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公开(公告)号：EP2480585A1
公开(公告)日：2012-08-01
申请号：EP10757034.3
申请日：2010-09-13
申请人： IGM Group B.V.
CPC分类号： C09D163/00 , C08G59/1466 , C08G59/182 , C08G2650/58 , C08L63/10 , C08L71/02 , C09D5/022 , C09D5/027 , C08L2666/22
摘要： The invention relates to aqueous radiation-hardenable epoxy acrylate dispersions comprising (a) an epoxy acrylate resin (P*) with at least two acrylate groups per molecule, wherein at 25 degrees Celsius, said epoxy acrylate resin is not self-disperging in water; and (b) a dispergator (D*) with at least one acrylate group per molecule, wherein said dispersions can be produced by converting, in a first step (i), in the presence of a catalyst if need be, one or several compounds (A) selected from the group of non-ionic compounds having a HLB value of less than 12, and containing at least two oxirane groups per molecule, with one or several compounds (B) selected from the group of non-ionic compounds having a HLB value in the range from 12 to 20, and which contain at least one h-acid group (ZH) per molecule. The compounds (A) and (B) are employed at an equivalence ratio EpO (A) : ZH (B) in the range from 1.3:1 to 400:1, and in a second step (ii), the reactive mixture thus obtained is converted, in the presence of a catalyst if need be, with one or several non-ionic compounds having a HLB value of less than 12, and containing at least two oxirane groups per molecule (compounds A), and with one or several compounds (C) selected from the group of non-ionic compounds having a HLB value of less than 12, and which contain at least two H-acid groups. The compounds (A) and (C) are employed at an equivalence ratio EpO (A) : ZH (C) in the range from 1.1:1 to 20:1. In a third step (iii), the reactive mixture thus obtained is converted, in the presence of a catalyst if need be, with acrylic acid by ring opening of all epoxy groups. In a fourth step (iv), the reactive mixture thus obtained is disperged in water.
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公开(公告)号：EP2430070A1
公开(公告)日：2012-03-21
申请号：EP10715732.3
申请日：2010-04-30
申请人： IGM Group B.V.
IPC分类号： C08G69/26 , C08G69/28 , C08G69/48 , C09D11/10 , C09D177/10 , C08G69/34 , C09D177/08
CPC分类号： C08G69/26 , C08G69/28 , C08G69/34 , C08G69/48 , C08L77/06 , C08L77/08 , C09D11/101 , C09D177/08
摘要： The invention relates to resins comprising acrylate groups that are liquid at 25°C, obtained in that polycarbolic acids (a) comprising at least 2 carboxyl groups and at least 2 C atoms per molecule are converted in a first stage with polyamines (b) comprising at least 2 amino groups and at least 2 C atoms per molecule, such that an intermediate compound (z) results, said compound being terminated by carboxyl groups, and said compound (z) being functionalized in a second stage, such that the free carboxyl groups thereof are provided with one or more (meth)acrylate groups in one or more stages, said resins being suitable as radiation-curing compounds for producing coatings.
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公开(公告)号：EP1814956B1
公开(公告)日：2015-12-23
申请号：EP05802646.9
申请日：2005-11-12
申请人： IGM Group B.V.
发明人： HÖFER, Rainer , DRUENE, Laurence , BALLIN, Jean-Marc , GARINET, Morgan , IYER, Ramesh Dr. , IYER, Lakshmi
IPC分类号： C09D163/10 , C09D5/02
CPC分类号： C08G59/1466 , C09D5/002 , C09D5/02 , C09D163/10
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