公开(公告)号：EP0696622A3

公开(公告)日：1997-12-03

申请号：EP95112560.8

申请日：1995-08-09

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Seki, Masashi ,  Kawasaki, Eiichi ,  Sekido, Takayoshi ,  Mizoguchi, Mitsuyuki ,  Miyawaki, Takahisa ,  Suewaka, Kousuke

IPC分类号： C09D5/03 ,  C09D133/14

CPC分类号： C09D133/068 ,  C08L73/02 ,  Y10T428/24 ,  C08L2666/14 ,  C08L2666/28

摘要： The present invention relates to a thermosetting powder paint comprising, as essential components, (A) a copolymer of particular composition composed of a glycidyl group-containing monomer, styrene and other monomer copolymerizable therewith and, as curing agents capable of reacting with the component (A) to crosslink the component (A), (B) an aliphatic polycarboxylic acid and (C) a linear anhydride of an aliphatic polycarboxylic acid; a coating method using the above thermosetting powder paint; and a coated article obtained by using the above thermosetting powder paint. The above thermosetting powder paint, when used as a paint for automobile, has excellent storage stability and gives a coating film having excellent appearance, properties, weathering resistance and yellowing resistance; therefore, the paint can be favorably used particularly as an top coat and an intermediate coat for automobile and its parts.

公开(公告)号：EP0480120A3

公开(公告)日：1993-01-13

申请号：EP91105085.4

申请日：1991-03-28

申请人： MITSUI TOATSU CHEMICALS, INC.

发明人： Kano, Taisaku ,  Sekido, Takayoshi ,  Miyazaki, Eiichiro ,  Nishimori, Makoto

IPC分类号： C09D125/14 ,  C09D133/06 ,  C09D201/08 ,  C09D5/03

CPC分类号： C09D133/14 ,  C08L33/06 ,  C08L67/02 ,  C08L2205/02 ,  Y10S525/934 ,  C08L2666/02

摘要： There is disclosed a resin composition for powder coatings, which comprises a blend of two acrylic resins being obtained by polymerizing a proscribed amount of monomer component (a-1) represented by formula (I) and a prescribed amount of another monomer component (a-2), respectively, and having different polymerization degrees represented by viscosities at 140°C and a polybasic acid compound in 1.5 to 0.5 equivalent ratio of the glycidyl groups in said acrylic resins to the acid groups in the polybasic acid compound.
wherein R 1 and R 2 each represent a hydrogen atom or a lower alkyl group. Disclosure described provides a resin composition for powder coatings that can form a coating film having a mat smooth appearance and excellent in flexibility as shown Du pont impact resistance and the Ericksen test as well as excellent in nail scratch resistance.

公开(公告)号：EP0480120A2

公开(公告)日：1992-04-15

申请号：EP91105085.4

申请日：1991-03-28

申请人： MITSUI TOATSU CHEMICALS, INC.

发明人： Kano, Taisaku ,  Sekido, Takayoshi ,  Miyazaki, Eiichiro ,  Nishimori, Makoto

IPC分类号： C09D125/14 ,  C09D133/06 ,  C09D201/08 ,  C09D5/03

CPC分类号： C09D133/14 ,  C08L33/06 ,  C08L67/02 ,  C08L2205/02 ,  Y10S525/934 ,  C08L2666/02

摘要： There is disclosed a resin composition for powder coatings, which comprises a blend of two acrylic resins being obtained by polymerizing a proscribed amount of monomer component (a-1) represented by formula (I) and a prescribed amount of another monomer component (a-2), respectively, and having different polymerization degrees represented by viscosities at 140°C and a polybasic acid compound in 1.5 to 0.5 equivalent ratio of the glycidyl groups in said acrylic resins to the acid groups in the polybasic acid compound.
wherein R 1 and R 2 each represent a hydrogen atom or a lower alkyl group. Disclosure described provides a resin composition for powder coatings that can form a coating film having a mat smooth appearance and excellent in flexibility as shown Du pont impact resistance and the Ericksen test as well as excellent in nail scratch resistance.

摘要翻译： 公开了一种用于粉末涂料的树脂组合物，其包含两种丙烯酸树脂的共混物，其通过将受限量的由式（I）表示的单体组分（a-1）和规定量的另一单体组分（a- 2），并且具有以140℃的粘度表示的不同聚合度和多元酸化合物，所述丙烯酸树脂中的缩水甘油基与多元酸化合物中的酸基的当量比为1.5至0.5当量比。 其中R1和R2各自表示氢原子或低级烷基。 所公开的公开内容提供了一种用于粉末涂料的树脂组合物，其可以形成具有平滑外观和柔韧性优异的涂膜，如杜邦耐冲击性和埃克森克氏试验以及耐刮擦性优异。

公开(公告)号：EP0458333B2

公开(公告)日：2001-11-07

申请号：EP91108356.6

申请日：1991-05-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Kano, Taisaku ,  Sekido, Takayoshi ,  Nomura, Hiroshi ,  Shikai, Kiyoshi

IPC分类号： C08G18/79 ,  C09D5/03 ,  C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/42 ,  C08G18/792 ,  C08G2150/20

公开(公告)号：EP0719848A3

公开(公告)日：1998-03-11

申请号：EP95120039.3

申请日：1995-12-19

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Seki, Masashi ,  Kawasaki, Eiichi ,  Sekido, Takayoshi ,  Mizoguchi, Mitsuyuki ,  Miyawaki, Takahisa

IPC分类号： C09D151/00

CPC分类号： C08F290/148 ,  C09D151/08

摘要： A heat-curable powder paint composition comprising a copolymer (A) obtained by radical copolymerization of (a1) a monomer having both an unsaturated double bond and a non-radical-polymerizable reactive functional group (e.g. glycidyl or hydroxyl group), (a2) a monomer having no reactive functional group other than an unsaturated double bond, and (a3) a silicone macromer having essentially no reactive functional group other than an unsaturated double bond in a specific ratio; and curing agent (B). The paint composition of this invention can achieve excellent performance simultaneously with respect to storage stability and coating film properties (such as appearance characteristics, physical characteristics and chemical characteristics).

