公开(公告)号：EP2588573A1

公开(公告)日：2013-05-08

申请号：EP11804111.0

申请日：2011-06-28

Applicant: ExxonMobil Research and Engineering Company

Inventor： PRENTICE, Krista, M. ,  DAAGE, Michel, A. ,  DANDEKAR, Ajit, B. ,  OLIVERI, Christopher G. ,  VIJAY, Rohit ,  MCCARTHY, Stephen, J. ,  LAI, Frank, Wenyih ,  FINGLAND, Bradley, R.

IPC: C10G45/00

CPC classification number: C10G67/02 ,  B01J29/7461 ,  B01J35/026 ,  B01J2229/36 ,  B01J2229/42 ,  C10G45/64 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/202 ,  C10G2300/302 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/10 ,  C10L1/08 ,  C10L2200/0446 ,  C10L2270/026 ,  C10L2290/543 ,  C10M101/02

Abstract: An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The integrated process includes an initial dewaxing of a feed under sour conditions, optional hydrocracking of the dewaxed feed, and a separation to form a first diesel product and a bottoms fraction. The bottoms fraction is then exposed to additional hydrocracking and dewaxing to form a second diesel product and optionally a lubricant base oil product. Alternatively, a feedstock can be hydrotreated, fractionated, dewaxed, and then hydrocracked to form a diesel fuel and a dewaxed, hydrocracked bottoms fraction that is optionally suitable for use as a lubricant base oil.

Abstract translation: 提供了一种在酸性条件下从原料生产石脑油燃料，柴油和/或润滑油基础油的综合方法。 在较高硫和/或氮条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 酸进料可以被输送到催化脱蜡步骤，而没有硫和氮污染物的任何分离。 一体化方法包括在酸性条件下进料的初始脱蜡，脱蜡进料的任选加氢裂化和分离以形成第一柴油产物和塔底馏分。 然后将底部馏分暴露于额外的加氢裂化和脱蜡以形成第二柴油产品和任选的润滑剂基础油产品。 或者，可以将原料加氢处理，分馏，脱蜡，然后进行加氢裂化，以形成任选适合用作润滑剂基础油的柴油燃料和脱蜡加氢裂化塔底馏分。

公开(公告)号：EP3077485A1

公开(公告)日：2016-10-12

申请号：EP14802798.0

申请日：2014-11-14

Applicant: ExxonMobil Research and Engineering Company

Inventor： VIJAY, Rohit ,  DANDEKAR, Ajit Bhaskar ,  DAAGE, Michel ,  OLIVERI, Christopher G. ,  ELIA, Christine Nicole ,  LACY, Darryl Donald ,  WEIGEL, Scott J. ,  FINGLAND, Bradley R.

IPC: C10G65/12

CPC classification number: C10G67/14 ,  C10G65/12 ,  C10G67/02 ,  C10G69/08 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4025 ,  C10G2400/04 ,  C10G2400/10

Abstract: Methods are provided for improving the yield of distillate products from hydroprocessing of gas oil feedstocks, such as vacuum gas oils. It has been unexpectedly found that stripping of gases or fractionation to separate out a distillate fraction during initial hydrotreatment of a feed can provide a substantial increase in distillate yield at a desired amount of feedstock conversion. The improvement in yield of distillate products can allow a desired level of conversion to be performed on a feedstock for generating lubricating base oil products while reducing or minimizing the amount of naphtha (or lower) boiling range products. Alternatively, the improvement in yield of distillate products can correspond to an improved yield during a single pass through a reaction system, so that distillate yield is increased even though a lubricant boiling range product is not generated.

Abstract translation: 提供了用于提高瓦斯油原料如真空瓦斯油加氢处理的馏出物产率的方法。 已经意外地发现，在进料的初始加氢处理期间汽提汽提或分馏以分离馏出物馏分可以在所需量的原料转化率下提供馏出物产率的显着增加。 馏出物产物的产率的改善可以在减少或最小化石脑油（或更低）沸点产物的量的同时，在用于产生润滑基础油产品的原料上进行所需水平的转化。 或者，馏出物产物的产率的提高可以对应于在单次通过反应体系期间的提高的产率，使得即使不产生润滑剂沸程产物，馏出物产率也增加。

公开(公告)号：EP2934745A1

公开(公告)日：2015-10-28

申请号：EP12809073.5

申请日：2012-12-19

Applicant: ExxonMobil Research and Engineering Company

Inventor： WU, Jianxin Jason ,  DANDEKAR, Ajit B. ,  OLIVERI, Christopher G.

