公开(公告)号：EP2045012A1

公开(公告)日：2009-04-08

申请号：EP07767478.6

申请日：2007-06-25

申请人： Idemitsu Kosan Co., Ltd. ,  PETROLEUM ENERGY CENTER (PEC), A juridical incorporated foundation

发明人： IINO, Akira ,  ITOH, Toshio ,  AKASHI, Shinji

IPC分类号： B01J29/16 ,  B01J35/10 ,  C10G11/05 ,  C10G11/18

CPC分类号： B01J29/166 ,  B01J29/48 ,  B01J29/64 ,  B01J29/7815 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0045 ,  B01J2229/12 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/1059 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/02

摘要： The present invention 1, 2 or 3 provides a desulfurization function-added FCC catalyst which can efficiently reduce the sulfur content of FCC gasoline while maintaining the yield of FCC gasoline in a process of producing FCC gasoline by cracking of heavy oil. The catalyst has vanadium supported on a carrier comprising (a) an alumina-coated zeolite and (b) a porous inorganic oxide except zeolite and/or a clay mineral, wherein the supported vanadium amount is from 500 to 20000 ppm by mass in terms of vanadium metal and the acid amount is from 20 to 450 µmol/g and the macropore surface area is from 30 to 150 m 2 /g; or the catalyst has vanadium supported on a carrier containing from 5 to 40 % by mass of (a) an alumina-coated zeolite and from 30 to 70 % by mass of (b) an alumina, wherein the vanadium concentration ratio before and after grinding the catalyst is at least 2; or the catalyst has at least vanadium and manganese and/or phosphorus supported on a porous inorganic oxide-containing carrier, wherein the supported vanadium amount is from 500 to 20000 ppm by mass in terms of vanadium metal, vanadium and manganese and/or phosphorus form a complex ion in the supporting solution for use in supporting vanadium and manganese and/or phosphorus, and the permeability of the complex ion through a reverse osmosis membrane is at most 25 % relative to the permeability of vanadium through the reverse osmosis membrane.

摘要翻译： 本发明1，2或3提供了脱硫附加功能-FCC催化剂，同时通过重油的裂化维护FCC汽油生产FCC汽油一个工序的成品率，能有效减少所述催化裂化汽油的硫含量。 该催化剂具有钒负载在载体，其包括（a）上涂覆氧化铝的沸石和（b）除沸石和/或粘土矿物，worin支持的钒量为500〜20000质量ppm来讲多孔无机氧化物的 钒金属和酸含量为20〜450摩尔/克和大孔表面积为30至150米2 /克; 或该催化剂的钒支持的质量含有5至40％的载体上的（a）氧化铝涂覆的沸石和从30至（b）中的氧化铝，前worin钒浓度比和后研磨的70质量％ 所述催化剂是至少2; 或催化剂具有至少钒和锰和/或磷负载在多孔无机氧化物含有载体，worin支持的钒量为500〜20000质量ppm的钒金属，钒的术语和锰和/或磷的形式上 在用于通过反渗透膜支撑钒和锰和/或磷，和复合离子的渗透性支撑溶液的复合离子是最相对通过反渗透膜25％钒的透气性的。

公开(公告)号：EP0638361B1

公开(公告)日：1999-07-28

申请号：EP94906390.3

申请日：1994-02-15

申请人： IDEMITSU KOSAN COMPANY LIMITED ,  PETROLEUM ENERGY CENTER (PEC) a juridical incorporated foundation

