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公开(公告)号：EP0263678B1
公开(公告)日：1992-01-15
申请号：EP87308846.2
申请日：1987-10-06
CPC分类号： C08K5/20 , C08L23/02 , C08L23/26 , C08L71/123 , Y10S525/905 , C08L23/00 , C08L2666/22 , C08L2666/04
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公开(公告)号：EP0263678A2
公开(公告)日：1988-04-13
申请号：EP87308846.2
申请日：1987-10-06
CPC分类号： C08K5/20 , C08L23/02 , C08L23/26 , C08L71/123 , Y10S525/905 , C08L23/00 , C08L2666/22 , C08L2666/04
摘要： A resin composition is a blend of, by wt:
a) 20-80% of at least partly crystalline homo- or copolymer of an olefin, or an oxidation, halogenation or sulfonation product thereof (preferably of ethylene, propylene, butene-1, 3-methylbutene-1 or 4-methylpentene-1) which may include a rubbery α-olefin polymer;
b) 20-80% of a polyphenylene ether resin which can have up to 4 substituents (preferably dialkyl) on the phenylene ring, or a copolymer thereof;
c) 4-50% of a hydrogenated copolymer, of mol wt 5,000 to 500,000 g/mol, of a block of an alkenyl aromatic compound which can have various substituents on the benzene ring and alkenyl group (e.g. styrene) and 45-80 wt% of a block of a conjugated diene, the copolymer being hydrogenated so that up to 50% of the unsaturated bonds in the aliphatic chain are non-hydrogenated; and
optionally (a) up to 50 part, per 100 of (a)+(b)=(c), of a diamide compound.
The composition is easily molded to make components such as automobile parts having good mechanical properties.摘要翻译： 树脂组合物是以下重量的共混物：a）20-80％的至少部分结晶的烯烃的均聚物或共聚物或其氧化，卤化或磺化产物（优选乙烯，丙烯，丁烯-1， 3-甲基丁烯-1或4-甲基戊烯-1），其可以包括橡胶状α-烯烃聚合物; b）在亚苯基环上可具有至多4个取代基（优选二烷基）的聚亚苯基醚树脂20-80％，或其共聚物; c）4-50％的氢化共聚物，其摩尔重量为5,000至500,000g / mol，可在苯环和烯基（例如苯乙烯）上具有各种取代基的链烯基芳族化合物嵌段和45-80wt ％的共轭二烯嵌段，共聚物被氢化，使脂族链中至多50％的不饱和键未氢化; 和（a）至多50份（a）+（b）=（c））的二酰胺化合物。 该组合物易于模制以制备具有良好机械性能的部件如汽车部件。
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公开(公告)号：EP0263678A3
公开(公告)日：1988-07-20
申请号：EP87308846
申请日：1987-10-06
CPC分类号： C08K5/20 , C08L23/02 , C08L23/26 , C08L71/123 , Y10S525/905 , C08L23/00 , C08L2666/22 , C08L2666/04
摘要： A resin composition is a blend of, by wt:
a) 20-80% of at least partly crystalline homo- or copolymer of an olefin, or an oxidation, halogenation or sulfonation product thereof (preferably of ethylene, propylene, butene-1, 3-methylbutene-1 or 4-methylpentene-1) which may include a rubbery α-olefin polymer; b) 20-80% of a polyphenylene ether resin which can have up to 4 substituents (preferably dialkyl) on the phenylene ring, or a copolymer thereof; c) 4-50% of a hydrogenated copolymer, of mol wt 5,000 to 500,000 g/mol, of a block of an alkenyl aromatic compound which can have various substituents on the benzene ring and alkenyl group (e.g. styrene) and 45-80 wt% of a block of a conjugated diene, the copolymer being hydrogenated so that up to 50% of the unsaturated bonds in the aliphatic chain are non-hydrogenated; and
optionally (a) up to 50 part, per 100 of (a)+(b)=(c), of a diamide compound. The composition is easily molded to make components such as automobile parts having good mechanical properties.-
公开(公告)号：EP0369598A3
公开(公告)日：1991-03-20
申请号：EP89310462.0
申请日：1989-10-12
CPC分类号： C08L23/02 , C08L71/123 , Y10S525/905 , C08L2666/24 , C08L2666/22 , C08L2666/04