IPC: B01J29/14 ,  B01J37/10 ,  B01J23/882 ,  B01J23/888 ,  B01J35/10 ,  B01J29/12 ,  C10G45/00

CPC classification number: B01J29/146 ,  B01J23/882 ,  B01J23/888 ,  B01J29/126 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/10 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/24 ,  B01J2229/36 ,  B01J2229/40 ,  C10G47/18 ,  C10G47/20

Abstract: This invention relates to the composition, method of making and use of a hydrocracking catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 A (angstrom) range as determined by nitrogen adsorption measurements. The hydrocracking catalysts of invention exhibit improved distillate yield and selectivity as well as improved conversions at lower temperatures than conventional hydrocracking catalysts containing Y zeolites. The hydrocracking catalysts herein are particularly useful in the hydrocracking processes as disclosed herein, particularly for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms and an associated maximization and/or improved selectivity of the distillate yield obtained from such hydrocracking processes.

公开(公告)号：EP3077485B1

公开(公告)日：2018-10-03

申请号：EP14802798.0

申请日：2014-11-14

Applicant: ExxonMobil Research and Engineering Company

Inventor： VIJAY, Rohit ,  DANDEKAR, Ajit Bhaskar ,  DAAGE, Michel ,  OLIVERI, Christopher G. ,  ELIA, Christine Nicole ,  LACY, Darryl Donald ,  WEIGEL, Scott J. ,  FINGLAND, Bradley R.

IPC: C10G65/12

CPC classification number: C10G67/14 ,  C10G65/12 ,  C10G67/02 ,  C10G69/08 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4025 ,  C10G2400/04 ,  C10G2400/10

Abstract: Methods are provided for improving the yield of distillate products from hydroprocessing of gas oil feedstocks, such as vacuum gas oils. It has been unexpectedly found that stripping of gases or fractionation to separate out a distillate fraction during initial hydrotreatment of a feed can provide a substantial increase in distillate yield at a desired amount of feedstock conversion. The improvement in yield of distillate products can allow a desired level of conversion to be performed on a feedstock for generating lubricating base oil products while reducing or minimizing the amount of naphtha (or lower) boiling range products. Alternatively, the improvement in yield of distillate products can correspond to an improved yield during a single pass through a reaction system, so that distillate yield is increased even though a lubricant boiling range product is not generated.

公开(公告)号：EP2683479A1

公开(公告)日：2014-01-15

申请号：EP12755532.4

申请日：2012-03-07

Applicant: ExxonMobil Research and Engineering Company

Inventor： OLIVERI, Christopher G. ,  LAI, Wenyih Frank ,  DANDEKAR, Ajit B. ,  WEIGEL, Scott J. ,  KAY, Robert Ellis ,  WU, Jianxin Jason

IPC: B01J29/00 ,  B01J29/16 ,  C10G47/00

CPC classification number: B01J29/12 ,  B01J23/42 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/084 ,  B01J29/123 ,  B01J29/126 ,  B01J29/16 ,  B01J29/166 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7026 ,  B01J29/80 ,  B01J29/85 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0045 ,  B01J37/0063 ,  B01J37/0201 ,  B01J37/0207 ,  B01J2229/18 ,  B01J2229/36 ,  B01J2229/42 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G2300/1059 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10L1/08

Abstract: This invention relates to hydrocracking catalysts utilizing stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystal lites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 μim. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4: 1 or more. This invention also relates to the use of such catalysts in hydrocracking processes for the conversion of heavy oils into lighter fuel products. The invention is particularly suited for the selective production of diesel range products from gas oil range feedstock materials under hydrocracking conditions.