公开(公告)号：EP0480120A3

公开(公告)日：1993-01-13

申请号：EP91105085.4

申请日：1991-03-28

申请人： MITSUI TOATSU CHEMICALS, INC.

发明人： Kano, Taisaku ,  Sekido, Takayoshi ,  Miyazaki, Eiichiro ,  Nishimori, Makoto

IPC分类号： C09D125/14 ,  C09D133/06 ,  C09D201/08 ,  C09D5/03

CPC分类号： C09D133/14 ,  C08L33/06 ,  C08L67/02 ,  C08L2205/02 ,  Y10S525/934 ,  C08L2666/02

摘要： There is disclosed a resin composition for powder coatings, which comprises a blend of two acrylic resins being obtained by polymerizing a proscribed amount of monomer component (a-1) represented by formula (I) and a prescribed amount of another monomer component (a-2), respectively, and having different polymerization degrees represented by viscosities at 140°C and a polybasic acid compound in 1.5 to 0.5 equivalent ratio of the glycidyl groups in said acrylic resins to the acid groups in the polybasic acid compound.
wherein R 1 and R 2 each represent a hydrogen atom or a lower alkyl group. Disclosure described provides a resin composition for powder coatings that can form a coating film having a mat smooth appearance and excellent in flexibility as shown Du pont impact resistance and the Ericksen test as well as excellent in nail scratch resistance.

公开(公告)号：EP0480120A2

公开(公告)日：1992-04-15

申请号：EP91105085.4

申请日：1991-03-28

申请人： MITSUI TOATSU CHEMICALS, INC.

发明人： Kano, Taisaku ,  Sekido, Takayoshi ,  Miyazaki, Eiichiro ,  Nishimori, Makoto

IPC分类号： C09D125/14 ,  C09D133/06 ,  C09D201/08 ,  C09D5/03

CPC分类号： C09D133/14 ,  C08L33/06 ,  C08L67/02 ,  C08L2205/02 ,  Y10S525/934 ,  C08L2666/02

摘要： There is disclosed a resin composition for powder coatings, which comprises a blend of two acrylic resins being obtained by polymerizing a proscribed amount of monomer component (a-1) represented by formula (I) and a prescribed amount of another monomer component (a-2), respectively, and having different polymerization degrees represented by viscosities at 140°C and a polybasic acid compound in 1.5 to 0.5 equivalent ratio of the glycidyl groups in said acrylic resins to the acid groups in the polybasic acid compound.
wherein R 1 and R 2 each represent a hydrogen atom or a lower alkyl group. Disclosure described provides a resin composition for powder coatings that can form a coating film having a mat smooth appearance and excellent in flexibility as shown Du pont impact resistance and the Ericksen test as well as excellent in nail scratch resistance.

摘要翻译： 公开了一种用于粉末涂料的树脂组合物，其包含两种丙烯酸树脂的共混物，其通过将受限量的由式（I）表示的单体组分（a-1）和规定量的另一单体组分（a- 2），并且具有以140℃的粘度表示的不同聚合度和多元酸化合物，所述丙烯酸树脂中的缩水甘油基与多元酸化合物中的酸基的当量比为1.5至0.5当量比。 其中R1和R2各自表示氢原子或低级烷基。 所公开的公开内容提供了一种用于粉末涂料的树脂组合物，其可以形成具有平滑外观和柔韧性优异的涂膜，如杜邦耐冲击性和埃克森克氏试验以及耐刮擦性优异。

公开(公告)号：EP0398749A2

公开(公告)日：1990-11-22

申请号：EP90305425.2

申请日：1990-05-18

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Sasagawa, Katsuyoshi ,  Kano, Taisaku ,  Shikai, Kiyoshi

IPC分类号： C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/794

摘要： Herein disclosed are a polyisocyanato-isocyanurate represented by the following formula (I):
wherein n is an integer ranging 1 to 5 and R₁, R₂ and R₃ may be the same or different and each represents hydrogen atom or a lower alkyl group and a method for preparing it; and a resin containing an organic polyisocyanate containing not lower than 10% by weight of the polyisocyanato-isocyanurate represented by Formula (I) and a compound having at least two active hydrogen atoms as well as a resin composition for coating materials which comprises the resin.

