公开(公告)号：EP1249343A2

公开(公告)日：2002-10-16

申请号：EP02008135.2

申请日：2002-04-11

申请人： Kodak Polychrome Graphics GmbH

发明人： Müller, Ursula ,  Wittig, Tobias ,  Timpe, Hans-Joachim

IPC分类号： B41C1/10

CPC分类号： B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/22 ,  B41C2210/24 ,  B41M5/465 ,  Y10S430/116 ,  Y10S430/117 ,  Y10S430/118 ,  Y10S430/119 ,  Y10S430/12 ,  Y10S430/121 ,  Y10S430/126 ,  Y10S430/127 ,  Y10S430/145 ,  Y10S430/146

摘要： The present invention relates to IR-sensitive compositions containing an initator system comprising:

(a) at least one compound capable of absorbing IR radiation selected from triarylamine dyes, thiazolium dyes, indolium dyes, oxazolium dyes, cyanine dyes, polyaniline dyes, polypyrrole dyes, polythiophene dyes and phthalocyanine pigments
(b) at least one compound capable of producing radicals selected from polyhaloalkyl-substituted compounds
(c) at least one polycarboxylic acid represented by the following formula I

        R 4 -(CR 5 R 6 ) r -Y-CH 2 COOH     (I)

wherein Y is selected from the group consisting of O, S and NR 7 , each of R 4 , R 5 and R 6 is independently selected from the group consisting of hydrogen, C 1 -C 4 alkyl, aryl which is optionally substituted, -COOH and NR 8 CH 2 COOH,
R 7 is selected from the group consisting of hydrogen, C 1 -C 6 alkyl, -CH 2 CH 2 OH, and C 1 -C 5 alkyl substituted with -COOH,
R8 is selected from the group consisting of -CH 2 COOH, -CH 2 OH and -(CH 2 ) 2 N(CH 2 COOH) 2
and r is 0, 1, 2 or 3
with the proviso that at least one of R 4 , R 5 , R 6 , R 7 and R 8 comprises a -COOH group
or salts thereof, and
(d) at least one leuco dye,
wherein the following inequation is met:

        ox a b + 1.6 eV

   with ox a = oxidation potential of component (a) in eV
      red b = reduction potential of component (b) in eV
These compositions are inter alia extraordinarily suitable for the manufacture of printing plates.

摘要翻译： 本发明涉及含有引发剂体系的IR敏感性组合物，其包含：（a）至少一种能够吸收选自三芳基胺染料，噻唑鎓染料，吲哚鎓染料，恶唑鎓染料，花青染料，聚苯胺染料，聚吡咯染料， 聚噻吩染料和酞菁颜料（b）至少一种能够产生选自多卤烷基取代的化合物的基团的化合物（c）至少一种由下式IR 4 - （CR 5 R 6）表示的多元羧酸， RY-CH2COOH其中Y选自O，S和NR 7，R 4，R 5和R 6各自独立地选自氢，C 1 -C 4 烷基，任选取代的芳基，-COOH和NR 8 CH 2 COOH，R 7选自氢，C 1 -C 6烷基，-CH 2 CH 2 OH和被-COOH取代的C 1 -C 5烷基，R 8是 选自-CH 2 COOH，-CH 2 OH和 - （CH 2）2 N（CH 2 COOH）2，且r为0， 1,2或3，条件是R 4，R 5，R 6，R 7和R 8中的至少一个包含-COOH基团或其盐，和（d） 至少一种无色染料，其中满足以下不符合要求：oxa

公开(公告)号：EP1249343A3

公开(公告)日：2004-01-02

申请号：EP02008135.2

申请日：2002-04-11

申请人： Kodak Polychrome Graphics GmbH

发明人： Müller, Ursula ,  Wittig, Tobias ,  Timpe, Hans-Joachim

IPC分类号： B41C1/10

CPC分类号： B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/22 ,  B41C2210/24 ,  B41M5/465 ,  Y10S430/116 ,  Y10S430/117 ,  Y10S430/118 ,  Y10S430/119 ,  Y10S430/12 ,  Y10S430/121 ,  Y10S430/126 ,  Y10S430/127 ,  Y10S430/145 ,  Y10S430/146

摘要： The present invention relates to IR-sensitive compositions containing an initator system comprising: (a) at least one compound capable of absorbing IR radiation selected from triarylamine dyes, thiazolium dyes, indolium dyes, oxazolium dyes, cyanine dyes, polyaniline dyes, polypyrrole dyes, polythiophene dyes and phthalocyanine pigments (b) at least one compound capable of producing radicals selected from polyhaloalkyl-substituted compounds (c) at least one polycarboxylic acid represented by the following formula IR4-(CR5R6)r-Y-CH2COOH wherein Y is selected from the group consisting of O, S and NR7, each of R4, R5 and R6 is independently selected from the group consisting of hydrogen, C1-C4 alkyl, aryl which is optionally substituted, -COOH and NR8CH2COOH, R7 is selected from the group consisting of hydrogen, C1-C6 alkyl, -CH2CH2OH, and C1-C5 alkyl substituted with -COOH, R8 is selected from the group consisting of -CH2COOH, -CH2OH and -(CH2)2N(CH2COOH)2 and r is 0, 1, 2 or 3 with the proviso that at least one of R4, R5, R6, R7 and R8 comprises a -COOH group or salts thereof, and (d) at least one leuco dye, wherein the following inequation is met:ox a b + 1.6 eV    with ox a = oxidation potential of component (a) in eV       red b = reduction potential of component (b) in eV These compositions are inter alia extraordinarily suitable for the manufacture of printing plates.