摘要： A resin compostion comprises from 20 to 77 wt.% of polyolefin (A); from 20 to 77 wt.% of polyphenylene ether resin (B); from 2 to 50 wt.% of polymer (C) having an alkenyl aromatic compound polymer chain (C1) and an aliphatic hydrocarbon chain (C2) in the same molecule, and also having a dynamic shearing modulus of elasticity G′ of at least 3 x 10⁸ dyn/cm²; and from 1 to 25 wt.% of an ester group containing ethylene copolymer (D) being a copolymer olefin comprising ethylene as principal component together with 8 to 43 wt.% of an unsaturated ester of the formula:
in which R¹ is a saturated C₁-C₅₀ hydrocarbon group containing or not containing an oxygen atom, an alicyclic hydrocarbon group or an aromatic hydrocarbon group; R2 is a hydrogen atom or a methyl group; and X and Y together are such that one of them is a direct bond and the other is an oxygen atom.-
公开(公告)号：EP0369598A2
公开(公告)日：1990-05-23
申请号：EP89310462.0
申请日：1989-10-12
CPC分类号： C08L23/02 , C08L71/123 , Y10S525/905 , C08L2666/24 , C08L2666/22 , C08L2666/04
摘要： A resin compostion comprises from 20 to 77 wt.% of polyolefin (A); from 20 to 77 wt.% of polyphenylene ether resin (B); from 2 to 50 wt.% of polymer (C) having an alkenyl aromatic compound polymer chain (C1) and an aliphatic hydrocarbon chain (C2) in the same molecule, and also having a dynamic shearing modulus of elasticity G′ of at least 3 x 10⁸ dyn/cm²; and from 1 to 25 wt.% of an ester group containing ethylene copolymer (D) being a copolymer olefin comprising ethylene as principal component together with 8 to 43 wt.% of an unsaturated ester of the formula:
in which R¹ is a saturated C₁-C₅₀ hydrocarbon group containing or not containing an oxygen atom, an alicyclic hydrocarbon group or an aromatic hydrocarbon group; R2 is a hydrogen atom or a methyl group; and X and Y together are such that one of them is a direct bond and the other is an oxygen atom.摘要翻译： 树脂组合物包含20至77重量％的聚烯烃（A）; 20〜77重量％的聚苯醚树脂（B）; 2至50重量％的在同一分子中具有链烯基芳族化合物聚合物链（C1）和脂肪族烃链（C2）的聚合物（C），并且还具有至少3的弹性动态剪切模量G' ×10 6 dyn / cm 2; 和1至25重量％的含酯基的乙烯共聚物（D），它是一种包含乙烯作为主要组分的共聚物烯烃以及8至43％（重量）的下式不饱和酯：其中R 1是饱和的C 1 含有或不含有氧原子，脂环族烃基或芳香族烃基的-C 50烃基; R2是氢原子或甲基; 并且X和Y一起是其中一个是直接键而另一个是氧原子。
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6.发明授权Process for the preparation of Polyphenylene ether-polyamide resin compositions 失效一种用于生产基于聚苯醚和聚酰胺的树脂组合物的方法。
公开(公告)号：EP0270796B1
公开(公告)日：1994-01-19
申请号：EP87115601.4
申请日：1987-10-23
CPC分类号： C08L71/123 , C08L63/00 , C08L71/00 , C08L75/00 , C08L77/04 , C08L81/00 , C08L83/04 , C08L77/00 , C08L2666/14
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7.发明公开Moldable composition of polyphenylene ether and polyamide resin 无效Formmasse aus Polyphenenether und Polyamidharz。
公开(公告)号：EP0225170A1
公开(公告)日：1987-06-10
申请号：EP86309224.3
申请日：1986-11-26
CPC分类号： C08L71/123 , C08L53/02 , C08L77/00 , Y10S525/905 , C08L2666/14 , C08L2666/02 , C08L2666/22 , C08L2666/04
摘要： A moldable composition comprises; by weight of components (1) + (2);
(1) 50-97% of a polyphenylene ether (which may be a copolymer), e.g. poly(2,6-dimethylphenol), of a mol. wt. so as to have intrinsic viscosity of 0.35-0.7 dl/g at 30°C, and a polyamide resin (e.g. a nylon);
(2) 3-50% of a block copolymer A-B A-B A) n where m =0 or an integer, n =0 or 1, A is an aromatic vinyl compound (e.g. styrene) and B is a conjugated diene (e.g. butadiene) and may include another hydrocarbon; block A content is 20-50%; the copolymer having a solution viscosity at 25°C of 200-100,000 cps; and
(3) 0.01-30% of a compound having in its molecule an unsaturated bond and a polar group, e.g. having affinity to the amido link in the polyamide (e.g. an unsaturated dicarboxylic acid or an hydride).
