摘要:
Adhesives based on polyurethane reactive compounds which are obtainable by reacting at least one type of polyol with at least one type of diisocyanate containing at least 80 percent by weight 2,4'-diphenyl- associated with a along reactivation time. The inventive method consists in applying methyl diisocyanate (2,4'-MDI) are convenient for hot-melt adhesion methods associated with a along reactivation time. The inventive method consists in applying adhesive to a surface to be glued of at least one substrate, thermally reactivating the adhesive layers of substrates provided with the adhesive in association with temporal and/or spatial separation of the adhesive application and after said reactivation in jointing the substrates to be stuck together. According to said invention, the substrates jointed according said method do not exhibit any negative difference with respect to adherence or ageing characteristics in comparison with substrates bonded according to classic methods, i.e. directly jointed after an adhesive application.
摘要:
The invention relates to a solvent-free, moisture-hardening polyurethane hot-melt adhesive composition, the adhesive comprising the following components: 20 to 85 wt.% of a polyurethane prepolymer having free isocyanate groups, produced from at least one polyol selected from the group comprising polyether polyols, polyester polyols, polyalkylene polyols and mixtures thereof with an excess of at least one polyisocyanate, the prepolymer containing less than 1 wt.% monomeric diisocyanates; 4 to 40 wt.% of at least one acrylate copolymer with a molecular weight of less than 60 000 g/mol; 3 to 35 wt.% of a thermoplastic polyester with a number average molecular weight (MN) of less than 6000 g/mol, which has fewer than 1.4 groups which react with NCO; and 0 to 25 wt.% of at least one additive selected from the group of catalysts, resins, softeners, fillers, pigments, stabilizers or adhesion promoters, the total of the components being 100 wt.%.
摘要:
The invention relates to a foamable composition that can be cross-linked, having a low monomeric isocyanate content, comprising 70 to 99.8 wt % of prepolymers produced from polyester polyols and/or polyether polyols by reacting same with an excess of aromatic diisocyanates and subsequently removing excess monomeric diisocyanate, 0.2 to 30 wt % of additives and at least one propellant, wherein the polyols comprise a functionality of less than 2.5, the polyols have a molar mass (M N ) between 150 and 3000 g/mol, and the prepolymers comprise a monomeric diisocyanate content of less than 5 wt %.
摘要:
The invention relates to polyether block copolymers of the general structure B-(A-OH) n . N is equal to or greater than 2 and the blocks A consist of polyoxypropylene units and the central block B consists of polyoxytetramethylene, polyoxyethylene, polybutadiene, polyisoprene, polyacrylate, polymethacrylate, polyamide, polyurethane, or polyester units. Said polyether block copolymers are suitable for producing compositions serving as the basis for preparations for use as single-component moisture-curing or two-component adhesive or sealing agents, for assembly adhesion, for surface adhesion and/or coating, as a reactive melt adhesive, or as a laminating adhesive.
摘要:
The invention relates to a cross-linkable foamable composition having a low content of monomer isocyanates, comprising a) 10 to 90% by weight of a prepolymer made of polyester dioles converted using an excess of diisocyanates, b) 90 to 10% by weight of a component based on polyether polyols comprising either at least one Si(OR) 3 group or at least one NCO group, c) 0.1 to 30% by weight of additive, d) and at least one propellant, wherein the polyester diole and the polyether diole comprise a molar mass (M N ) of less than 5000 g/mol, and the mixture of a and b has a content of monomer diisocyanates of less than 1% by weight.
摘要:
The invention relates to reactive polyurethane compositions that can be produced by reacting polyols with a stoichiometric excess of mixtures consisting of asymmetric polyisocyanates having a molecular weight of less than 500 and an NCO functionality ranging from 0.175 to 2.5 and high-molecular isocyanates. These high-molecular polyisocyanates consist, according to WO 01/40342, of low-molecular diols and of monomeric diisocyanates. These reactive polyurethane compositions are suited for producing reactive hot-melt-type adhesives, solvent-free or solvent-containing laminating adhesives, assembly foams, casting compounds, soft/hard and integral foams and for producing reactive one-component or two-component adhesives/sealants.
摘要:
Isocyanate-functional silanes made of non-volatile aliphatic or cycloaliphatic polyisocyanates having a steam pressure of less than 5* 10-5 h Pa at 20? C and organo-functional silanes having Zerewitinoff-active hydrogen groups are suitable as adhesion promoters for adhesive, caulking, and coating materials made of polyurethane. Said isocyanate-functional silanes are particularly suitable as an additive to hot-melt-type adhesives and covering adhesives because the adhesives produced therewith can also be applied at high temperatures without emitting hazardous pollutants for work hygiene.
摘要:
Compositions containing a reaction product of a stochiometic excess of a polyisocyanate with hydroxy functional polyester-ether-block copolymers based on aromatic dicarboxylic acids, a reaction product of a polyisocyanate with a polyester polyol and/or optionally, a reaction product of a polyisocyanate with a polyester polyol and/or, optionally, a reaction product of a polyisocyanate with a polyether polyol and, optionally, non-reactive thermoplastic polymers. Said compositions are suitable for use as reactive melt adhesives. The use of reaction products of the hydrofunctional polyester-ether block copolymers with polyisocyantaes enables the block copolymer constitutional unit to be solidly incorporated into the adhesive matrix, increases the reactive part in the adhesive composition and results in better heat resistance and hydrolysis resistance while, at the same time, lowering ther melting point of the polyester-ether copolymer components without any adverse effects on heat resistance and setting speed. The compatibility of the components of the composition is also increased as a result of said incorporation into the polymer matrix.