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    VERFAHREN ZUM RECYCLING VON PHENOLHARZHALTIGEN MATERIALIEN, INSBESONDERE PHENOLHARZBASIERTEN FASERVERBUNDKUNSTSTOFFEN
    8.
    发明公开
    VERFAHREN ZUM RECYCLING VON PHENOLHARZHALTIGEN MATERIALIEN, INSBESONDERE PHENOLHARZBASIERTEN FASERVERBUNDKUNSTSTOFFEN 审中-公开

    公开(公告)号：EP3374421A1

    公开(公告)日：2018-09-19

    申请号：EP16794590.6

    申请日：2016-11-09

    申请人： Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

    发明人： SÖTHJE, Dominik ,  DREYER, Christian ,  BAUER, Monika ,  LANG, Jürgen

    IPC分类号： C08J11/28 ,  C08G8/10 ,  C08L61/06

    CPC分类号： C08J11/28 ,  C08G8/10 ,  C08G8/32 ,  C08J2361/06 ,  Y02P20/582 ,  Y02W30/706

    摘要： The present invention relates to a method of degrading a phenol resin-containing material, characterized in that the phenol resin-containing material is subjected to an aminolysis with a reagent containing at least one amino group, and to a method of constructing and deconstructing a phenol resin-containing material, characterized in that the phenol resin-containing material is produced by curing the starting components at a temperature of below 140°C and, for the purpose of degradation, subjecting them to an aminolysis with a reagent containing at least one amino group. The inventors have additionally discovered a method of producing a novolak partly or fully degradable by aminolysis, comprising the steps of: (a) reacting a phenolic component with an aldehyde in the presence of (i) an acid, (ii) an aminic hardener and (iii) a triglyceride or a triglyceride mixture, and (b) hardening the resin formed in (a) at a temperature of ≤ 180°C, preferably of ≤ 140°C. And finally, the invention provides a method of recycling a phenol resin-containing material, comprising – the degrading of the material by aminolysis, forming a liquid and possibly components that have remained in the solid state, – in the case of components that have remained in the solid state, the separating of these components from the liquid, – the treating of the liquid for removal of volatile products, preferably under reduced pressure and/or at elevated temperature, to form a nonvolatile residue, – the mixing of the nonvolatile residue with starting materials required for a phenol resin synthesis or with one or more compounds selected from monomers, oligomers and polymers having at least two functional groups which react with amino groups and/or hydroxyl groups.

    CYANATBASIERTE HARZE MIT VERRINGERTER VISKOSITÄT SOWIE DARAUS HERGESTELLTE DUROMERE MIT VERBESSERTER SCHLAGFESTIGKEIT
    10.
    发明公开
    CYANATBASIERTE HARZE MIT VERRINGERTER VISKOSITÄT SOWIE DARAUS HERGESTELLTE DUROMERE MIT VERBESSERTER SCHLAGFESTIGKEIT 有权
    粘度降低CYANATBASIERTE树脂和由其MADE WITH改进的抗冲击性热固性

    公开(公告)号：EP2714774A1

    公开(公告)日：2014-04-09

    申请号：EP12723715.4

    申请日：2012-05-29

    申请人： Fraunhofer Gesellschaft zur Förderung der angewandten Forschung E.V.

    发明人： BAUER, Monika ,  UHLIG, Christoph

    IPC分类号： C08G77/54

    CPC分类号： C08L83/14 ,  C08G77/445 ,  C08G77/54 ,  C09D183/14 ,  D06M15/37 ,  Y10T442/2721

    摘要： The invention relates to a cyanate resin that can be obtained by mixing at least (i) at least one difunctional, oligofunctional, and/or polyfunctional cyanate and/or at least one prepolymer thereof, optionally in combination with at least one additional copolymerizable component, and (ii) at least one siloxane and/or siloxane-containing compound. The invention is characterized in that the resin contains a linear polydialkylsiloxane with a viscosity ranging from 500 to 1500 and/or a polydialkylsiloxane caprolactone or caprolactam copolymer as the siloxane and/or the siloxane-containing compound. The invention further relates a substrate that is saturated or coated with said type of cyanate resin and to a duromer that can be obtained by compressing and/or heating the cyanate resin or the saturated or coated substrate.

    摘要翻译： 本发明涉及氰酸酯树脂确实可以通过至少（i）一种双官能，低官能和/或多官能氰酸酯和/或其至少一种预聚物的组合与至少一种另外的可共聚的成分和混合，任选地被获得（二 ）至少一个硅氧烷和/或含硅氧烷的化合物，在其特点，所述树脂含有具有的粘度为500至1500和/或聚二烷基硅氧烷己内酯或己内酰胺共聚物作为硅氧烷和/或含硅氧烷的化合物的线性聚二烷基硅氧烷。 到基片并为饱和或涂覆有所述型氰酸酯树脂，和热固性也可通过压缩和/或加热所述氰酸酯树脂或饱和的或涂覆的基材而获得，本发明涉及进一步。