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    SYSTEM AND PROCESS FOR PRODUCING LINEAR ALPHA OLEFINS
    3.
    发明公开
    SYSTEM AND PROCESS FOR PRODUCING LINEAR ALPHA OLEFINS 审中-公开
    系统和方法用于生产直α-烯烃

    公开(公告)号：EP2414313A2

    公开(公告)日：2012-02-08

    申请号：EP09742972.4

    申请日：2009-04-02

    申请人： Lummus Technology Inc.

    发明人： GARTSIDE, Robert, J. ,  GREENE, Marvin, I. ,  JONES, Quincy, J. ,  CHELLPPANNAIR, Thulusidas

    IPC分类号： C07C11/107 ,  B01D3/14 ,  B01D3/32

    CPC分类号： C07C11/107 ,  B01D3/146 ,  C07C5/2506 ,  C07C6/04 ,  C07C11/08

    摘要： Processes and systems for producing linear alpha olefins are described herein. One embodiment is a process comprising: a) separating a mixed butene stream comprising 1 -butene and 2-butene into an overhead 1 -butene stream and a bottoms 2-butene stream in a butene distillation column, a portion of the bottoms 2-butene stream being separated to form a butene reboiler stream that is heated and vaporized in a reboiler and returned to the butene distillation column, (b) subjecting at least a portion of the overhead 1 -butene stream from (a) to catalytic metathesis to produce an effluent including 3-hexene, (c) isomerizing 3-hexene from (b) to produce a mixed hexene stream comprising 1 -hexene, 2-hexene and 3-hexene, (d) separating the mixed hexene stream in a hexene fractionation tower to form a 1 -hexene vapor overhead stream that is condensed in a cooler and a bottoms stream comprising 2-hexene and 3-hexene, and (e) using heat obtained by condensing the 1 -hexene vapor overhead stream of (d) to heat the butene reboiler stream of (a). Another embodiment is a superfractionation process. Corresponding systems are also disclosed.

    VERFAHREN ZUR HERSTELLUNG VON 1-BUTEN
    5.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON 1-BUTEN 有权
    用于生产1-丁烯

    公开(公告)号：EP1682468B1

    公开(公告)日：2009-07-15

    申请号：EP04790913.0

    申请日：2004-10-27

    申请人： BASF SE

    发明人： SCHINDLER, Götz-Peter ,  BRODHAGEN, Andreas ,  JOHANN, Thorsten ,  HILL, Thomas ,  SIGL, Marcus ,  BENFER, Regina

    IPC分类号： C07C5/333 ,  C07C5/25 ,  C07C5/05 ,  C07C7/08

    CPC分类号： C07C5/333 ,  C07C5/05 ,  C07C5/2506 ,  C07C7/08 ,  C07C11/08

    摘要： The invention relates to a method for producing 1-butene by feeding an n-butane containing feed gas flow (a) to a dehydration zone and dehydrating the n-butane, thereby obtaining a product gas flow (b); removing hydrogen and low-boiling secondary constituents, thereby obtaining a C4 product gas flow (c); separating the C4 product gas flow (c) into an n-butane containing return flow and a 1-butene, 2-butene and butadiene containing flow (d2) by extractive distillation and returning the return flow to the dehydration zone; feeding the flow (d2) to a selective hydration zone and selectively hydrating butadiene to give 1-butene and/or 2-butene, thereby obtaining a 1-butene and 2-butene containing flow (4); feeding the flow (e) and a 1-butene and 2-butene containing circular flow to a distillation zone and removing a 1-butene containing value product flow, thereby leaving a 2-butene containing flow (f2); feeding the flow (f2) to an isomerization zone and isomerizing 2-butene to give 1-butene, thereby obtaining the circular flow, and returning the same to the distillation zone.

