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    Chromophore-containing compounds for opto-electronic applications
    1.
    发明公开
    Chromophore-containing compounds for opto-electronic applications 失效
    Chromophor enthaltende Verbindungenfüroptoelektronische Verwendungen。

    公开(公告)号：EP0474402A2

    公开(公告)日：1992-03-11

    申请号：EP91307718.6

    申请日：1991-08-21

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Ryan, Timothy George ,  Devonald, David Phillip ,  Gordon, Hutchings Michael ,  Ian, Ferguson ,  Carter, Neil

    IPC分类号： G02F1/35 ,  C09B23/14 ,  C09B17/00

    CPC分类号： G02F1/065 ,  G02F1/3615 ,  Y10T428/261 ,  Y10T428/31935

    摘要： The use of a multi-functional, chromophore containing, polymerisable compound for producing an optical element having non-linear optical properties (an NLO element) wherein the multi-functional chromophore is a compound capable of being polymerised into a cross-linked network and of being poled under the influence of an electric field whilst being polymerised into the cross-linked network, the compound having the generalised formula (D) (C) (A) (F) D, C, A and F representing covalently linked moieties where C represents at least one conjugated system of π-bonds,
    A and D represent at least one respectively π-electron acceptor and π -electron donor groups linked at opposite ends of the conjugated system, and are preferably conjugated with the conjugated system of π-bonds (C) and where more than one moiety A, C or D is present they may be the same or different,
    F represents at least two polymerisable functional groups, which may be the same or different, attached to the π-conjugated system C or the groups A and D via substituent groups R₁ and R₂, where R₁ and R₂ are selected from alkyl, cycloalkyl, aryl heteroalkyl, alkenyl, cycloalkenyl, and alkynyl including groups which have been substituted or contain heteroatom replacement, the groups F being linked to the compound so that after the compound has been polymerised to give a cross-linked network the interpolymerised functional groups prevent significant realignment of the chromophore groups when the optical element is subject to temperature changes during any further fabrication and in use.

    摘要翻译： 使用含有多功能发色团的可聚合化合物来制造具有非线性光学性质的光学元件（NLO元件），其中多功能发色团是能够聚合成交联网络的化合物和 在聚合成交联网络的同时，在电场的影响下被极化，该化合物具有通式为D，C，A和F的共价连接部分，其中C表示至少一个π- 键，A和D表示在共轭系统的相对端连接的至少一个分别为π电子受体和π-电子供体基团，并且优选与π-键（C）的共轭体系缀合，并且其中多于一个部分 A，C或D存在，它们可以相同或不同，F表示至少两个可连接到π-共轭系统的可聚合官能团，其可以相同或不同 取代基R 1和R 2，其中R 1和R 2选自烷基，环烷基，芳基杂烷基，链烯基，环烯基和炔基，包括被取代或含有杂原子取代的基团，基团F为 与化合物连接，使得在化合物聚合得到交联网络之后，当在任何进一步制备和使用期间光学元件经受温度变化时，互聚官能团可防止发色团的显着重新对准。

    Chromophore-containing compounds for opto-electronic applications
    3.
    发明公开
    Chromophore-containing compounds for opto-electronic applications 失效
    用于光电子应用的含色素化合物

    公开(公告)号：EP0474402A3

    公开(公告)日：1992-05-27

    申请号：EP91307718.6

    申请日：1991-08-21

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Ryan, Timothy George ,  Devonald, David Phillip ,  Gordon, Hutchings Michael ,  Ian, Ferguson ,  Carter, Neil

