公开(公告)号：EP3089941A1

公开(公告)日：2016-11-09

申请号：EP14828604.0

申请日：2014-12-17

Applicant: ExxonMobil Research and Engineering Company

Inventor： JOHNSON, Ivy D. ,  BEUTEL, Tilman W. ,  RAVIKOVITCH, Peter I. ,  DECKMAN, Harry W. ,  JOHNSON, Jack W. ,  BEECKMAN, Jean W. ,  FASSBENDER, Natalie A. ,  HRYCENKO, Nadya A. ,  SMILEY, Randy J.

IPC: C01B37/02 ,  C01B39/02 ,  C01B39/48 ,  B01J20/30 ,  B01D53/02

CPC classification number: B01J20/3078 ,  B01D53/02 ,  B01D2253/108 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/504 ,  B01J20/18 ,  B01J20/186 ,  B01J20/282 ,  B01J20/30 ,  B01J20/3085 ,  B01J29/035 ,  B01J29/70 ,  B01J2220/80 ,  B01J2229/36 ,  B01J2229/40 ,  C01B37/02 ,  C01B39/026 ,  C01B39/04 ,  C01B39/48 ,  Y02C10/08 ,  Y02P20/152

Abstract: Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Steaming the H-form DDR framework type crystals at a temperature from 426±° C. to 1100±° C. for a time period from about 30 minutes to about 48 hours can attain one or more of the following properties: a CH4 diffusivity of no more than 95% of the CH4 diffusivity of the unsteamed H-form DDR framework type crystals; an N2 BET surface area from 85% to 110% of the surface area of unsteamed H-form DDR framework type crystals; and an equilibrium CO2 sorption capacity from 80% to 105% of the equilibrium CO2 sorption capacity of unsteamed H-form DDR framework type crystals.

Abstract translation: 提供了用于合成具有改进的形态和/或改进的尺寸分布的ZSM-58晶体的方法。 通过控制合成ZSM-58晶体的条件，可以产生具有窄尺寸分布的有用尺寸的晶体。 另外，通过控制合成混合物中水含量与二氧化硅含量的比例，意外地发现可以形成具有改进形态的ZSM-58晶体。 改进的形态可以导致在晶体的各种尺寸上具有更均匀尺寸的ZSM-58晶体，这允许在晶体内更均匀的扩散。 这与常规合成的晶体形成对比，其中晶体的尺寸可以沿晶体的不同轴线变化。

公开(公告)号：EP2680940A2

公开(公告)日：2014-01-08

申请号：EP12707455.7

申请日：2012-02-27

Applicant: ExxonMobil Research and Engineering Company

Inventor： GUPTA, Ramesh ,  DECKMAN, Harry W. ,  LETA, Daniel P.

IPC: B01D53/02 ,  B01J20/32 ,  B01D53/047

CPC classification number: B01D53/047 ,  B01D53/0438 ,  B01D53/0462 ,  B01D53/0473 ,  B01D53/526 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20489 ,  B01D2253/102 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2253/306 ,  B01D2253/311 ,  B01D2253/34 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2257/102 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2257/7022 ,  B01D2259/40022 ,  B01D2259/40052 ,  B01D2259/402 ,  B01D2259/41 ,  B01J20/18 ,  B01J20/186 ,  B01J20/20 ,  B01J20/226 ,  B01J20/28016 ,  B01J20/28019 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/28078 ,  B01J20/28095 ,  B01J20/3408 ,  B01J20/3416 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/42 ,  B01J2220/46 ,  B01J2220/56 ,  C01B17/0408 ,  C01B17/167 ,  C10L3/103 ,  C10L3/104 ,  C10L3/105 ,  Y02C10/08 ,  Y02P20/152 ,  Y10T428/2991

Abstract: The present invention relates to a pressure-temperature swing adsorption process wherein gaseous components that have been adsorbed can be recovered from the adsorbent bed at elevated pressures. In particular, the present invention relates to a pressure-temperature swing adsorption process for the separation of C2+ hydrocarbons (hydrocarbons with at least 2 carbon atoms) from natural gas streams to obtain a high purity methane product stream. In more preferred embodiments of the present processes, the processes may be used to obtain multiple, high purity hydrocarbon product streams from natural gas stream feeds resulting in a chromatographic-like fractionation with recovery of high purity individual gaseous component streams.

公开(公告)号：EP3374057A1

公开(公告)日：2018-09-19

申请号：EP16798361.8

申请日：2016-11-10

Applicant: Exxonmobil Research And Engineering Company ,  Georgia Tech Research Corporation

Inventor： MCCOOL, Benjamin A. ,  DECKMAN, Harry W. ,  LIVELY, Ryan P. ,  KOH, Dong-Yeun ,  PARTRIDGE, Randall D.

IPC: B01D53/22 ,  B01D69/12 ,  C07C7/144 ,  B01D61/00 ,  B01D61/02 ,  B01D71/02

CPC classification number: B01D61/025 ,  B01D53/228 ,  B01D61/002 ,  B01D61/007 ,  B01D67/0067 ,  B01D69/08 ,  B01D69/12 ,  B01D69/125 ,  B01D71/021 ,  B01D71/022 ,  B01D2323/30 ,  B01D2325/022 ,  B01D2325/04 ,  C02F1/441 ,  C02F2103/08 ,  C07C5/2732 ,  C07C7/005 ,  C07C7/14 ,  C07C7/144 ,  C07C15/08

Abstract: Asymmetric membrane structures are provided that are suitable for various types of separations, such as separations by reverse osmosis. Methods for making an asymmetric membrane structure are also provided. The membrane structure can include at least one polymer layer. Pyrolysis can be used to convert the polymer layer to a porous carbon structure with a higher ratio of carbon to hydrogen.

公开(公告)号：EP3374056A1

公开(公告)日：2018-09-19

申请号：EP16798360.0

申请日：2016-11-10

Applicant: Exxonmobil Research And Engineering Company ,  Georgia Tech Research Corporation

Inventor： MCCOOL, Benjamin A. ,  DECKMAN, Harry W. ,  LIVELY, Ryan P. ,  KOH, Dong-Yeun

IPC: B01D53/22 ,  B01D69/12 ,  B01D71/02 ,  C07C7/144

CPC classification number: B01D61/025 ,  B01D53/228 ,  B01D61/002 ,  B01D61/007 ,  B01D67/0067 ,  B01D69/08 ,  B01D69/12 ,  B01D69/125 ,  B01D71/021 ,  B01D71/022 ,  B01D2323/30 ,  B01D2325/022 ,  B01D2325/04 ,  C02F1/441 ,  C02F2103/08 ,  C07C5/2732 ,  C07C7/005 ,  C07C7/14 ,  C07C7/144 ,  C07C15/08

Abstract: Asymmetric membrane structures are provided that are suitable for various types of separations, such as separations by reverse osmosis. Methods for making an asymmetric membrane structure are also provided. The membrane structure can include at least one polymer layer. Pyrolysis can be used to convert the polymer layer to a porous carbon structure with a higher ratio of carbon to hydrogen.