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1.发明授权
公开(公告)号：EP1144534B2
公开(公告)日：2013-03-06
申请号：EP98965528.7
申请日：1998-12-29
IPC分类号： C09J153/00 , C09J7/02 , C08F297/02 , C08F293/00
CPC分类号： C09J153/00 , C08F293/005 , C08F297/026 , C08L53/00 , C08L2666/02 , C08L2666/24 , C09J7/387
摘要： Hot-melt processable adhesive, such as pressure-sensitive-adhesive (PSA) or heat-activatable adhesive, compositions of the present invention possess a broad formulation latitude and adequate cohesive strength after application for use in high performance applications. Hot-melt processable adhesives of the invention comprise at least one block copolymer comprising at least two A blocks and at least one B block. The A and B blocks are derived from monoethylenically unsaturated monomers, which monomers result in saturated polymer backbones without the need for subsequent hydrogenation upon their polymerization. Preferably, the block copolymer is a (meth)acrylate block copolymer.
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公开(公告)号：EP1163307B1
公开(公告)日：2004-06-02
申请号：EP99911480.4
申请日：1999-03-19
发明人： DANIELS, Michael, P. , CHEN, Yen-Lane , EVERAERTS, Albert, I. , KRAMPE, Stephen, E. , YOUNG, James, K.
IPC分类号： C09J4/06 , C09J151/08 , C08F283/06 , C09J133/06 , C09J157/10 , C09J171/00 , A61L15/58
CPC分类号： C09J151/08 , A61L15/585 , C08F283/06 , C08L2666/04 , C08L2666/28 , C09J133/064 , C09J171/02 , C09J2201/606 , C08L33/06 , C08F220/10
摘要： A wet stick pressure sensitive adhesive comprising the solventless polymerization product of: a) about 30 to about 70 parts by weight of an (meth)acrylate ester monomer wherein the (meth)acrylate ester monomer, when homopolymerized, has a Tg of less than about 10 DEG C; b) about 70 to about 30 parts by weight of a hydrophilic acidic comonomer; and c) about 10 to 100 parts based on 100 parts of the sum of components (a + b) of a non-reactive plasticizing agent, wherein the pressure sensitive adhesive adheres to wet substrate surfaces and a method of making.
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3.发明授权
公开(公告)号：EP0889935B1
公开(公告)日：2003-09-24
申请号：EP96923723.9
申请日：1996-07-09
CPC分类号： C09D4/00 , C09J7/201 , C09J7/22 , Y10T428/31667 , Y10T428/31692 , Y10T428/31721 , Y10T428/31797 , Y10T428/31826 , Y10T428/31909 , Y10T428/31993 , C08F220/10
摘要： Compositions containing conductivity enhancers, which are capable of being coated onto a substrate by means of electrostatic assistance. The compositions comprise one or more free-radically curable monomer(s), and one or more non-volatile conductivity enhancer(s), having cationic and anionic portions, which are soluble in the monomer(s) and which do not interfere with free-radical polymerization, wherein said anionic portion is a non-coordinating organophilic carbon-containing anion. The compositions may further comprise one or more initiator(s), one or more dissociation enhancing agent(s), cross-linking agent(s), cationically polymerizable monomer(s), cationic initiator(s), leveling agents, oligomer(s) or polymer(s), preferably co-reactive, and other additives or adjuvants to impart specific properties to the cured coating.
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4.发明授权POLYDIORGANOSILOXANE OLIGOUREA SEGMENTED COPOLYMERS AND A PROCESS FOR MAKING SAME 失效基于分段聚二oligourea共聚物及其制备方法
公开(公告)号：EP0822952B1
公开(公告)日：2003-07-23
申请号：EP96913846.0
申请日：1996-04-25
发明人： SHERMAN, Audrey, A. , ROMANKO, Walter, R. , EVERAERTS, Albert, I. , LEIR, Charles, M. , MAZUREK, Mieczyslaw, H. , NELSON, Constance, J.
