PROCESS FOR PRODUCING FLUOROOLEFINS
    9.
    发明公开
    PROCESS FOR PRODUCING FLUOROOLEFINS 有权
    用于生产的氟烯烃

    公开(公告)号:EP1430011A1

    公开(公告)日:2004-06-23

    申请号:EP02773563.8

    申请日:2002-09-25

    IPC分类号: C07C17/25 C07C21/18

    摘要: A process for producing a fluoroolefin of the formula: CF3CY=CXnHp wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); nand p are integers independently equal to 0, 1 or 2, provided that (n + p) = 2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF3C (RlaR2b) C (R3CR4d) , wherein R?1, R2, R3, and R4¿ are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R?1, R2, R3, and R4¿ is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently = 0, 1 or 2 and (a+b) = 2; and c and d are independently = 0, 1, 2 or 3 and (c+d) = 3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and ls-crown-S; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olefin is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.