发明人： IINO, Akira ,  IWAMOTO, Ryuichiro ,  MITANI, Tsuyoshi

IPC分类号： B01J23/85

CPC分类号： B01J23/85 ,  B01J37/0236 ,  C10G45/08

摘要： A suspension of alumina gel obtained by dispersing alumina gel into pure water so that the concentration of alumina is in the range of 0.1-12 wt.% and an aqueous solution of metallic salt in which a compound of metal in VIA group and that of metal in VIII group are dissolved are mixed, and the resultant mixture is dried and hardened by evaporating the water while agitating the mixture, whereby these metal components can be supported effectively on the alumina gel up to a sufficiently high support quantity. This enables a high-performance catalyst composition constituting a catalyst the performance, such as activity, of which is superior to that of a hydrogen treated catalyst, and such as a conventional hydrodesulfurized molten catalysts to be obtained easily. When this catalyst composition is brought into contact with sulfur-containing hydrocarbon in the presence of hydrogen, hydrocarbons from which sulfur has been sufficiently removed can be obtained.

公开(公告)号：EP2463026A1

公开(公告)日：2012-06-13

申请号：EP10806412.2

申请日：2010-08-02

申请人： Idemitsu Kosan Co., Ltd. ,  JGC Catalysts and Chemicals Ltd. ,  Japan Petroleum Energy Center

发明人： INAMURA, Kazuhiro ,  IINO, Akira ,  TAKAHASHI, Nobuyuki ,  SUNAGAWA, Yoji ,  WATABE, Mitsunori ,  YAMAHATA, Yuichi ,  EURA, Shinya ,  SHIRAHAMA, Yuji

IPC分类号： B01J29/16 ,  B01J35/10 ,  C10G47/12 ,  C10G47/20

CPC分类号： C10G47/18 ,  B01J29/064 ,  B01J29/076 ,  B01J29/106 ,  B01J29/166 ,  B01J29/42 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/20 ,  B01J2229/42 ,  C10G47/20

摘要： Provided is a catalyst for hydrocracking of heavy oil which is excellent in both functions of cracking activity and desulfurization activity with respect to heavy oil by striking a balance between the cracking activity and desulfurization activity and which includes a support including a crystalline aluminosilicate and a porous inorganic oxide excluding the crystalline aluminosilicate, with an active metal being supported on the support, in which (a) the support includes the crystalline aluminosilicate in an amount of 45% by mass or greater and smaller than 60% by mass and the porous inorganic oxide excluding the crystalline aluminosilicate in an amount of greater than 40% by mass and 55% by mass or smaller, based on the sum of an amount of the crystalline aluminosilicate and an amount of the porous inorganic oxide excluding the crystalline aluminosilicate, (b) the active metal is at least one kind of metal selected from metals belonging to Groups 6, 8, 9, and 10 of the Periodic Table, and (c) the catalyst for hydrocracking of heavy oil has a distribution of pores in which an entire pore volume of pores defined as pores having a diameter of 5 to 1000 nm is 0.40 dm 3 /kg or greater, and a volume of intermediate mesopores having a diameter of 10 nm or larger and smaller than 20 nm accounts for 60% or greater of the entire pore volume.

摘要翻译： 提供了一种用于重油所有的加氢裂化催化剂，该催化剂由撞击裂化活性和脱硫活性和其包括支持，包括结晶硅铝酸盐和多孔无机之间的平衡是优异的裂化活性和脱硫活性相对于重油的两种功能 被支撑在所述支撑氧化物不包括结晶硅铝酸盐，与活性金属，其中（a）所述支撑件包括在和的45％的量的质量或更大，并且小于60质量％的多孔性无机氧化物不包括结晶硅铝酸盐 结晶硅铝酸盐在按质量计大于40％的量，并通过质量或更小的55％，基于在不包括结晶硅铝酸盐的多孔无机氧化物的量的结晶硅铝酸盐的和的量的总和，（b）该活性 金属是至少一种金属选自属于6族，第8，第9族金属，和周期表的第10， 和（c）用于重油加氢裂化的催化剂具有细孔的在其中定义为孔的直径为5〜1000纳米的孔的整个孔容积的分布0时40分米3 / kg或更大，和中间孔的体积 具有直径为10nm以上且小于20nm的占整个孔体积的60％或更大的。

公开(公告)号：EP1826178A1

公开(公告)日：2007-08-29

申请号：EP05805533.6

申请日：2005-11-02

申请人： IDEMITSU KOSAN CO., LTD.

