LITHIUM SECONDARY BATTERY
    1.
    发明公开

    公开(公告)号:EP4398375A1

    公开(公告)日:2024-07-10

    申请号:EP22878891.5

    申请日:2022-10-05

    摘要: The present invention relates to a lithium secondary battery comprising: an anode including an anode active material; a cathode including a cathode active material; a separator interposed between the anode and the cathode; and an electrolyte, wherein the anode active material includes silicon particles, the cathode active material includes a lithium manganese-based oxide represented by [chemical formula 1], the Si depth of charge, represented by the following formula (1), is 30% to 60%, and the Si depth of discharge, represented by the following formula (2), is 10% or more. Formula (1): Si depth of charge (%) = {(cathode loading amount + anode pre-lithiation capacity)/anode loading amount} ×100, and Formula (2): Si depth of discharge (%) = {(cathode loading amount + anode pre-lithiation capacity - discharge loading amount) /anode loading amount} ×100, wherein in formulae (1) and (2), the cathode loading amount is the capacity per unit area of the cathode (unit: mAh/cm2), the anode loading amount is the capacity per unit area of the anode (unit: mAh/cm2), the anode pre-lithiation capacity is the capacity per unit area of lithium (Li) intercalated into the anode by pre-lithiation (unit: mAh/cm2), and the discharge loading amount is a value obtained by dividing the discharge capacity of the secondary battery by the cathode area at the discharge cut-off voltage.

    METHOD FOR MANUFACTURING ANODE
    4.
    发明公开

    公开(公告)号:EP4084131A1

    公开(公告)日:2022-11-02

    申请号:EP21775423.3

    申请日:2021-03-24

    摘要: Provided is a method of manufacturing a negative electrode, which includes: applying a negative electrode slurry on a negative electrode current collector and subjecting the applied negative electrode slurry to a first roll-pressing to form a negative electrode active material layer; pre-lithiating the negative electrode active material layer; and subjecting the pre-lithiated negative electrode active material layer to a second roll-pressing, wherein the negative electrode active material layer includes a silicon-based active material, and a ratio (p 1 /p 2 ) of porosity (p 1 ) of negative electrode active material layer after the first roll-pressing to porosity (p 2 ) of negative electrode active material layer after the second roll-pressing is in a range of 1.05 to 1.65.