摘要:
A particulate inorganic mixed oxide comprising: aluminum; zirconium; cerium; and first and second additional elements each selected from the group consisting of rare earth elements other than cerium and alkaline earth elements, wherein a content of aluminum in the inorganic mixed oxide is 60 to 90 at%, in terms of element content, relative to a total amount of elements which form cations in the inorganic mixed oxide; a content of cerium in the inorganic mixed oxide is 0.4 to 50 at%, in terms of element content, relative to a total amount of zirconium and cerium in the inorganic mixed oxide; a content of a total amount of the first and second additional elements is 1 to 12 at%, in terms of element content, relative to the total amount of the elements which form cations in the inorganic mixed oxide; at least 80% of primary particles of the inorganic mixed oxide have a particle diameter of 100 nm or less; at least a part of the primary particles have an enriched surface region where a content of the second additional element is locally increased in a surface layer portion thereof; and an amount of the second additional element in the enriched surface region is 0.1 to 0.95% by mass, in terms of oxide, relative to a whole amount of the inorganic mixed oxide.
摘要:
The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end and a downstream end. The first catalyst layer contains first catalyst particles and lies on the substrate across a first region extending between the upstream end and a first position. The first position is at a first distance from the upstream end toward the downstream end. The second catalyst layer contains second catalyst particles and lies on the first catalyst layer across the first region. The second catalyst layer is provided with pores. Pore connectivity of the second catalyst layer is 5% to 35%. A mean value of areas of the pores of the second catalyst layer in a cross-sectional backscattered electron image of the second catalyst layer may be 0.7 µm2 to 9.0 µm2.
摘要:
A catalyst for purification of exhaust gas in which a noble metal is supported on a metal-oxide support wherein, in a oxidation atmosphere, the noble metal exists on the surface of the support in high oxidation state, and the noble metal binds with a cation of the support via an oxygen atom on the surface of the support to form a surface oxide layer and, in a reduction atmosphere, the noble metal exists on the surface of the support in a metal state, and an amount of noble metal exposed at the surface of the support, measured by CO chemisorption, is 10% or more in atomic ratio to a whole amount of the noble metal supported on the support.
摘要:
Provided is a catalyst for purification of exhaust gas, which comprises a noble metal supported on a catalyst support comprising a predetermined amount of ceria supported on a surface of a composite oxide composed of alumina, zirconia, and titania, exhibiting a high heat resistance and a high catalytic activity; further, a NOx storage-reduction catalyst comprising the catalyst for purification of exhaust gas and a NOx storage material (such as alkali and alkaline earth metal(s)) promotes sulfur desorption during a reduction treatment, readily recovering the catalytic performance, and exhibiting a high NOx purifying activity even when the NOx storage-reduction catalyst is exposed to sulfur.
摘要:
A method for producing iron-supporting chabazite-type zeolite, comprising the following steps in order: mixing iron(II) chloride and chabazite-type zeolite, heat treating under a reducing atmosphere, and a hydrogen reducing.
摘要:
An exhaust gas purifying catalyst includes a substrate (1) that defines an exhaust gas passage; a lower catalyst layer (2) formed over the substrate, and an upper catalyst layer (3) formed over the lower catalyst layer (2). The lower catalyst layer (2) has a lower catalytic precious metal that contains at least one of Pt and Pd, and a lower-layer carrier that supports the lower catalytic precious metal. The upper catalyst layer (3) has an upper catalytic precious metal that contains Rh, and an upper-layer carrier that supports the upper catalytic precious metal. The upper-layer carrier comprises an inorganic mixed oxide that contains Ce, Zr, Al, Nd, and at least one element selected from the group consisting of rare earth elements other than Ce. The inorganic mixed oxide has interior regions containing a mixed aggregate composed of first particles comprising Ce and Zr in a form of a composite oxide, and second particles comprising Al in a form of alumina, and has cover layers containing Nd that cover surfaces of the respective interior regions. The Nd is unevenly present in the cover layers or the Nd is concentrated in the cover layers.