公开(公告)号：EP2692431A1

公开(公告)日：2014-02-05

申请号：EP12763133.1

申请日：2012-03-14

申请人： Japan Oil, Gas and Metals National Corporation ,  INPEX Corporation ,  JX Nippon Oil & Energy Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel & Sumikin Engineering Co., Ltd.

发明人： NAGAYASU Yoshiyuki ,  ONO Hideki ,  HAYASAKA Kazuaki ,  YOKOI Mayumi

IPC分类号： B01J23/75 ,  C10G2/00 ,  C07B61/00

CPC分类号： C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100°C is within a range from 0.40 to 1.0 ml/g.

摘要翻译： 费 - 托合成反应的催化剂包括负载在所述催化剂载体在催化剂载体含有以质量基于催化剂载体的质量的0.5至14％量的二氧化硅和氧化锆和钴金属及钴氧化物 相当于10至40％的量通过基于催化剂的重量，worin还原钴原子的程度四氧化三钴的质量的范围内75〜93％，氢气吸附每单位质量的量 在100℃下将催化剂从00:40至1.0毫升/克的范围内。

公开(公告)号：EP2468840A1

公开(公告)日：2012-06-27

申请号：EP10809858.3

申请日：2010-08-06

申请人： JX Nippon Oil & Energy Corporation

发明人： HAYASAKA Kazuaki ,  ONO Hideki ,  NAGAYASU Yoshiyuki ,  TAGUCHI Masahiro ,  IKI Hideshi

IPC分类号： C10G65/12 ,  C10G45/60 ,  C10G45/62 ,  C10M101/02 ,  C10M105/04 ,  C10N20/00 ,  C10N20/02 ,  C10N20/06

CPC分类号： C10G65/02 ,  B01J21/066 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J29/7484 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03 ,  C10G45/58 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M101/02 ,  C10M2203/1025 ,  C10M2205/173 ,  C10N2220/026 ,  C10N2220/027 ,  C10N2220/028 ,  C10N2220/031 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2230/43 ,  C10N2240/10 ,  C10N2270/00 ,  C10N2220/022

摘要： A method for producing a lubricant base oil, comprising: a first step of contacting a feedstock containing normal paraffins having not less than 20 carbon atoms with a first catalyst in the presence of molecular hydrogen to obtain a first produced oil, and a second step of contacting the first produced oil with a second catalyst in the presence of molecular hydrogen to obtain a second produced oil, wherein the first catalyst comprises a first carrier in which a fraction of an amount of NH 3 to be desorbed at 300 to 800°C based on a total amount of NH 3 to be desorbed is 80 to 90% in temperature-programmed desorption of NH 3 , a first metal that is at least one selected from metals that belong to Group VI in the periodic table and is carried on the first carrier, and a second metal that is at least one selected from metals that belong to Group VIII to Group X in the periodic table and is carried on the first carrier; a sum C 1 + C 2 of a proportion C 1 of the first metal contained in the first catalyst in terms of an oxide (% by mass) and a proportion C 2 of the second metal contained in the first catalyst in terms of an oxide (% by mass) is 22 to 36% by mass; and a ratio D 1 /D 2 between a content of the second metal D 2 (mol) and a content of the first metal D 1 (mol) in the first catalyst is 1.07 to 7.78.

摘要翻译： 一种润滑油基油的制造方法，其特征在于，包括：在分子氢存在下使含有不少于20个碳原子的正链烷烃的原料与第一催化剂接触的第一工序，得到第一生产油，第二工序 在分子氢存在下使第一产生的油与第二催化剂接触以获得第二产生的油，其中第一催化剂包含第一载体，其中一部分在300至800℃下解吸的NH 3的量为基于 NH 3的总量将在NH 3的温度程序解吸中为80〜90％，NH 3是选自元素周期表中属于Ⅵ族的金属中的至少一种的第一种金属， 载体和选自属于周期表中第VIII族至第X族的金属中的至少一种的第二种金属，并携带在第一载体上; 以氧化物（质量％）表示的第一催化剂中含有的第一金属的比例C 1与第一催化剂中所含的第二金属的比例C 2的氧化物的总和C 1 + C 2 （质量％）为22〜36质量％ 并且第一催化剂中第二金属D 2（摩尔）的含量与第一金属D 1（摩尔）的含量之比D 1 / D 2为1.07〜7.78。

公开(公告)号：EP2898947A1

公开(公告)日：2015-07-29

申请号：EP13838141.3

申请日：2013-09-12

申请人： JX Nippon Oil & Energy Corporation

发明人： NAGAYASU Yoshiyuki ,  HAYASAKA Kazuaki ,  KOSAKA Eri ,  TAKAHAMA Koshi

IPC分类号： B01J23/75 ,  B01J32/00 ,  B01J37/08 ,  C07C1/04 ,  C07C9/00 ,  C10G2/00 ,  C07B61/00

CPC分类号： B01J23/75 ,  B01J21/08 ,  B01J23/462 ,  B01J23/8913 ,  B01J32/00 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0244 ,  B01J37/08 ,  B01J37/18 ,  C10G2/00 ,  C10G2/332 ,  C10G2/333 ,  C10G2/334

摘要： A process for producing a Fischer-Tropsch synthesis catalyst according to the present invention comprises a step of calcining a carrier precursor containing silica calcined at a temperature T 1 and a zirconium compound at a temperature T 2 to obtain a carrier; and a step of calcining a catalyst precursor containing the carrier and a cobalt compound and/or a ruthenium compound at a temperature T 3 , wherein the content of the zirconium compound in the carrier precursor is 0.01 to 7% by mass in terms of zirconium oxide based on the total mass of the catalyst, and T 1, T 2 , and T 3 satisfy conditions represented by expressions (1) to (3): T 1 ≥ T 3 250 ⁢ °C ≤ T 2 ≤ 450 ⁢ °C 250 ⁢ °C ≤ T 3 ≤ 450 ⁢ °C

摘要翻译： 一种用于生产费 - 托合成催化剂gemäß到本发明的方法包括煅烧的载体前体含有二氧化硅在温度T 1和在温度T 2的锆化合物，以获得载体煅烧的步骤; 和煅烧催化剂前体含有载体和钴化合物和/或在温度T 3钌化合物，worin在载体前体的锆化合物的含量的步骤是0点01分至7质量％的氧化锆计 基于催化剂的总质量，和T 1，T 2和T 3满足由表达式表示的条件（1）〜（3）：T 1‰¥吨3 250℃¢‰¤Ť2‰¤450 ¢℃，250℃¢‰¤Ť3‰¤¢450℃