发明人： INAMURA, Kazuhiro ,  IIDA, Hiroshi ,  OKAZAKI, Yoshihiro ,  IINO, Akira

IPC分类号： C01B39/24 ,  B01J29/16 ,  B01J35/10 ,  C10G47/16

CPC分类号： C10G47/20 ,  B01J29/146 ,  B01J29/166 ,  B01J29/88 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/065 ,  C01B39/24 ,  C10G2400/06

摘要： The present invention relates to an iron-containing crystalline aluminosilicate, a hydrocracking catalyst comprising the same and a process for hydrocracking utilizing the catalyst, and employing the catalyst in hydrocracking for heavy oil results in easy production of great quality kerosene and gas oil having low contents of sulfur and nitrogen as well as increased production thereof.

摘要翻译： 本发明涉及结晶性硅铝酸盐，加氢裂化催化剂，其包含相同的，并且用于加氢裂化利用催化剂和采用在加氢裂化催化剂的重油导致容易制造的大质量煤油和瓦斯油具有低的内容的过程中，以含铁 的硫和氮，以及它们的产量增加。

公开(公告)号：EP2258476A1

公开(公告)日：2010-12-08

申请号：EP09726115.0

申请日：2009-03-17

申请人： Petroleum Energy Center, A Juridical Incorporated Foundation ,  Idemitsu Kosan Co., Ltd.

发明人： IINO, Akira ,  INAMURA, Kazuhiro

IPC分类号： B01J29/16 ,  B01J35/10 ,  C10G45/06 ,  C10G45/08 ,  C10G45/12 ,  C10G47/20

CPC分类号： B01J29/166 ,  B01J29/076 ,  B01J29/106 ,  B01J29/146 ,  B01J35/10 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  C10G45/06 ,  C10G45/08 ,  C10G45/12 ,  C10G47/20

摘要： A catalyst for hydrocracking of heavy oil which comprises a support comprising crystalline aluminosilicate and a porous inorganic oxide excluding the crystalline aluminosilicate and an active metal supported on the support, wherein (a) the support comprises the crystalline aluminosilicate in an amount of 18% by mass or greater and smaller than 45% by mass and the porous inorganic oxide in an amount exceeding 55% by mass and of 82% by mass or smaller based on a sum of the amount of the crystalline aluminosilicate and the amount of the porous inorganic aluminosilicate, (b) the active metal is at least one metal selected from molybdenum, tungsten and nickel, and (c) the distribution of pores in the catalyst for hydrocracking of heavy oil is such that a volume of pores having a diameter of 500 to 10,000 Å is 10% or smaller and a volume of pores having a diameter of 100 to 200 Å is 60% or greater based on a volume of entire pores having a diameter of 50 to 10,000 Å. The catalyst exhibits excellent desulfurizing function and excellent activity for decomposition of fractions having a high boiling point of 525°C or higher such as the vacuum residue.

摘要翻译： 一种用于加氢裂化重油的催化剂，其包括包含结晶硅铝酸盐的载体和除了结晶硅铝酸盐之外的多孔无机氧化物和负载在载体上的活性金属，其中（a）载体包含18质量％的结晶硅铝酸盐 或更多且小于45质量％，多孔无机氧化物的量超过55质量％且基于结晶硅铝酸盐的量与无机硅酸铝多孔体的量的总和为82质量％ （b）活性金属是选自钼，钨和镍中的至少一种金属，和（c）催化剂中用于重油加氢裂化的孔分布使得直径为500至10,000埃的孔体积 相对于直径为50〜10,000的整个孔的体积，为10％以下，直径为100〜200的孔体积为60％以上。 该催化剂具有优异的脱硫功能和优异的分解具有525℃或更高沸点的馏分的活性，如减压渣油。