公开(公告)号：EP2512655A1

公开(公告)日：2012-10-24

申请号：EP10787215.2

申请日：2010-11-19

申请人： Lyondell Chemical Technology, L.P.

发明人： SHAY, Daniel, Travis

IPC分类号： B01J21/06 ,  B01J23/44 ,  B01J23/52 ,  C04B35/636 ,  C04B38/06 ,  C04B35/46 ,  B01J37/00 ,  C07C67/055

CPC分类号： C04B30/00 ,  B01J21/063 ,  B01J23/44 ,  B01J23/52 ,  B01J23/66 ,  B01J37/0018 ,  C04B24/383 ,  C04B26/285 ,  C04B35/46 ,  C04B35/462 ,  C04B35/465 ,  C04B35/49 ,  C04B35/6263 ,  C04B35/632 ,  C04B35/63488 ,  C04B35/6365 ,  C04B38/0645 ,  C04B2111/00129 ,  C04B2235/3217 ,  C04B2235/3244 ,  C04B2235/3418 ,  C04B2235/3445 ,  C04B2235/3463 ,  C04B2235/349 ,  C04B2235/6021 ,  C04B2235/606 ,  C04B2235/6562 ,  C04B2235/721 ,  C07C67/055 ,  C04B14/305 ,  C04B40/0268 ,  C04B38/067 ,  C07C69/15

摘要： An extrudate comprising titania, a carboxyalkyl cellulose, and a hydroxyalkyl cellulose is disclosed. The extrudates have a smooth outer surface when they exit the extruder. The extrusion processibility is improved.

公开(公告)号：EP2364208B1

公开(公告)日：2015-01-14

申请号：EP09748865.4

申请日：2009-10-27

申请人： Lyondell Chemical Technology, L.P.

发明人： SHAY, Daniel, Travis

IPC分类号： B01J23/68 ,  C07C67/055

CPC分类号： B01J23/687 ,  B01J23/002 ,  B01J2523/00 ,  C07C67/055 ,  C07C69/01 ,  B01J2523/13 ,  B01J2523/19 ,  B01J2523/47 ,  B01J2523/69 ,  B01J2523/824 ,  C07C69/15

公开(公告)号：EP2544815A1

公开(公告)日：2013-01-16

申请号：EP10784629.7

申请日：2010-11-19

申请人： Lyondell Chemical Technology, L.P.

发明人： SHAY, Daniel, Travis

IPC分类号： B01J21/06 ,  B01J23/44 ,  B01J23/52 ,  C04B35/636 ,  C04B38/06 ,  C04B35/46 ,  B01J37/00 ,  C07C67/055 ,  B01J37/02 ,  B01J23/66

CPC分类号： C04B30/00 ,  B01J21/063 ,  B01J23/44 ,  B01J23/52 ,  B01J23/66 ,  B01J37/0018 ,  C04B26/285 ,  C04B35/46 ,  C04B35/63488 ,  C04B35/6365 ,  C04B38/0645 ,  C04B2111/00129 ,  C04B2111/0081 ,  C04B2235/3217 ,  C04B2235/656 ,  C07C67/055 ,  C04B14/303 ,  C04B14/305 ,  C04B38/067 ,  C07C69/15

摘要： A catalyst comprising palladium supported on a titania-alumina extrudate is disclosed. The extrudate comprises at least 80 wt% titania and 0.1 to 15 wt% alumina. A palladium catalyst prepared from the titania-alumina extrudate has significantly higher crush strength. Its catalytic performance in vinyl acetate production is improved.

公开(公告)号：EP2512654A1

公开(公告)日：2012-10-24

申请号：EP10779908.2

申请日：2010-11-19

申请人： Lyondell Chemical Technology, L.P.

发明人： SHAY, Daniel, Travis

IPC分类号： B01J21/06 ,  B01J23/44 ,  B01J23/52 ,  C04B35/636 ,  C04B38/06 ,  C04B35/46 ,  B01J37/00 ,  C07C67/055

CPC分类号： C04B30/00 ,  B01J21/063 ,  B01J23/44 ,  B01J23/52 ,  B01J23/66 ,  B01J37/0018 ,  C04B24/383 ,  C04B26/285 ,  C04B35/46 ,  C04B35/462 ,  C04B35/465 ,  C04B35/49 ,  C04B35/6263 ,  C04B35/632 ,  C04B35/63488 ,  C04B35/6365 ,  C04B38/0645 ,  C04B2111/00129 ,  C04B2235/3217 ,  C04B2235/3244 ,  C04B2235/3418 ,  C04B2235/3445 ,  C04B2235/3463 ,  C04B2235/349 ,  C04B2235/6021 ,  C04B2235/606 ,  C04B2235/6562 ,  C04B2235/721 ,  C07C67/055 ,  C04B14/305 ,  C04B40/0268 ,  C04B38/067 ,  C07C69/15

摘要： A method for preparing a palladium-gold catalyst containing a titania extrudate is disclosed. The titania extrudate is produced by using a carboxyalkyl cellulose and a hydroxyalkyl cellulose as extrusion aids. The titania extrudate has improved processibility and/or mechanical properties. After calcination, the extrudate is used as a carrier for the palladium-gold catalyst. The catalyst is useful in producing vinyl acetate by oxidizing ethylene with oxygen in the presence of acetic acid.

公开(公告)号：EP2364208A1

公开(公告)日：2011-09-14

申请号：EP09748865.4

申请日：2009-10-27

申请人： Lyondell Chemical Technology, L.P.

发明人： SHAY, Daniel, Travis

IPC分类号： B01J23/68 ,  C07C67/055

CPC分类号： B01J23/687 ,  B01J23/002 ,  B01J2523/00 ,  C07C67/055 ,  C07C69/01 ,  B01J2523/13 ,  B01J2523/19 ,  B01J2523/47 ,  B01J2523/69 ,  B01J2523/824 ,  C07C69/15

摘要： Disclosed is a catalyst. The catalyst comprises palladium, gold, and a support comprising titanium dioxide and tungsten trioxide. The support preferably comprises from 75 wt% to 99 wt% of titanium dioxide and from 1 wt% to 25 wt% of tungsten trioxide. A method for preparing the catalyst is also disclosed. The method comprises impregnating the support with a palladium compound and a gold compound, calcining the impregnated support, and then reducing the calcined support. Further disclosed is a method for preparing vinyl acetate with the catalyst. The catalyst exhibits improved catalytic activity and selectivity.