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公开(公告)号：EP0098522B1
公开(公告)日：1989-06-07
申请号：EP83106353.2
申请日：1983-06-29
发明人： Kaneko, Masaharu , Yoneyama, Tomio , Iwanami, Junko , Imazeki, Syuji , Mukoo, Akio , Sato, Mikio
CPC分类号： C09B69/00 , C09B1/20 , C09B1/51 , C09B1/542 , C09B1/56 , C09B3/14 , C09B19/02 , C09B25/00 , C09B29/0003 , C09B29/0011 , C09B29/0029 , C09B29/081 , C09B29/0813 , C09B29/26 , C09B31/043 , C09B31/08 , C09B31/157 , C09B35/02 , C09B35/34 , C09B57/08 , C09B57/12 , C09B57/14 , C09K19/60
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2.发明公开Phthalonitrile derivatives and liquid crystal compositions containing them 失效PHTHALONITRILE衍生物和含有它们的液晶组合物
公开(公告)号：EP0087963A3
公开(公告)日：1985-03-20
申请号：EP83301036
申请日：1983-02-25
发明人： Mukoh, Akio , Kitamura, Teruo , Kaneko, Masaharu , Ozawa, Tetsuo
IPC分类号： C07C121/75 , C07C121/56
CPC分类号： C07C255/00 , C09K19/06 , C09K19/12 , C09K19/3003 , C09K19/3066 , C09K19/321 , C09K2019/0407
摘要： Phthalonitrile derivatives are represented by the formula (I):
wherein X and Y each represents a C1-9 alkyl or alkoxy group, The compounds are prepared by cyclisation reaction of a butadiene derivative X-CH=CH-CH-CH-Y with fumaronitrile or dicycanoacetylene, followed by oxidation or bromination. The compounds have a large negative dielectric anis- tropy, and wide liquid crystal range, and are useful, alone or with other liquid crystals, in liquid crystal display devices.
wherein R represents H,
or a halogen atom, where m is an integer of 1 to 9 and n is 0, 1 or 2, but at least one of X and Y does not represents a methyl group, and Y does not represent an alkyl or alkoxy group when X represents
and R' represents an alkyl group.-
公开(公告)号：EP0098736B1
公开(公告)日：1989-12-06
申请号：EP83303771.6
申请日：1983-06-29
发明人： Imazeki, Shuji Hitachi Ltd. , Mukoo, Akio Hitachi Ltd. , Sato, Mikio Hitachi Ltd. , Ozawa, Tetsuo , Kaneko, Masaharu , Yoneyama, Tomio
CPC分类号： C09K19/603 , C09B1/26
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4.发明公开Anthraquinone dyes and liquid crystal compositions containing the dyes 失效Anthrachinonfarbstoffe und diese Farbstoffe enthaltendeflüssigkristallineZusammensetzungen。
公开(公告)号：EP0120717A2
公开(公告)日：1984-10-03
申请号：EP84302158.5
申请日：1984-03-29
发明人： Imazeki, Shuji c/o Hitachi Ltd. , Mukoh, Akio c/o Hitachi Ltd. , Sato, Mikio c/o Hitachi Ltd. , Kaneko, Masaharu , Ozawa, Tetsuo , Yoneyama, Tomio
CPC分类号： C09K19/603 , C09B1/22 , C09B1/58 , C09B1/62
摘要： Anthraquinone dyes are of the general formula:
where R' x C1-9 alkyl; alkoxyalkyl, (substituted)phenyl or -O-CH 2 - or -O-CH 2 - (substituted) phenyl, and R' = C1-18 alkyl, alkoxyalkyl, furfuryl, aralkyl or allyl.
The synthesis uses reagents HS-R' and HO-R' on an anthraquinone dye.
Suitable host liquid crystals are described, and an electro-optic cell in which the crystal compositions is used.
The dyes shown have maximum absorptions of 580-602 nm and have good order parameter, allowing bright display.摘要翻译： 蒽醌染料具有以下通式：...