The composition is moldable and has good mechanical strength and solvent resistance.摘要翻译： 可成型组合物包含： 的组分（1）+（2）; ......（1）50-97％的聚苯醚（其可以是共聚物），例如 聚（2,6-二甲基苯酚） 重量。 在30℃下的特性粘度为0.35〜0.7dl / g，聚酰胺树脂（例如尼龙）等。 ...（2）3-50％的嵌段共聚物AB @@ AB @@@ A）n其中m = 0或整数n = 0或1，A为芳族乙烯基化合物（如苯乙烯），B为 共轭二烯（例如丁二烯），并且可以包括另一种烃; 块A含量为20-50％; 该共聚物在25℃下的溶液粘度为200-100,000cps; 和（3）0.01-30％的分子中具有不饱和键和极性基团的化合物，例如， 对聚酰胺中的酰胺键具有亲和性（例如不饱和二羧酸或氢化物）。 ......组合物是可成型的，具有良好的机械强度和耐溶剂性。
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8.发明公开Resin composition containing a polyamide and a polyphenylene ether 失效Polyamid和Polyphenenätherenthaltende Harzzusammensetzung。
公开(公告)号：EP0248526A1
公开(公告)日：1987-12-09
申请号：EP87303766.7
申请日：1987-04-28
CPC分类号： C08K5/372 , C08L71/00 , C08L71/123 , C08L75/00 , C08L77/00 , C08L81/00 , C08L2666/22 , C08L2666/02
摘要： A blend is made of, by weight (a) 10-70 parts of a polyphenylene ether which may have various substituents on the phenyl nucleus, and has at least 50 recurring units, (b) 30-90 parts of a polyamide (a nylon) and optionally (c) 3-50% of a rubbery polymer which is elastic at room temperature (e.g. a copolymer of an aromatic vinyl compound and a conjugated diene); and as a stabilizer, a thioether compound (preferably of formula R⁰-S-CHR¹R², where the Rs are hydrocarbon or substituted hydrocarbon groups of 1-35 C atoms and R¹ and R² can be H; 28 specific compounds are shown.
Optional further ingredients are 0.01-5 parts of sterically hindered phenol compound; and 0.01 to 30 parts of a compound containing a -C=C- or -C=C- bond and a polar group (e.g. carboxyl group), per 100 parts of (a), (b) and (c).
The blending can be at 200-380°C, and the melt is extruded and pelletised.
The resultant resin composition can be molded into products of large size, e.g. for automobile parts, and is highly resistant to solvents.摘要翻译： 共混物按重量计（a）10-70份可在苯基核上具有各种取代基的聚苯醚，并具有至少50个重复单元，（b）30-90份聚酰胺（尼龙 ）和任选地（c）3-50％在室温下是弹性的橡胶状聚合物（例如芳族乙烯基化合物和共轭二烯的共聚物）; 和作为稳定剂的硫醚化合物（优选具有式R 0 -S-CHR 1 R 2），其中R 5是1-35个C原子的烃基或取代的烃基，R 1和R 2 <2>可以是H;显示28个特定化合物，任选的另外的成分是0.01-5份空间位阻酚化合物;和0.01-30份包含-C = C-或-C = C-键的化合物， 每100份（a），（b）和（c）中的极性基团（例如羧基），共混物可以在200-380℃，将熔体挤出并造粒，得到的树脂组合物可以是 模制成大尺寸的产品，例如汽车部件，并且耐溶剂性高。
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公开(公告)号：EP0214747B1
公开(公告)日：1990-10-17
申请号：EP86305870.7
申请日：1986-07-30
发明人： Yazaki, Takao , Hattori, Satoru , Hattori, Kazuhide , Matsuno, Takumi , Shibuya, Nobuhiro , Hayama, Kazuhide , Itoh, Isao
CPC分类号： B32B7/12 , B32B5/18 , B32B27/065 , B32B27/32 , B32B2266/0278 , B32B2323/10 , F25D23/064 , Y10T428/249985 , Y10T428/249992 , Y10T428/249993 , Y10T428/31576 , Y10T428/31587
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公开(公告)号：EP0214747A3
公开(公告)日：1988-10-05
申请号：EP86305870
申请日：1986-07-30
发明人： Yazaki, Takao , Hattori, Satoru , Hattori, Kazuhide , Matsuno, Takumi , Shibuya, Nobuhiro , Hayama, Kazuhide , Itoh, Isao
CPC分类号： B32B7/12 , B32B5/18 , B32B27/065 , B32B27/32 , B32B2266/0278 , B32B2323/10 , F25D23/064 , Y10T428/249985 , Y10T428/249992 , Y10T428/249993 , Y10T428/31576 , Y10T428/31587
摘要： A sheet of a polymer comprising at least 50 mol% of units of an olefin (e.g. polypropylene ) is coated on one surface with an aqueous solution or dispersion
(A) 55 to 90% of a polymer comprising an olefin; (B) 1 to 30% of a copolymer of ethylene and acrylic acid; and (C) 10 to 30% of a polymer containing styrene units. The sheet optionally contains up to 65% of an inorganic fine powder. The adhesive layer adheres strongly to a cellular foamed polyurethane, to form a composite heat-insulating material without voids. The polymer sheet can be deep-drawn to shape, adhesive-coated, placed over the metal pressing of a refrigerator body or door, and the urethane components injected through a hole in the sheet so that the polyurethane is formed between the sheet and the metal pressing and is foamed and adhered in situ ; the sheet can be a laminate having a lustrous outer surface layer.
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