摘要:
The invention is directed to a Fluid Catalytic Cracking process conducted in a fluid catalytic cracking unit (FCCU) comprising one or more risers, each of said risers having a plurality of injection nozzles therein and at least one reaction zone therein comprising the steps of spatially nonuniformly injecting a plurality of feeds wherein said plurality of feeds comprises at least one feed (α) and at least another feed (β), wherein said feeds (α) and (β): (a) differ in Conradson Carbon Residue by at least about 2 wt.% points or (b) differ in hydrogen content by at least about 0.2 wt.%; or (c) differ in API gravities by at least about 2 points; or (d) differ in nitrogen content by at least about 50 ppm; or (e) differ in carbon-to-hydrogen ratio by at least about 0.3; or (f) differ in mean boiling point by at least about 200 °F; and wherein said spatially nonuniform injection is accomplished by (i) simultaneously injecting into a single reaction zone of a single riser said feed (α) from at least one injection nozzle of said riser and said feed (β) from the remaining nozzles of said riser; (ii) simultaneously injecting said feed (α) into at least one of said reaction zones of said riser of said FCCU and said feed (β) into another of said reaction zones of said riser of said FCCU; or (iii) simultaneously injecting said feed (α) into at least one riser of said FCCU and said feed (β) into a second riser of said FCCU. Wherein when said spatially nonuniform injection is accomplished by (iii), said feeds are substantially non-paraffinic feeds.
摘要:
The instant invention is directed to a process for removing hard sulfurs from hydrocarbon streams comprising: selectively oxidizing hard sulfurs in a hydrotreated stream, under oxidizing conditions in the presence of an effective amount of an oxidizing agent, wherein said oxidizing agent is a peroxometal complex and wherein said hard sulfurs are oxidized into the corresponding sulfoxides and sulfones.
摘要:
The present invention relates to an apparatus and a process for the high-throughput, quick screening, optimization, regeneration, reduction and activation of catalysts. More specifically, the present invention is a method and apparatus to quickly screen, optimize and regenerate multiple fast deactivating catalysts while maintaining a predefined range of time-on-stream.
摘要:
The instant invention is directed to a process for removing hard sulfurs from hydrocarbon streams comprising: selectively oxidizing hard sulfurs in a hydrotreated stream, under oxidizing conditions in the presence of an effective amount of an oxidizing agent, wherein said oxidizing agent is a peroxometal complex and wherein said hard sulfurs are oxidized into the corresponding sulfoxides and sulfones.
摘要:
An FCC unit (10) comprises a hollow, liquid feed conduit (12), through which a hot, liquid FCC oilfeed is passed from an upstream source. At the same time, a cavitation liquid comprising lower boiling hydrocarbon liquid is passed down into the conduit (12) via line (14), which intersects at the tee joint. The cavitation liquid is injected into the flowing hot oil, which it mixes, to form a liquid solution comprising both liquids, in the vicinity of zone (16).
摘要:
A process fo hydroprocessing petroleum and chemical feedstocks by use of a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least one, preferably two Group VIB metal wherein the ratio of Group VIB metal to Group VIII metal is from about 10:1 to 1:10.
摘要:
The present invention is directed to a Fluid Catalytic Cracking process conducted under fluid catalytic cracking conditions by injecting into at least one reaction zone of a fluid catalytic cracking unit (FCCU) having one or more risers, a plurality of feeds wherein said plurality of feeds comprises at least one feed (α) and at least another feed (β) wherein said feeds (α) and (β) (a) differ in Conradson Carbon Residue by at least about 2 wt % points; or (b) differ in hydrogen content by at least about 0.2 wt %; or (c) differ in API gravities by at least about 2 points; or (d) differ in nitrogen content by at least about 50 ppm; or (e) differ in carbon-to-hydrogen ratio by at least about 0.3; or (f) differ in mean boiling point by at least about 200 °F; and wherein said feeds (α) and (β) are alternately injected and wherein said alternate injection maintains said risers in a cyclic steady state, while the rest of the FCC unit is in a steady state.