CPC分类号： C08G18/289 , C08G18/61 , C08G18/71 , C08G18/718 , C08G18/8108 , C08G18/833 , C08G77/458 , C08G2190/00
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5.发明公开CURE-ON-DEMAND, MOISTURE-CURABLE COMPOSITIONS HAVING REACTIVE SILANE FUNCTIONALITY 失效具有活性硅烷官能度的可按需固化的组合物
公开(公告)号：EP0966503A1
公开(公告)日：1999-12-29
申请号：EP98910362.0
申请日：1998-03-12
发明人： LIU, Junkang , LEIR, Charles, M. , MOORE, George, G., I. , SHERMAN, Audrey, A. , EVERAERTS, Albert, I. , BOULOS, Marie, A.
CPC分类号： C08L101/10 , C08K5/5415 , C08L2666/28
摘要： Cure-on-demand, moisture-curable compositions of one or more compounds comprising molecules having reactive silane functional groups and an acid generating material are taught herein. The acid generating material releases an acid upon exposure to heat, ultraviolet light, visible light, electron beam irradiation or microwave irradiation to initiate and accelerate the cross-linking reaction. Articles prepared using the moisture curable materials are also disclosed, as are methods of curing those materials.
摘要翻译： 本文中教导了一种或多种包含具有反应性硅烷官能团的分子和产酸材料的化合物的按需固化的湿固化组合物。 酸产生物质在暴露于热，紫外线，可见光，电子束照射或微波照射时释放酸以引发和加速交联反应。 也公开了使用可湿固化材料制备的制品，以及固化这些材料的方法。
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公开(公告)号：EP0889940A1
公开(公告)日：1999-01-13
申请号：EP96923712.0
申请日：1996-07-09
CPC分类号： C08F290/148 , C09D183/10 , Y10T428/31663 , Y10T428/31667 , Y10T442/2066 , Y10T442/218 , C08L2666/28
摘要： Free-radically polymerizable release coating compositions containing conductivity enhancers, which are capable of being electrosprayed onto a substrate. The compositions comprise (a) about 100 parts by weight of one or more free-radically polymerizable vinyl monomer(s), (b) from about 0.05 to about 250 parts by weight of one or more polydiorganosiloxane polymer(s) copolymerizable with the vinyl monomer(s), and (c) from about 0.10 to about 10 parts by weight, based on 100 parts by weight of (a) and (b), of one or more non-volatile conductivity enhancer(s), which are soluble in the monomer(s) and which do not interfere with polymerization, wherein the composition may be electrosprayed. The composition may further comprise from about 0.1 to about 5 parts by weight of one or more initiator(s) based on 100 parts by weight of monomer(s) and polydiorganosiloxane polymer(s). Another embodiment of the present invention further comprises at leas 0.1 part by weight, based on 100 parts by weight of monomer(s) and polydiorganosiloxane polymer(s), of one or more dissociation enhancing agent(s) soluble in the monomer(s).
摘要翻译： 含有导电增强剂的可自由基聚合的剥离涂层组合物，其能够被电喷射到基材上。 该组合物包含（a）约100重量份的一种或多种可自由基聚合的乙烯基单体，（b）约0.05至约250重量份的一种或多种可与乙烯基化合物共聚的聚二有机硅氧烷聚合物 单体和（c）基于100重量份的（a）和（b）约0.10至约10重量份的一种或多种可溶解的非挥发性导电增强剂 在单体中并且不干扰聚合，其中组合物可以是电喷雾的。 基于100重量份的单体和聚二有机硅氧烷聚合物，组合物可以进一步包含约0.1至约5重量份的一种或多种引发剂。 基于100重量份的单体和聚二有机硅氧烷聚合物，本发明的另一个实施方案进一步包含0.1重量份的一种或多种可溶于单体中的解离增强剂（一种或多种） 。
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公开(公告)号：EP1163308B1
公开(公告)日：2004-10-06
申请号：EP99912695.6
申请日：1999-03-19
IPC分类号： C09J133/08
CPC分类号： C09J133/06 , C08L2666/28 , C09J2201/606
摘要： Non-tacky, base polymers are plasticized into pressure-sensitive adhesives and comprise: a) about 100 parts by weight of a base copolymer having a Tg greater than about 0 DEG C, wherein the base copolymer is formed from and comprises: (1) about 50 to 70% by weight of a high Tg comonomer component, wherein the homopolymer formed from the high Tg comonomer component has a Tg of at least about 20 DEG C; (2) optionally, up to about 20% by weight based on the total weight of the base copolymer of an acidic comonomer; and (3) about 30 to 50% by weight of one or more low Tg (meth)acrylate comonomer, wherein the Tg homopolymer of the low Tg comonomer is less than about 20 DEG C, and b) about 1 to about 100 parts based on the base copolymer of a non-reactive, non-volatile, non-acrylic-based plasticizing agent.
