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1.发明公开Process for bleaching using peroxo-polyoxometalates for textiles made from mixtures of cellulosic fibers such as: flax-cotton, hemp-cotton 审中-公开使用过氧由纤维素纤维如亚麻，棉花，大麻棉的混合物制成的多金属氧酸盐漂白纺织品的方法
公开(公告)号：EP2703553A1
公开(公告)日：2014-03-05
申请号：EP13464006.9
申请日：2013-04-02
摘要： According to the invention, the process consists of bleaching textile materials from mixtures of cellulosic fibre, such as: (flax-cotton, hemp-cotton) until achieving a whiteness degree of 70-80%, which is carried out in two stages: in the first stage, the materials are treated in aqueous solution containing peroxo-POM catalysts {(NH 4 ) 8 [Mo 10 O 22 (O 2 ) 12 ]; Na 2 [MoO(O 2 ) 2 (C 2 O 4 )]; MoO(O 2 ) 2 ; WO(O 2 ) 2 } in the presence of ionic surfactant and H 2 O 2 , at the temperature of 70-90° C for 60-90 minutes, while in the second stage the material treated in the first stage is suspended in a solution containing 1,5-7 g NaOH, 0,2-1,3 g Na 2 SiO 3 and 0,8-3,2 g H 2 O 2 , for 1-1.5 hours at the temperature of 70-80°C, after which it is washed with cold water until it reaches neutral pH, and then it is air-dried.
摘要翻译： 。根据本发明，从纤维素纤维的混合物，例如漂白织物材料的过程besteht：（亚麻棉，麻，棉），直到实现70-80％的白度，所有这一切是在两个阶段进行：在 第一阶段中，将材料在水溶液中的含过氧POM催化剂{（NH 4）8 [沫10 O 22（O 2）12]治疗; 的Na 2 [的MoO（O 2）2（C 2 O 4）]; 的MoO（O 2）2; WO（O 2）2}在离子表面活性剂和H 2 O 2，在70-90℃下进行60-90分钟的温度，存在而在第二阶段，在第一阶段处理的材料悬浮在 含有溶液1.5-7克NaOH，0.2-1.3克的Na 2的SiO 3和0.8〜3.2克H 2 O 2，1-1.5小时在70-80℃的温度下 ，afterwhich它用冷水洗涤，直到它达到中性pH，然后将其空气干燥。
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2.发明公开Functionalization process of cellulosic textile materials (fibres, yarns, fabrics and knitted fabrics) such as:cotton, hemp, flax, ramie, nettle, etc., and different mixtures of such fibres 审中-公开的纤维素纺织材料的官能化（纤维，纱线，织物和针织），例如棉，麻，苎麻，荨麻疹等，以及这些纤维的各种混合物
公开(公告)号：EP2703555A1
公开(公告)日：2014-03-05
申请号：EP13464004.4
申请日：2013-04-02
发明人： Sirghie, Cecilia , Botar, Alexandru
摘要： The functionalization process of cellulosic textile materials is characterised by the fact that in the first stage it is the cationization of the cellulosic material, in two treatment stages, followed by the actual functionalization stage of the cellulosic material, cationized in two treatment stages. The material's cationization is made in two stages. During the first stage, the treatment of the cellulosic textile material takes place in a strong alkaline environment, with solution of NaOH of HM 1:20, followed by washing, until it reaches neutralisation, and then treatment during the second stage, with cationization agent, 3-chloro-2-hydroxypropyl trimethylammonium chloride of 60% concentration in an alkaline environment, followed by washing, until it reaches neutralisation. The actual functionalization takes place in two stages. During the first stage, there is the reaction between the cationized textile material and the aqueous solution of excess POM, followed by wash of the POM excess. In the second stage, takes place the reaction between POM and Ag and Cu cations, followed by the treatment with the aqueous solution of NaBH 4 in order to obtain Ag and Cu nanoparticles.
摘要翻译： 纤维素纺织材料的官能化方法是通过在第一阶段是纤维素材料的两个处理阶段阳离子化的factthat，其次是纤维素材料的实际官能阶段，在两个治疗阶段阳离子化特征的。 该材料的阳离子化两个阶段取得。 在第一阶段期间，所述纤维素纺织材料的处理发生在强碱性环境下，与HM 1:20的氢氧化钠溶液，然后洗涤，直到它在第二阶段期间达中和，然后处理，用阳离子化剂 ，3-氯-2-羟丙基三甲基氯化铵的60％浓度的对碱性环境，通过洗涤其次，直到它到达中和。 实际的功能化发生在两个阶段。 在第一阶段期间，存在的阳离子化纺织材料和过量的POM的wässrige溶液中，然后由POM过量的洗涤之间的反应。 在第二阶段，需要将POM和Ag和Cu阳离子之间的反应，然后用NaBH 4，以获得Ag和Cu的纳米粒子的溶液wässrige治疗。
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