    PROCESS FOR PREPARING BICYCLO 2.2.1]HEPTANE DERIVATIVES
    6.
    发明公开
    PROCESS FOR PREPARING BICYCLO 2.2.1]HEPTANE DERIVATIVES 有权
    VERFAHREN ZUR HERSTELLUNG VON BICYCLO [2.2.1] HEPTAN-DERIVATEN

    公开(公告)号：EP1254882A4

    公开(公告)日：2005-06-01

    申请号：EP01951140

    申请日：2001-02-06

    申请人： IDEMITSU KOSAN CO

    发明人： TSUBOUCHI TOSHIYUKI ,  YOSHIDA YUKIO ,  IDO MOTOHISA ,  KATAYAMA MASAHIRO

    IPC分类号： B01J21/04 ,  C07B61/00 ,  C07C5/25 ,  C07C13/40 ,  C07C13/42

    CPC分类号： C07C5/2506 ,  C07C5/2518 ,  C07C13/40 ,  C07C13/42 ,  C07C2602/42

    摘要： A process for preparing economically and efficiently 2-methylene-3-methylbicyclo[2.2.1]heptane, 2,3-dimethylbicyclo[2.2.1]hept-2-ene, and so on, which are useful as raw materials in producing base oils for traction drive fluids to be used as lubricating oils for traction drive units, which process comprises reacting one or more C3-4 noncyclic olefins with cyclopentadiene to form one or more bicyclo[2.2.1]heptene derivatives and isomerizing the bicyclo[2.2.1]heptene derivatives in the presence of an isomerization catalyst to form one or more bicyclo[2.2.1]heptane derivatives.

    摘要翻译： 本发明涉及用于生产2-亚甲基-3-甲基双环[2,2,2]庚烷，2,3-二甲基二环己基-2,2-庚-2-烯等的经济有效的方法，其用于生产牵引驱动流体的基础油的材料 用于牵引驱动润滑油。 所述方法包括使一种或多种C 3-4无环烯烃与环戊二烯反应，并在异构化催化剂存在下异构化得到的双环哒嗪衍生物，得到一种或多种二环己烷衍生物。

    Composite product and manufacturing method thereof
    7.
    发明公开
    Composite product and manufacturing method thereof 审中-公开
    复合材料产品和工艺及其制备方法

    公开(公告)号：EP1232788A3

    公开(公告)日：2003-01-29

    申请号：EP02003048.2

    申请日：2002-02-12

    申请人： Kuraray Co., Ltd.

    发明人： Tokitoh, Yasuo, c/o Kuraray Co., Ltd.

    IPC分类号： B01J23/04 ,  B01J37/04 ,  C07C5/02 ,  C07C45/29

    CPC分类号： C07C5/2506 ,  B01J21/18 ,  B01J23/04 ,  B01J37/04 ,  C07C45/29 ,  C07C11/107 ,  C07C47/21 ,  C07C49/603

    摘要： It is an object of the present invention to provide a composite product which is easy to manufacture, and is excellent in catalytic activities and mechanical strength. The object can be achieved by a composite product obtained by heating and drying a mixture of a carrier in powder form and a metal hydroxide in powder form or in molten form. Such a composite product can be manufactured by mixing a carrier in powder form and a metal hydroxide in powder form or in molten form, heating and wetting the mixture, and drying the mixture under a gas flow or under reduced pressure. It can be preferably used as the catalyst for the isomerization reaction of an olefin or for the oxidation reaction of alcohols.

    METHOD FOR PRODUCING METHACRYLIC ACID ESTER
    8.
    发明公开
    METHOD FOR PRODUCING METHACRYLIC ACID ESTER 审中-公开
    VERFAHREN ZUR HERSTELLUNG VONMETHACRYLSÄUREESTER

    公开(公告)号：EP2960228A4

    公开(公告)日：2016-10-19

    申请号：EP14775559

    申请日：2014-03-19

    申请人： SUMITOMO CHEMICAL CO

    发明人： SEKI KOHEI ,  SUZUTA TETSUYA ,  MIURA NAOKI

    IPC分类号： C07C67/38 ,  C07C1/24 ,  C07C5/25 ,  C07C11/14 ,  C07C11/22 ,  C07C69/54

    CPC分类号： C07C67/38 ,  C07C1/2076 ,  C07C1/24 ,  C07C5/2506 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/04 ,  Y02P20/582 ,  C07C69/54 ,  C07C11/24 ,  C07C11/14