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公开(公告)号：EP0883658B1
公开(公告)日：2000-11-15
申请号：EP97902947.7
申请日：1997-01-16
IPC分类号： C09J133/08 , B32B27/30
CPC分类号： C09J133/08 , C08L2666/02 , C09J2201/606 , Y10T428/28 , Y10T428/2809 , Y10T428/2852 , Y10T428/2891 , Y10T442/2738 , Y10T442/2754
摘要： Acrylate copolymer pressure sensitive adhesives (PSAs) which incorporate relatively small amounts of a plasticizer are disclosed. The resulting PSAs exhibit improved low temperature performance and minimal effect on other properties, when used as adhesives for graphic marking films. The adhesive system has been found to allow the graphic marking film to be applied at temperatures as low as 20 DEG F. (-7 DEG C.) and to improve the ability of the film to be applied to a substrate without trapping air between the marking film and the substrate. The adhesive system of the marking film also demonstrates resistance to tenting around the compound curved surfaces of rivet heads and corrugations typical of truck trailer sides.
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9.发明公开
公开(公告)号：EP0934360A1
公开(公告)日：1999-08-11
申请号：EP97943568.0
申请日：1997-09-25
发明人： SHERMAN, Audrey, A. , MAZUREK, Mieczyslaw, H. , ROMANKO, Walter, R. , HYDE, Patrick, D. , WONG, Roy , EVERAERTS, Albert, I.
CPC分类号： C09D183/10 , C08L83/10 , C08L2666/04 , C09J183/10
摘要： A mixture is provided comprising (a) at least one of an elastomeric thermoplastic, a non-elastomeric thermoplastic, an elastomeric thermoset and mixtures thereof, excluding polydiorganosiloxane fluids and (b) a polymer having soft polydiorganosiloxane units, hard polyisocyanate residue units, optionally, soft and/or hard organic polyamine residue units and terminal groups. The hard polyisocyanate residue and the hard polyamine residue comprise less than 50% by weight of the polydiorganosiloxane urea containing component. The polyisocyanate residue is the polyisocyanate minus the -NCO groups and the polyamine residue is the polyamine minus the -NH2 groups. The polyisocyanate residue is connected to the polyamine residue by urea linkages. The terminal groups are non-functional groups or functional groups. The polydiorganosiloxane urea containing component may be reactive under free-radical or moisture curing conditions. The mixture may also optionally contain tackifying materials, free radical initiators, crosslinking agents, cure catalysts, and nonreactive additives such as fillers, pigments, stabilizers, antioxidants, flame retardants, plasticizers, compatibilizers and the like.
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公开(公告)号：EP0888401A1
公开(公告)日：1999-01-07
申请号：EP96920350.0
申请日：1996-05-22
CPC分类号： A61L15/58 , A61K9/0009 , A61N1/0436 , A61N1/0456 , A61N1/0468 , C08K5/0016 , C08L2666/28 , C09J133/14 , C08L101/02
摘要： Ionically conductive adhesives are disclosed. The adhesives are prepared from zwitterionic polymers, preferably prepared from zwitterionic monomers. Medical devices, such as biomedical electrodes, skin coverings, and transdermal delivery devices using such adhesives so prepared are also disclosed.
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