...其中R 1 x C 1-19烷基; 烷氧基烷基，（取代的）苯基或-O-CH 2 - 或-O-CH 2 - （取代的）苯基，R 2 = C 1-18烷基，烷氧基烷基，糠基，芳烷基或烯丙基。 合成在蒽醌染料上使用试剂HS-R 2和HO-R 1。 描述合适的主体液晶，以及使用晶体组成的电光电池。 所示的染料具有580-602nm的最大吸收并且具有良好的顺序参数，允许明亮的显示。 -
5.发明授权Guest-host type liquid crystal composition and liquid crystal display device 失效GUEST-HOST型液晶组合物和液晶显示装置
公开(公告)号：EP0061181B1
公开(公告)日：1984-07-04
申请号：EP82102298.5
申请日：1982-03-19
发明人： Imazeki, Shuji , Mukoh, Akio , Sato, Mikio , Imahori, Seiichi , Kaneko, Masaharu , Ozawa, Tetsuo
CPC分类号： C09B1/22 , C09B31/043 , C09B31/062 , C09K19/603
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6.发明公开
公开(公告)号：EP0098736A2
公开(公告)日：1984-01-18
申请号：EP83303771.6
申请日：1983-06-29
发明人： Imazeki, Shuji Hitachi Ltd. , Mukoo, Akio Hitachi Ltd. , Sato, Mikio Hitachi Ltd. , Ozawa, Tetsuo , Kaneko, Masaharu , Yoneyama, Tomio
CPC分类号： C09K19/603 , C09B1/26
摘要： Anthraquinone dyes are of the general formula:
wherein R is a trans-4-alkylcyclohexyl, trans-4-cyclohexyl- cyclohexyl, trans-4-alkylcyclohexylcyclohexyl, p-(trans-4--alkylcyclohexyl)phenyl or alkyl, aralkyl or aryl group each of which may be substituted with specified organic groups; and R 2 is an alkyl, cycloalkyl, aralkyl or aryl group each of which may be substituted with specified organic groups; with provisos as to the values of R 1 and R 2 together.
The dyes have a cyan color and excellent order parameter, solubility and stability.
In an electro-optic cell, a liquid crystal composition (9) containing the dye is interposed between two facing electrode plates (8) and permits the realization of good color displays utilizing the guest-host effect of a liquid crystal.摘要翻译： 蒽醌染料是通式：...
... worin - [R <1>是一个反式-4-烷基环己基，反式-4- -cyclohexylcyclohexyl，反式-4- alkylcyclohexylcyclohexy，对 - （反式-4-烷基环己基）苯基或烷基 ，芳烷基或芳基的每一个可以是substituiertem与指定的有机基团; 且R 2是烷基，环烷基，芳烷基或芳基的每一个可与指定的有机基团substituiertem; 与附带条件为R的<1>和R <2>一起的值。 ... 的染料有青色和优异的顺序参数，溶解度和稳定性。 ... 在电光细胞，含有该染料的液晶组合物（9）被插入两个相对的电极板（8）之间，并允许实现良好的彩色显示器利用了液晶的宾主效应的 ， -
公开(公告)号：EP0087248B2
公开(公告)日：1989-02-08
申请号：EP83300684.4
申请日：1983-02-10
发明人： Imazeki, Shuji , Mukoh, Akio , Sato, Mikio , Kaneko, Masaharu , Yoneyama, Tomio , Iwanami, Junko
IPC分类号： C09K19/24
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公开(公告)号：EP0087248B1
公开(公告)日：1986-05-28
申请号：EP83300684.4
申请日：1983-02-10
发明人： Imazeki, Shuji , Mukoh, Akio , Sato, Mikio , Kaneko, Masaharu , Yoneyama, Tomio , Iwanami, Junko
IPC分类号： C09K19/24
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公开(公告)号：EP0098522A3
公开(公告)日：1986-03-19
申请号：EP83106353
申请日：1983-06-29
发明人： Kaneko, Masaharu , Yoneyama, Tomio , Iwanami, Junko , Imazeki, Syuji , Mukoo, Akio , Sato, Mikio
IPC分类号： C09K03/34 , C09B69/00 , C09B29/00 , C09B31/00 , C09B01/00 , C09B03/14 , C09B25/00 , C09B57/08
CPC分类号： C09B69/00 , C09B1/20 , C09B1/51 , C09B1/542 , C09B1/56 , C09B3/14 , C09B19/02 , C09B25/00 , C09B29/0003 , C09B29/0011 , C09B29/0029 , C09B29/081 , C09B29/0813 , C09B29/26 , C09B31/043 , C09B31/08 , C09B31/157 , C09B35/02 , C09B35/34 , C09B57/08 , C09B57/12 , C09B57/14 , C09K19/60
摘要： A liquid crystal composition of the guest-host type contains a pleochroic dye dissolved therein. The dye molecule has an end group or end groups in the molecule represented by the general formula:
wherein Ro designates a straight chain alkyl group, in which methylene groups not adjacent to the nitrogen atom may be substituted by oxygen atom or sulfur atom; R1 designates an alkyl group having a chain length different from the alkyl group of Ro or a group
in R1 a methylene group not adjacent of the nitrogen atom may be substituted by an oxygen atom or sulfur atom, and R2 designates a hydrogen atom, an alkyl group, alkoxy group, cycloalkyl group or dialkylamino group.-
公开(公告)号：EP0120463A2
公开(公告)日：1984-10-03
申请号：EP84103132.1
申请日：1984-03-21
发明人： Imazeki, Shuji , Mukoh, Akio , Sato, Mikio , Kaneko, Masaharu , Ozawa, Tetsuo , Yoneyama, Tomio
CPC分类号： C09B1/20 , C09B1/50 , C09B1/542 , C09B1/58 , C09K19/603
摘要： A liquid crystal composition comprising a host liquid crystal material and at least one guest novel anthraquine dye dissolved in said host liquid crystal material has a high order parameter, sufficient solubility in the host liquid crystal and high stability.
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