公开(公告)号：EP2878033A2

公开(公告)日：2015-06-03

申请号：EP13822701.2

申请日：2013-07-23

申请人： Lockheed Martin Advanced Energy Storage, LLC

发明人： AMADEO, Desiree ,  ESSWEIN, Arthur J. ,  GOELTZ, John ,  JARVI, Thomas D. ,  KING, Evan R. ,  REECE, Steven Y. ,  TYAGI, Nitin

IPC分类号： H01M10/42

CPC分类号： H01M10/4242 ,  H01M8/188 ,  Y02E60/528

摘要： This invention is directed to aqueous redox flow batteries comprising redox-active metal ligand coordination compounds. The compounds and configurations described herein enable flow batteries with performance and cost parameters that represent a significant improvement over that previous known in the art.

公开(公告)号：EP2878026A1

公开(公告)日：2015-06-03

申请号：EP13823245.9

申请日：2013-07-24

申请人： Lockheed Martin Advanced Energy Storage, LLC

发明人： AMADEO, Desiree ,  ESSWEIN, Arthur, J. ,  GOELTZ, John ,  JARVI, Thomas, D. ,  KING, Evan, R. ,  MADDEN, Thomas, H. ,  REECE, Steven, Y. ,  TYAGI, Nitin

IPC分类号： H01M8/00 ,  H01M4/13

CPC分类号： H01M8/188 ,  H01M8/1053 ,  H01M8/1055 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/528

摘要： This invention is directed to aqueous redox flow batteries comprising ionically charged redox active materials and separators, wherein the separator is about 100 microns or less and the flow battery is capable of (a) operating with a current efficiency of at least 85% with a current density of at least about 100 mA/cm
2 ; (b) operating with a round trip voltage efficiency of at least 60% with a current density of at least about 100 mA/cm
2 ; and / or (c) giving rise to diffusion rates through the separator for the first active material, the second active material, or both, of about 1x10
-7 mol/cm
2 -sec or less.

公开(公告)号：EP2878021A1

公开(公告)日：2015-06-03

申请号：EP13823283.0

申请日：2013-07-24

申请人： Lockheed Martin Advanced Energy Storage, LLC

发明人： AMADEO, Desiree ,  ESSWEIN, Arthur J. ,  GOELTZ, John ,  JARVI, Thomas D. ,  KING, Evan R. ,  REECE, Steven Y. ,  TYAGI, Nitin

IPC分类号： H01M4/13 ,  H01M8/00

CPC分类号： H01M8/188 ,  H01M4/96 ,  H01M8/0234 ,  H01M8/04298 ,  H01M8/20 ,  Y02E60/528

摘要： The invention concerns flow batteries comprising: a first aqueous electrolyte comprising a first redox active material; a second aqueous electrolyte comprising a second redox active material; a first electrode in contact with the first aqueous electrolyte; a second electrode in contact with the second aqueous electrolyte and a separator disposed between the first aqueous electrolyte and the second aqueous electrolyte; the flow battery having an open circuit potential of at least 1.4 V, and is capable of operating or is operating at a current density at least about 50 mA/cm2, wherein both of the first and second redox active materials remain soluble in both the charged and discharged states. In certain embodiments, the redox active materials are metal ligand coordination compounds. The disclosure also describes systems comprising these flow batteries and methods of them.

公开(公告)号：EP2885248A1

公开(公告)日：2015-06-24

申请号：EP13829203.2

申请日：2013-03-12

申请人： Lockheed Martin Advanced Energy Storage, LLC

发明人： GOELTZ, John ,  GOELTZ, John ,  ESSWEIN, Arthur, J. ,  AMADEO, Desiree

IPC分类号： C01C3/12

CPC分类号： H01M8/222 ,  H01M8/08 ,  H01M8/188 ,  H01M8/20 ,  H01M2300/0002 ,  Y02E60/528

摘要： Stable solutions comprising high concentrations of charged coordination complexes, including iron hexacyanides are described, as are methods of preparing and using same in chemical energy storage systems, including flow battery systems. The use of these compositions allows energy storage densities at levels unavailable by other iron hexacyanide systems.

摘要翻译： 描述了包括带电配位络合物（包括六氰基铁）的稳定溶液，以及在化学能量存储系统（包括液流电池系统）中制备和使用它们的方法。 这些组合物的使用允许能量存储密度达到其他六氰基铁系统无法获得的水平。

公开(公告)号：EP2878020A1

公开(公告)日：2015-06-03

申请号：EP13822525.5

申请日：2013-07-24

申请人： Lockheed Martin Advanced Energy Storage, LLC

发明人： AMADEO, Desiree ,  ESSWEIN, Arthur, J, ,  GOELTZ, John ,  JARVI, Thomas, D. ,  KING, Evan, R. ,  REECE, Steven, Y. ,  TYAGI, Nitin

IPC分类号： H01M4/13 ,  H01M8/00

CPC分类号： H01M4/96 ,  H01M4/86 ,  H01M8/188 ,  H01M8/20 ,  Y02E60/528

摘要： The invention concerns flow batteries comprising: a first half-cell comprising: (i) a first aqueous electrolyte comprising a first redox active material; and a first carbon electrode in contact with the first aqueous electrolyte; (ii) a second half-cell comprising: a second aqueous electrolyte comprising a second redox active material; and a second carbon electrode in contact with the second aqueous electrolyte; and (iii) a separator disposed between the first half-cell and the second half-cell; the first half-cell having a half-cell potential equal to or more negative than about -0.3 V with respect to a reversible hydrogen electrode; and the first aqueous electrolyte having a pH in a range of from about 8 to about 13, wherein the flow battery is capable of operating or is operating at a current density at least about 25 mA/cm2 .