摘要翻译： 本文公开了由下式（I）表示的多异氰酸酯 - 异氰脲酸酯：其中n为1〜5的整数，R 1，R 2和R 3可以相同或不同，表示氢原子或低级烷基 及其制备方法。 和含有不低于10重量％的由式（I）表示的多异氰酸酯 - 异氰脲酸酯和具有至少两个活性氢原子的化合物的有机多异氰酸酯以及包含该树脂的涂料的树脂组合物的树脂。

公开(公告)号：EP0458333B2

公开(公告)日：2001-11-07

申请号：EP91108356.6

申请日：1991-05-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Kano, Taisaku ,  Sekido, Takayoshi ,  Nomura, Hiroshi ,  Shikai, Kiyoshi

IPC分类号： C08G18/79 ,  C09D5/03 ,  C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/42 ,  C08G18/792 ,  C08G2150/20

公开(公告)号：EP0398749B1

公开(公告)日：1995-07-26

申请号：EP90305425.2

申请日：1990-05-18

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Sasagawa, Katsuyoshi ,  Kano, Taisaku ,  Shikai, Kiyoshi

IPC分类号： C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/794

公开(公告)号：EP0458333A3

公开(公告)日：1992-07-15

申请号：EP91108356.6

申请日：1991-05-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Kano, Taisaku ,  Sekido, Takayoshi ,  Nomura, Hiroshi ,  Shikai, Kiyoshi

IPC分类号： C08G18/79 ,  C09D5/03 ,  C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/42 ,  C08G18/792 ,  C08G2150/20

摘要： Polyisocyanato-isocyanurate and mixture of the same obtained by trimerizing straight chain aliphatic diisocyanate represented by the formula:
        OCN-R₄-NCO
wherein R₄ is an alkylene group having 2 - 12 carbon atoms and polycyclo-aliphatic diisocyanate represented by the formula:

wherein k is an integer of 0 to 2, j and m are integers of 1 to 5, and h is an integer of 0 to 2; powder-paint curing agent which contains blocked isocyanate obtained by reacting the above raw materials with a blocking agent having at least one active hydrogen in a moelcule; non-yellowing urethane paint resin prepared from the above raw materials and compound having at least two active hydrogen in a molecule; and paint composition comprising the curing agent and the resin; is disclosed.

公开(公告)号：EP0480120B1

公开(公告)日：1995-11-29

申请号：EP91105085.4

申请日：1991-03-28

申请人： MITSUI TOATSU CHEMICALS, INC.

发明人： Kano, Taisaku ,  Sekido, Takayoshi ,  Miyazaki, Eiichiro ,  Nishimori, Makoto

IPC分类号： C09D125/14 ,  C09D133/06 ,  C09D201/08 ,  C09D5/03

CPC分类号： C09D133/14 ,  C08L33/06 ,  C08L67/02 ,  C08L2205/02 ,  Y10S525/934 ,  C08L2666/02

公开(公告)号：EP0544206A3

公开(公告)日：1993-12-08

申请号：EP92119899.0

申请日：1992-11-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Miyazaki, Eiichiro ,  Nishimori, Makoto ,  Kano, Taisaku ,  Sekido, Takayoshi ,  Seki, Masashi

IPC分类号： C09D133/06 ,  C08K5/09 ,  C09D5/03

CPC分类号： C09D133/068 ,  C08K5/092 ,  C08L33/068 ,  C08L2205/02 ,  C09D137/00 ,  Y10T428/31511 ,  C08L33/06 ,  C08L2666/04 ,  C08L2666/28 ,  C08L2666/34

