公开(公告)号：EP0970163B1

公开(公告)日：2005-04-06

申请号：EP98911418.6

申请日：1998-02-26

Applicant: ExxonMobil Research and Engineering Company

Inventor： MCVICKER, Gary, B. ,  HO, Teh, C. ,  SOLED, Stuart, L. ,  DAAGE, Michel ,  KRYCAK, Roman ,  MISEO, Sabato ,  BUCHHOLZ, Viktor ,  LEWIS, William, E.

IPC: C10G45/02 ,  C10G45/04 ,  C10G65/04

CPC classification number: C10G45/04

Abstract: Hydrocarbon feeds are upgraded by contact of the stream under hydrodesulfurization (HDS) conditions with a catalyst system comprising a sulfided, transition metal promoted tungsten/molybdenum HDS catalyst, e.g., Ni/Co-Mo/A12O3 and a solid acid catalyst which is effective for the isomerization/disproportionation/transalkylation of alkyl substituted, condensed ring heterocyclic sulfur compounds present in the feedstream, e.g. zeolite or a heteropolyacid compound. Isomerization, disproportionation and transalkylation reactions convert refractory sulfur compounds such as 4- or 4,6-alkyl dibenzothiophenes into corresponding isomers or disproportionated isomers which can be more readily desulfurized by conventional HDS catalysts to H2S and other products. A hydrocarbon feed is first passed to a hydrotreating reactor (1). The effluent from the hydrotreating reactor (1) goes through a high-pressure gas-liquid separator (2) and is passed to a fractionator (3). The fractionator bottoms are passed to reactor (4) and effluent from reactor (4) is recycled to hydrotreater (1).

公开(公告)号：EP0999893B1

公开(公告)日：2005-01-12

申请号：EP98934397.5

申请日：1998-07-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： SOLED, Stuart, L. ,  MISEO, Sabato ,  KRYCAK, Roman ,  VROMAN, Hilda ,  HO, Win-Sow, Winston ,  RILEY, Kenneth, Lloyd

IPC: B01J23/883 ,  B01J23/888 ,  B01J37/03 ,  C10G45/08

CPC classification number: B01J35/002 ,  B01J23/002 ,  B01J23/85 ,  B01J23/88 ,  B01J23/883 ,  B01J23/8885 ,  B01J37/03 ,  B01J37/082 ,  B01J2523/00 ,  C08F8/04 ,  C10G45/08 ,  C10G45/16 ,  C10G47/04 ,  C10G65/04 ,  C10G65/12 ,  C10G2400/10 ,  C10G2400/14 ,  C08F240/00 ,  B01J2523/68 ,  B01J2523/847 ,  B01J2523/69

Abstract: A hydrodenitrogenation catalyst is prepared by decomposing a nickel (ammonium) molybdotungstate precursor and sulfiding, either pre-use or in situ, the decomposition product.

公开(公告)号：EP0999893A1

公开(公告)日：2000-05-17

申请号：EP98934397.5

申请日：1998-07-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： SOLED, Stuart, L. ,  MISEO, Sabato ,  KRYCAK, Roman ,  VROMAN, Hilda ,  HO, Win-Sow, Winston ,  RILEY, Kenneth, Lloyd

IPC: B01J23/883 ,  B01J23/888 ,  B01J37/03 ,  C10G45/08

CPC classification number: B01J35/002 ,  B01J23/002 ,  B01J23/85 ,  B01J23/88 ,  B01J23/883 ,  B01J23/8885 ,  B01J37/03 ,  B01J37/082 ,  B01J2523/00 ,  C08F8/04 ,  C10G45/08 ,  C10G45/16 ,  C10G47/04 ,  C10G65/04 ,  C10G65/12 ,  C10G2400/10 ,  C10G2400/14 ,  C08F240/00 ,  B01J2523/68 ,  B01J2523/847 ,  B01J2523/69

Abstract: A hydrodenitrogenation catalyst is prepared by decomposing a nickel (ammonium) molybdotungstate precursor and sulfiding, either pre-use or in situ, the decomposition product.

公开(公告)号：EP2539421A2

公开(公告)日：2013-01-02

申请号：EP11706433.7

申请日：2011-02-21

Applicant: ExxonMobil Research and Engineering Company

Inventor： KISS, Gabor ,  NISTOR, Iulian ,  ZENGEL, John ,  MISEO, Sabato ,  KRYCAK, Roman ,  HO, Teh, C.

IPC: C10G45/08

CPC classification number: C10G49/24 ,  B01J38/56 ,  C10G45/02 ,  C10G45/08 ,  C10G2300/1055 ,  C10G2300/1096 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/04

Abstract: A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed using a fresh supported CoMo catalyst, includes treating the fresh catalyst under first hydrotreating conditions with a second hydrocarbon feed having a lower aromatics content than the first feed.

公开(公告)号：EP1169415A1

公开(公告)日：2002-01-09

申请号：EP00905627.6

申请日：2000-01-14

Applicant: ExxonMobil Research and Engineering Company

Inventor： SOLED, Stuart, Leon ,  MISEO, Sabato ,  KRYCAK, Roman ,  VROMAN, Hilda, B. ,  HO, Teh, Chung ,  RILEY, Kenneth, Lloyd

IPC: C10G45/04 ,  C10G45/60 ,  C10G29/04 ,  C10G11/00 ,  C10G11/02 ,  C10G11/04 ,  B01J23/00

CPC classification number: B01J23/002 ,  B01J23/85 ,  B01J23/88 ,  B01J23/883 ,  B01J23/8878 ,  B01J23/888 ,  B01J23/8885 ,  B01J37/03 ,  B01J37/082 ,  B01J2523/00 ,  C08F8/00 ,  C08F8/04 ,  C08F8/50 ,  C10G45/08 ,  C10G45/16 ,  C10G47/04 ,  C10G65/04 ,  C10G65/08 ,  C10G65/12 ,  C10G2300/1062 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/4018 ,  C10G2300/44 ,  C10G2400/10 ,  C10G2400/14 ,  C08F240/00 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/67 ,  B01J2523/847 ,  B01J2523/31 ,  B01J2523/41

Abstract: A process fo hydroprocessing petroleum and chemical feedstocks by use of a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least one, preferably two Group VIB metal wherein the ratio of Group VIB metal to Group VIII metal is from about 10:1 to 1:10.