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公开(公告)号:EP3485026A1
公开(公告)日:2019-05-22
申请号:EP17737817.1
申请日:2017-07-12
发明人: BÄRZ, Manfred , BEISER, Marc , BORCHERS, Georg , DERNEDDE, Mathias , DIEHL, Michael , DONG, Xiao Daniel , HABERLAND, Jürgen , JOHNSON, Michael Benjamin , LEBERT, Jochen , MATTHEWS, SR., Kirt Lyvell , NEJAKO II, Mark Edward , PFEIFER, Holger , RABE, Christian , SHANK, Ginger Marie , TARWADE, Vinod , TINSLEY, David Allen , VERKOEIJEN, Daniel
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公开(公告)号:EP3485028A1
公开(公告)日:2019-05-22
申请号:EP17742987.5
申请日:2017-07-12
发明人: BÄRZ, Manfred , BEISER, Marc , BORCHERS, Georg , CHERINKO, Stephen Robert , DERNEDDE, Mathias , DIEHL, Michael , DONG, Xiao Daniel , HABERLAND, Jürgen , JOHNSON, Michael Benjamin , KERTIS, Robert Cody , LEBERT, Jochen , LEININGER, Neil Francis , MATTHEWS, Kirt Lyvell, SR. , PFEIFER, Holger , RABE, Christian , RESOP, Shannon Elizabeth Ethier , SHANK, Ginger Marie , TARWADE, Vinod , TINSLEY, David Allen , VERKOEIJEN, Daniel
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公开(公告)号:EP3380461A1
公开(公告)日:2018-10-03
申请号:EP16802026.1
申请日:2016-11-25
发明人: HOFEN, Willi , HAAS, Thomas , WÖLL, Wolfgang , KOLBE, Bärbel , DIETZ, Hans-Christian , BRENDEL, Marc , JAEGER, Bernd , BÄRZ, Manfred , KLEIBER, Michael
IPC分类号: C07D301/12 , C07D301/32
CPC分类号: C07D301/12 , B01D3/14 , B01D2257/7022 , B01D2257/80 , B01J23/30 , B01J29/7049 , C07D301/32
摘要: In a process for the epoxidation of propene, comprising the steps of reacting propene with hydrogen peroxide, separating propene oxide and a recovered propene stream from the reaction mixture, separating propane from all or a part of the recovered propene stream in a C3 splitter column, and passing the overhead product stream of the C3 splitter column to the epoxidation step, a propane starting material with a propane fraction of from 0.002 to 0.10 is used, the epoxidation is operated to provide a propane fraction in the reaction mixture of from 0.05 to 0.20 and the C3 splitter column is operated to provide an overhead product stream which comprises a propane fraction of at least 0.04 in order to reduce the size and the energy consumption of the C3 splitter column.
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公开(公告)号:EP3380459A1
公开(公告)日:2018-10-03
申请号:EP16791559.4
申请日:2016-11-01
发明人: PASCALY, Matthias , BÄRZ, Manfred , BRENDEL, Marc , JAHN, Robert , SCHEMEL, Jürgen , DOPFER, Michael
IPC分类号: C07D301/12
摘要: In a process for the epoxidation of an olefin by continuously reacting the olefin with hydrogen peroxide in a methanol solvent on a fixed bed epoxidation catalyst comprising a titanium zeolite, the hydrogen peroxide is used as an aqueous hydrogen peroxide solution made by an anthraquinone process, the aqueous hydrogen peroxide solution is mixed with methanol to give a feed mixture and this feed mixture is filtered before being contacted with the fixed bed epoxidation catalyst.
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公开(公告)号:EP3380460A1
公开(公告)日:2018-10-03
申请号:EP16791560.2
申请日:2016-11-01
发明人: BRENDEL, Marc , BÄRZ, Manfred , KOWOLL, Johannes , BOLZ, David , HOFEN, Willi , SCHEMEL, Jürgen , JAEGER, Bernd , BREDEMEYER, Niels , KOLBE, Bärbel , ULLRICH, Norbert , DOPFER, Michael , WÖLL, Wolfgang , PORSCHA, Peter , PFENNING, Dana , BERNHARD, Maik
IPC分类号: C07D301/12 , C07D303/04
CPC分类号: C07D301/12 , C07D303/04
摘要: Propene is continuously reacted with hydrogen peroxide in a tube bundle reactor comprising a multitude of parallel reaction tubes in the presence of a titanium silicalite catalyst arranged as a fixed bed in the reaction tubes. A cooling jacket encloses the reaction tubes, which has a feed point for cooling medium near the entry of the reaction tubes,a withdrawal point for cooling medium near the end of the reaction tubes and at least one additional withdrawal point upstream of the withdrawal point near the end of the reaction tubes. Cooling medium is fed to the feed point for cooling medium, a part of the cooling medium is withdrawn at the at least one additional withdrawal point and the remainder exits at the withdrawal point near the end of the reaction tubes.
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公开(公告)号:EP3380461B1
公开(公告)日:2019-07-24
申请号:EP16802026.1
申请日:2016-11-25
发明人: HOFEN, Willi , HAAS, Thomas , WÖLL, Wolfgang , KOLBE, Bärbel , DIETZ, Hans-Christian , BRENDEL, Marc , JAEGER, Bernd , BÄRZ, Manfred , KLEIBER, Michael
IPC分类号: C07D301/12 , C07D301/32
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