摘要： A composition for thermosetting powder coating, which comprises
(a) an acrylic copolymer of high softening point having an epoxy equivalent of 250-1,000 g/eq and a softening point of 90-160 o C, (b) an acrylic copolymer of low softening point having an epoxy equivalent of 200-600 g/eq and a softening point of 30-70 o C, (c) a polycarboxylic acid, and (d) optionally, a phosphoric acid ester compound and/or a phosphorous acid ester compound, and wherein the difference in softening point between (a) and (b) is 60-120 o C, the weight ratio of (a)/(b) is 95/5 to 60/40, and the equivalent ratio of [the total epoxy groups of (a) and (b)] : [the acid group of (c)] is 0.5 : 1 to 1 : 0.5. Said composition has excellent storage stability and, when used as a coating for automobiles, gives a film superior in appearance, solvent resistance and acid resistance.

公开(公告)号：EP0544206A2

公开(公告)日：1993-06-02

申请号：EP92119899.0

申请日：1992-11-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Miyazaki, Eiichiro ,  Nishimori, Makoto ,  Kano, Taisaku ,  Sekido, Takayoshi ,  Seki, Masashi

IPC分类号： C09D133/06 ,  C08K5/09 ,  C09D5/03

CPC分类号： C09D133/068 ,  C08K5/092 ,  C08L33/068 ,  C08L2205/02 ,  C09D137/00 ,  Y10T428/31511 ,  C08L33/06 ,  C08L2666/04 ,  C08L2666/28 ,  C08L2666/34

摘要： A composition for thermosetting powder coating, which comprises

(a) an acrylic copolymer of high softening point having an epoxy equivalent of 250-1,000 g/eq and a softening point of 90-160 o C,
(b) an acrylic copolymer of low softening point having an epoxy equivalent of 200-600 g/eq and a softening point of 30-70 o C,
(c) a polycarboxylic acid, and
(d) optionally, a phosphoric acid ester compound and/or a phosphorous acid ester compound,
and wherein the difference in softening point between (a) and (b) is 60-120 o C, the weight ratio of (a)/(b) is 95/5 to 60/40, and the equivalent ratio of [the total epoxy groups of (a) and (b)] : [the acid group of (c)] is 0.5 : 1 to 1 : 0.5.
Said composition has excellent storage stability and, when used as a coating for automobiles, gives a film superior in appearance, solvent resistance and acid resistance.

摘要翻译： 一种热固性粉末涂料组合物，其包含（a）具有环氧当量为250-1,000g / eq和软化点为90-160℃的高软化点的丙烯酸共聚物，（b）丙烯酸共聚物， 环氧当量为200-600g / eq，软化点为30-70℃的低软化点，（c）多元羧酸，和（d）任选的磷酸酯化合物和/或磷 酸酯化合物，其中（a）和（b）之间的软化点的差为60-120℃，（a）/（b）的重量比为95/5〜60/40， [（a）和（b）]的全部环氧基的当量比：[（c）的酸基）为0.5:1〜1:0.5。 所述组合物具有优异的储存稳定性，并且当用作汽车涂料时，得到外观优异，耐溶剂性和耐酸性的膜。

公开(公告)号：EP0398749A3

公开(公告)日：1991-12-27

申请号：EP90305425.2

申请日：1990-05-18

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Sasagawa, Katsuyoshi ,  Kano, Taisaku ,  Shikai, Kiyoshi

IPC分类号： C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/794

摘要： Herein disclosed are a polyisocyanato-isocyanurate represented by the following formula (I):
wherein n is an integer ranging 1 to 5 and R₁, R₂ and R₃ may be the same or different and each represents hydrogen atom or a lower alkyl group and a method for preparing it; and a resin containing an organic polyisocyanate containing not lower than 10% by weight of the polyisocyanato-isocyanurate represented by Formula (I) and a compound having at least two active hydrogen atoms as well as a resin composition for coating materials which comprises the resin.