    摘要： The method for producing a methacrylic acid ester of the present invention comprises a dehydration reaction step of having acetone undergo a dehydration reaction in the presence of a dehydration reaction catalyst to obtain a reaction mixture; a propyne/propadiene separation step of separating a mixture containing propyne and propadiene as main components from the obtained reaction mixture; a propyne purification step of separating the separated mixture containing propyne and propadiene as main components into a liquid, gas, or gas-liquid mixture containing propyne as a main component, and a liquid, gas, or gas-liquid mixture containing propadiene as a main component; and a carbonylation reaction step of bringing the obtained liquid, gas, or gas-liquid mixture containing propyne as a main component into contact with carbon monoxide and an alcohol having 1 to 3 carbon atoms in the presence of a catalyst containing at least one selected from the group consisting of Group 8 metal elements, Group 9 metal elements, and Group 10 metal elements to obtain a methacrylic acid ester. According to the method of the present invention, it is possible to provide a method for producing a methacrylic acid ester, which is less likely to receive location restrictions and is also economically and industrially advantageous.

    摘要翻译： 本发明的甲基丙烯酸酯的制造方法包括在脱水反应催化剂的存在下进行脱水反应的脱水反应工序，得到反应混合物; 丙烯/丙二烯分离步骤，从得到的反应混合物中分离含有丙炔和丙二烯作为主要成分的混合物; 将以丙炔和丙二烯为主要成分的分离混合物分离成含有丙炔作为主要成分的液体，气体或气液混合物的丙炔纯化步骤，以丙二烯为主要原料的液体，气体或气液混合物 零件; 以及羰基化反应步骤，将含有丙炔作为主要成分的所得液体，气体或气液混合物与一氧化碳和具有1至3个碳原子的醇在含有至少一种选自 由8族金属元素，9族金属元素和10族金属元素组成的组，得到甲基丙烯酸酯。 根据本发明的方法，可以提供一种生产甲基丙烯酸酯的方法，其不太可能获得位置限制，并且在经济和工业上也是有利的。

    METATHESIS UNIT PRETREATMENT PROCESS WITH FORMATION OF OCTENE
    9.
    发明公开
    METATHESIS UNIT PRETREATMENT PROCESS WITH FORMATION OF OCTENE 有权
    多元烷烃预处理与OCTENE形成过程

    公开(公告)号：EP2346799A1

    公开(公告)日：2011-07-27

    申请号：EP08878190.1

    申请日：2008-11-17

    申请人： UOP LLC

    发明人： KRUPA, Steven L. ,  MEISTER, Jill M.

    IPC分类号： C07C6/04

    CPC分类号： C07C5/2506 ,  C07C2/08 ,  C07C2/14 ,  C07C6/04 ,  C07C7/163 ,  C07C11/02 ,  C07C11/06 ,  C10G2300/1092 ,  C10G2400/20 ,  C10G2400/22 ,  C07C11/08

    摘要： Disclosed is a process for integrating a butene dimerization process with a metathesis process to remove isobutene from the feed stream to the metathesis reactor. The isobutene is preferentially dimerized in the dimerization process to leave n-butenes for metathesis with ethylene. An upstream selective hydrogenation process also isomerizes 1-butenes to 2-butenes which is the preferred butene reagent in the metathesis process. A common fractionator column for the dimerization and hydrogenation processes is also described.

    摘要翻译： 公开了一种将丁烯二聚过程与复分解过程结合从而将异丁烯从进料流移除至复分解反应器的方法。 异丁烯优先在二聚过程中二聚化以使正丁烯与乙烯易位。 上游选择性加氢方法也将1-丁烯异构化成2-丁烯，其是易位过程中优选的丁烯试剂。 还描述了用于二聚和氢化过程的普通分馏塔。