    IPC分类号： G02F1/35 ,  C09B23/14 ,  C09B17/00

    CPC分类号： G02F1/065 ,  G02F1/3615 ,  Y10T428/261 ,  Y10T428/31935

    摘要： The use of a multi-functional, chromophore containing, polymerisable compound for producing an optical element having non-linear optical properties (an NLO element) wherein the multi-functional chromophore is a compound capable of being polymerised into a cross-linked network and of being poled under the influence of an electric field whilst being polymerised into the cross-linked network, the compound having the generalised formula (D) (C) (A) (F) D, C, A and F representing covalently linked moieties where C represents at least one conjugated system of π-bonds,
    A and D represent at least one respectively π-electron acceptor and π -electron donor groups linked at opposite ends of the conjugated system, and are preferably conjugated with the conjugated system of π-bonds (C) and where more than one moiety A, C or D is present they may be the same or different,
    F represents at least two polymerisable functional groups, which may be the same or different, attached to the π-conjugated system C or the groups A and D via substituent groups R₁ and R₂, where R₁ and R₂ are selected from alkyl, cycloalkyl, aryl heteroalkyl, alkenyl, cycloalkenyl, and alkynyl including groups which have been substituted or contain heteroatom replacement, the groups F being linked to the compound so that after the compound has been polymerised to give a cross-linked network the interpolymerised functional groups prevent significant realignment of the chromophore groups when the optical element is subject to temperature changes during any further fabrication and in use.

    Amphiphilic compounds for sequential monolayer deposition
    7.
    发明公开
    Amphiphilic compounds for sequential monolayer deposition 失效
    两栖动物动物动物

    公开(公告)号：EP0474431A1

    公开(公告)日：1992-03-11

    申请号：EP91307891.1

    申请日：1991-08-22

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Ryan, Timothy George, Aireyholme House ,  Devonald, David Phillip ,  Hutchings, Michael Gordon

    IPC分类号： C07C245/08 ,  G02F1/35 ,  B05D1/20

    CPC分类号： B82Y30/00 ,  B05D1/202 ,  B82Y20/00 ,  B82Y40/00 ,  C07C245/08 ,  C07C255/27 ,  G02F1/3618 ,  Y10S430/146

    摘要： Amphiphilic compounds and oligomers and polymers derived therefrom suitable for Langmuir Blodgett deposition having the general formula

    where M is a molecular moiety.
    x and y may be the same or different and are between 1 and 6, preferably 2 or 3,
    B₁ and B₂ may be the same or different and are chosen from phenyl, alkylphenyl or any molecular moiety made hydrophobic by attachment of a group containing from 8 to 40, preferably 10 to 20, carbon atoms.
    P is selected from a C₁ to C₆ alkyl group,

    Q is selected from a C₁ to C₆ alkyl group,

    where B₃ and B₄ may be the same or different from B₁ and B₂ and are chosen from the same list of substituent groups with the proviso that when the compound contains only 2 nitrogen atoms in the chain both B₁ and B₂ must be molecular moieties made hydrophobic by attachment of a group containing 8 to 40 carbon atoms and when the compound contains only 3 nitrogen atoms at least one of B₁, B₂, B₃ or B₄ must be a molecular moiety made hydrophobic by attachment of a group containing 8 to 40 carbon atoms. The compounds can be used to form non-centro symmetric bilayers and are useful for forming various non-linear optical elements.

    摘要翻译： 两性化合物和衍生自其的低聚物和聚合物适用于具有通式（CHEM）的Langmuir Blodgett沉积，其中M是分子部分。 x和y可以相同或不同，在1和6之间，优选2或3，B1和B2可以相同或不同，并且选自苯基，烷基苯基或通过连接含有 8至40，优选10至20个碳原子。 P选自C1至C6烷基， Q选自C1至C6烷基，其中B3和B4可以与B1和B2相同或不同，并选自同一列表 取代基，条件是当化合物在链中仅含有2个氮原子时，B1和B2必须是通过连接含有8至40个碳原子的基团而疏水化的分子部分，并且当该化合物仅含有3个氮原子时，至少有一个 B1，B2，B3或B4必须是通过连接含有8至40个碳原子的基团而疏水化的分子部分。 这些化合物可以用于形成非中心对称双层，并且可用于形成各种非线性光学元件。