01J29/7669 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/307 ,  C10G2300/4018 ,  C10G2400/04

摘要： A process is described for improving the quality as a fuel of hydrotreated hydrocarbon blends by reaction with hydrogen in the presence of a bifunctional catalytic system comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re, and a silico-aluminate of an acidic nature, se- lected from a micro-mesoporous silico-alumina and a zeolite belonging to the MTW family. The process of the invention produces an increase in the cetane index and a decrease in the density and T95.

公开(公告)号：EP1641561A1

公开(公告)日：2006-04-05

申请号：EP04740340.7

申请日：2004-06-25

申请人： ENI S.p.A. ,  ENITECNOLOGIE S.p.A.

发明人： CALEMMA, Vincenzo ,  FLEGO, Cristina ,  CARLUCCIO, Luciano, Cosimo ,  PARKER, Wallace ,  GIARDINO, Roberto ,  FARACI, Giovanni

IPC分类号： B01J27/16 ,  B01J27/182 ,  B01J35/10 ,  B01J37/03 ,  C10G49/06 ,  C10G47/14

CPC分类号： B01J37/036 ,  B01J27/16 ,  B01J27/182 ,  B01J27/1856 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  C10G2400/06 ,  C10G2400/10

摘要： A solid catalyst for hydrotreating processes of hydrocarbons, comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of be tween 0.05 and 5% by weight with respect to the total weight of the catalyst. Said catalyst is advantageously used in hydrocracking processes of hydrocarbon mixtures, for obtaining fuels and lubricating bases.

公开(公告)号：EP1641899A1

公开(公告)日：2006-04-05

申请号：EP04740379.5

申请日：2004-06-28

申请人： ENI S.p.A. ,  Institut Français du Pétrole ,  ENITECNOLOGIE S.p.A.

发明人： CALEMMA, Vincenzo ,  FLEGO, Cristina ,  CARLUCCIO, Luciano, Cosimo ,  PARKER, Wallace ,  GIARDINO, Roberto ,  FARACI, Giovanni

IPC分类号： C10G47/14

CPC分类号： C10G47/14

摘要： Process for the contemporaneous production of fuels and lubricating bases from synthetic paraffinic mixtures, which includes a hydrocracking step in the presence of a solid bi-functional catalyst comprising: (A) a support of an acidic nature consisting of a catalytically active porous solid, including silicon, aluminum, phosphorus and oxygen bonded to one another in such a way as to form a mixed amorphous solid characterized by an Si/Al atomic ratio of between 15 and 250, a P/Al ratio of at least 0.1, but lower than 5, a total pore volume ranging from 0.5 to 2.0 ml/g, with an average pore diameter ranging from 3 nm. to 40 nm, and a specific surface area ranging from 200 to 1000 M2/g; (B) at least one metal with a hydro-dehydrogenating activity selected from groups 6 to 10 of the periodic table of elements, dispersed on said support (A) in an amount of between 0.05 and 5% by weight with respect to the total weight of the catalyst.

公开(公告)号：EP1641561B1

公开(公告)日：2013-01-09

申请号：EP04740340.7

申请日：2004-06-25

申请人： ENI S.p.A.

发明人： CALEMMA, Vincenzo ,  FLEGO, Cristina ,  CARLUCCIO, Luciano, Cosimo ,  PARKER, Wallace ,  GIARDINO, Roberto ,  FARACI, Giovanni

IPC分类号： C10G49/06 ,  C10G47/14 ,  B01J27/16 ,  B01J27/182 ,  B01J35/10 ,  B01J37/03

CPC分类号： B01J37/036 ,  B01J27/16 ,  B01J27/182 ,  B01J27/1856 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  C10G2400/06 ,  C10G2400/10

公开(公告)号：EP1404783B1

公开(公告)日：2005-01-26

申请号：EP02767160.1

申请日：2002-06-26

申请人： ENI S.p.A. ,  ENITECNOLOGIE S.p.A. ,  Institut Français du Pétrole

发明人： CALEMMA, Vincenzo ,  GUANZIROLI, Silvia ,  PAVONI, Silvia ,  GIARDINO, Roberto

IPC分类号： C10G65/12

CPC分类号： C10G65/12 ,  Y10S208/95

公开(公告)号：EP1404783A1

公开(公告)日：2004-04-07

申请号：EP02767160.1

申请日：2002-06-26

申请人： ENI S.p.A. ,  ENITECNOLOGIE S.p.A. ,  Institut Français du Pétrole

发明人： CALEMMA, Vincenzo ,  GUANZIROLI, Silvia ,  PAVONI, Silvia ,  GIARDINO, Roberto

IPC分类号： C10G65/12

CPC分类号： C10G65/12 ,  Y10S208/95

摘要： A process with an increased efficiency for the preparation of middle distillates with excellent properties at low temperatures and substantially without oxygenated organic compounds, starting from a synthetic mixture of hydrocarbons at least partly waxy, containing a fraction of alcohols, comprising the separation of the mixture into a low-boiling fraction and a high-boiling fraction; the subsequent hydrogenation of the low-boiling fraction under such conditions as to avoid any substantial variation in its average molecular weight; the joining of at least a part of the hydrogenated fraction with said high-boiling fraction, and the subsequent catalytic hydrocracking treatment of the mixture of hydrocarbons thug formed, to obtain a substantial conversion of the waxy part into middle distillate.