摘要翻译： 一种热可固化粉末涂料组合物，其包含通过（a1）具有不饱和双键和非自由基聚合反应性官能团（例如缩水甘油基或羟基）的单体的自由基共聚得到的共聚物（A），（a2） 不具有不饱和双键以外的反应性官能团的单体，（a3）特定比例的基本上不具有不饱和双键的反应性官能团的硅氧烷大单体; 和固化剂（B）。 本发明的涂料组合物在储存稳定性和涂膜性能（如外观特性，物理特性和化学特性）方面可以同时获得优异的性能。

公开(公告)号：EP0659826B1

公开(公告)日：1997-09-17

申请号：EP94309825.1

申请日：1994-12-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Kojima, Nobumoto ,  Ichikawa, Kouzo ,  Amemiya. Hideo ,  Okajima, Shinji ,  Sekido, Takayoshi ,  Kato, Mitsuyoshi

IPC分类号： C08L25/02 ,  C08K5/42

CPC分类号： C08K5/0075 ,  C08K5/42 ,  C08L25/02 ,  C08L25/14 ,  C08L33/06 ,  C08L71/02 ,  C08L2666/02

公开(公告)号：EP0458333A3

公开(公告)日：1992-07-15

申请号：EP91108356.6

申请日：1991-05-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Kano, Taisaku ,  Sekido, Takayoshi ,  Nomura, Hiroshi ,  Shikai, Kiyoshi

IPC分类号： C08G18/79 ,  C09D5/03 ,  C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/42 ,  C08G18/792 ,  C08G2150/20

摘要： Polyisocyanato-isocyanurate and mixture of the same obtained by trimerizing straight chain aliphatic diisocyanate represented by the formula:
        OCN-R₄-NCO
wherein R₄ is an alkylene group having 2 - 12 carbon atoms and polycyclo-aliphatic diisocyanate represented by the formula:

wherein k is an integer of 0 to 2, j and m are integers of 1 to 5, and h is an integer of 0 to 2; powder-paint curing agent which contains blocked isocyanate obtained by reacting the above raw materials with a blocking agent having at least one active hydrogen in a moelcule; non-yellowing urethane paint resin prepared from the above raw materials and compound having at least two active hydrogen in a molecule; and paint composition comprising the curing agent and the resin; is disclosed.

公开(公告)号：EP0719848A2

公开(公告)日：1996-07-03

申请号：EP95120039.3

申请日：1995-12-19

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Seki, Masashi ,  Kawasaki, Eiichi ,  Sekido, Takayoshi ,  Mizoguchi, Mitsuyuki ,  Miyawaki, Takahisa

IPC分类号： C09D151/00

CPC分类号： C08F290/148 ,  C09D151/08

摘要： A heat-curable powder paint composition comprising a copolymer (A) obtained by radical copolymerization of (a1) a monomer having both an unsaturated double bond and a non-radical-polymerizable reactive functional group (e.g. glycidyl or hydroxyl group), (a2) a monomer having no reactive functional group other than an unsaturated double bond, and (a3) a silicone macromer having essentially no reactive functional group other than an unsaturated double bond in a specific ratio; and curing agent (B).
The paint composition of this invention can achieve excellent performance simultaneously with respect to storage stability and coating film properties (such as appearance characteristics, physical characteristics and chemical characteristics).

公开(公告)号：EP0458333B1

公开(公告)日：1996-01-24

申请号：EP91108356.6

申请日：1991-05-23

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Haseyama, Ryuji ,  Hayashi, Kouzou ,  Kuroda, Kazuyuki ,  Kano, Taisaku ,  Sekido, Takayoshi ,  Nomura, Hiroshi ,  Shikai, Kiyoshi

IPC分类号： C08G18/79 ,  C09D5/03 ,  C07D251/34

CPC分类号： C08G18/6229 ,  C07D251/34 ,  C08G18/42 ,  C08G18/792 ,  C08G2150/20

公开(公告)号：EP0314447B1

公开(公告)日：1993-08-25

申请号：EP88310049.7

申请日：1988-10-26

申请人： UNITIKA LTD. ,  MITSUI TOATSU CHEMICALS, Inc.

发明人： Sasaki, Shingo ,  Wakamura, Kazuyuki ,  Kano, Taisaku ,  Naito, Hisayuki ,  Sekido, Takayoshi ,  Kikuta, Yoshio

IPC分类号： C08G18/40 ,  C08G18/62 ,  C08G18/42 ,  C08G18/80 ,  C09D133/08 ,  C09D133/10 ,  C09D175/04

CPC分类号： C08G18/4063 ,  C08G18/4263 ,  C08G18/6216 ,  C08G2150/20 ,  C08G2250/00