摘要:
Provided are [1] a xylylenediamine composition containing xylylenediamine and 1,2-ditolylethane wherein the content of 1,2-ditolylethane is 0.001 to 0.02 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a diamine containing xylylenediamine, a dicarboxylic acid, and 1,2-ditolylethane into a reaction system and performing polycondensation reaction, wherein the amount of the 1,2-ditolylethane to be introduced is 0.001 to 0.02 parts by mass based on 100 parts by mass of the xylylenediamine.
摘要:
Capable of being provided are [1] a master batch comprising polyamide (X) comprising a diamine unit containing 70 mole % or more of a metaxylylenediamine unit and a dicarboxylic acid unit and an alkali compound (A), wherein an average particle diameter of the alkali compound (A) contained in the master batch is 50 µm or less; a contained number of particles having a particle diameter of exceeding 80 µm in 5 square millimeter of a cross section of the master batch is 1.5 particle or less; and a sum (m) of values obtained by multiplying a mole concentration of an alkali metal atom and a mole concentration of an alkaline earth metal atom each contained per g of the master batch by valencies thereof respectively is 60 µmol/g or more and 1710 µmol/g or less and [2] a production process for a polyamide resin composition prepared by making use of the master batch described in the above item [1]. Making use of the master batch of the present invention makes it possible to provide a polyamide resin composition which has a good appearance and a good color tone and which forms less gels in mold processing.
摘要:
Provided are [1] a xylylenediamine composition containing xylylenediamine and a compound represented by the following general formula (1), wherein the content of the compound represented by the general formula (1) is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine; and a method for producing a polyamide resin including the steps of introducing a compound represented by the following general formula (1), a diamine including xylylenediamine (but excluding the compound represented by the general formula (1)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the compound represented by the general formula (1) to be introduced is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine, where, in the general formula (1), n and m each independently represent an integer of 0 to 6, excluding the case where n and m are both 1.
摘要:
The present invention relates to a polyamide resin composition comprising polyamide (X) comprising a diamine unit containing 70 mol% or more of a metaxylylenediamine unit and a dicarboxylic acid unit and an alkali compound (A), wherein the following equations (1) to (4) are satisfied: 10 ‰¤ COOH - NH 2 ‰¤ 80 0.32 ‰¤ P
摘要:
The present invention relates to a polyamide resin composition comprising polyamide (X) comprising a diamine unit containing 70 mol% or more of a metaxylylenediamine unit and a dicarboxylic acid unit and an alkali compound (A), wherein the following equations (1) to (3) are satisfied; 0.03 ‰¤ P
摘要:
The present invention provides a multilayer plastic container capable of effectively preventing the degradation of content and a reduction in flavor such as taste or aroma, which are caused by oxygen. The multilayer plastic container of the present invention is a multilayer plastic container having at least one oxygen-absorbing layer and at least one oxygen-blocking layer, wherein the oxygen-absorbing layer is a layer formed from a thermoplastic polyester resin composition comprising a thermoplastic polyester resin and an oxygen absorber, and the content of the oxygen absorber to the total mass of the thermoplastic polyester resin composition is 0.01% to 3% by mass, the oxygen-blocking layer is a layer formed from a polyamide resin composition comprising a polyamide resin, and the content of a transition metal selected from the group consisting of cobalt, copper, cerium, aluminum and manganese to the total mass of the polyamide resin composition is less than 10 ppm, and at least one of the oxygen-absorbing layers is arranged on a side more inside than the oxygen-blocking layer.
摘要:
Provided are [1] a xylylenediamine composition containing xylylenediamine and a 5-membered or 6-membered heterocyclic compound (A) having at least one nitrogen-containing substituent and having two nitrogen atoms as atoms constituting a ring, wherein the content of the heterocyclic compound (A) is 0.001 to 0.02 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a 5-membered or 6-membered heterocyclic compound (A) having at least one nitrogen-containing substituent and having two nitrogen atoms as atoms constituting a ring, a diamine including xylylenediamine (but excluding a diamine corresponding to the above-mentioned heterocyclic compound (A)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the heterocyclic compound (A) to be introduced is 0.001 to 0.02 parts by mass based on 100 parts by mass of xylylenediamine.
摘要:
Provided are [1] a xylylenediamine composition containing xylylenediamine and a pyridine compound (A) having at least one substituent including an amino group, wherein the content of the pyridine compound (A) is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a pyridine compound (A) having at least one substituent including an amino group, a diamine including xylylenediamine (but excluding a diamine corresponding to the above-mentioned pyridine compound (A)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the pyridine compound (A) to be introduced is 0.001 to 0.1 parts by mass based on 100 parts by mass of xylylenediamine.