公开(公告)号：EP0802208A1

公开(公告)日：1997-10-22

申请号：EP97302602.4

申请日：1997-04-16

申请人： MITSUI TOATSU CHEMICALS, INC.

发明人： Fujii, Kenichi ,  Kawauchi, Nobuya ,  Suzuki, Toshiyuki ,  Kobayashi, Seiichi ,  Imai, Masao

IPC分类号： C08F283/00 ,  C08G18/38 ,  G02B1/04

CPC分类号： C08G18/3876 ,  C08F283/006 ,  C08F291/18 ,  G02B1/041 ,  C08L51/08 ,  C08L75/04 ,  C08L81/00

摘要： This invention relates to (1) an optical resin composition comprising Component A: a thiourethane prepolymer compound prepared by reacting a polythiol compound having at least 3 functional groups and an intramolecular sulfide bond, with a polyisocyanate compound in a molar ratio of -SH to -NCO ranging from 3.0 to 7.0; Component B: at least one (meth)acrylate compound having at least 2 functional groups; and Component C: a compound radically polymerizable with Components A and B, in 10 to 50% by weight, 35 to 70% by weight, and 5 to 30% by weight, respectively; (2) a preparation process for an optical resin by photopolymerization; (3) an optical resin; and (4) a prepolymer suitable for Component A. A composition of this invention is a novel, rapidly polymerizable composition for an optical resin.
Furthermore, a resin prepared by curing a composition of this invention not only has a high refractive index and a high Abbe number, but also is excellent in transparency and optical homogeneity.

摘要翻译： 本发明涉及（1）一种光学树脂组合物，其包含组分A：通过使具有至少3个官能团和分子内硫键的多硫醇化合物与-SH至 - 的摩尔比的多异氰酸酯化合物反应制备的硫代氨基甲酸酯预聚物化合物， NCO范围从3.0到7.0; 组分B：至少一种具有至少2个官能团的（甲基）丙烯酸酯化合物; 和组分C：组分A和B可自由基聚合的化合物，分别为10至50重量％，35至70重量％和5至30重量％; （2）通过光聚合制备光学树脂的制备方法; （3）光学树脂; 和（4）适用于组分A的预聚物。本发明的组合物是用于光学树脂的新型快速聚合组合物。 此外，通过固化本发明的组合物制备的树脂不仅具有高折射率和高阿贝数，而且透明性和光学均匀性也优异。

公开(公告)号：EP0586091A2

公开(公告)日：1994-03-09

申请号：EP93306038.6

申请日：1993-07-30

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Kobayashi, Seiichi ,  Kanemura, Yoshinobu ,  Sasagawa, Katsuyoshi

IPC分类号： G02B1/04 ,  C08G18/38 ,  C08G18/76

CPC分类号： C08G18/7628 ,  C08G18/3876 ,  G02B1/041 ,  C08L75/00

摘要： The present invention discloses a composition for high refractive index plastic lens consisting of a monomer mixture wherein a particular aliphatic thiol compound is added to a polyisocyanate represented by general formula (1) :

wherein each X represents a hydrogen atom or a methyl group ; each R represents a chlorine atom, a bromine atom, a methyl group or an ethyl group ; m represents an integer of 0-4 ; and n represents an integer of 2-4, and a polythiol of formula (2) :

and a high refractive index plastic lens made of a urethane-containing resin obtained by polymerizing said composition.

摘要翻译： 本发明公开了一种高折射率塑料透镜组合物，其由单体混合物组成，其中将特定的脂族硫醇化合物加入由通式（1）表示的多异氰酸酯：其中每个X表示氢原子或甲基 ; 每个R表示氯原子，溴原子，甲基或乙基; m表示0-4的整数; 和n表示2-4的整数，和式（2）的多硫醇：＆lt; CHEM＆gt;和通过聚合所述组合物而获得的含氨基甲酸酯的树脂制成的高折射率塑料透镜。

公开(公告)号：EP0810210A2

公开(公告)日：1997-12-03

申请号：EP97303553.8

申请日：1997-05-23

申请人： MITSUI TOATSU CHEMICALS, INC.

发明人： Kobayashi, Seiichi ,  Kawauchi, Nobuya ,  Suzuki, Toshiyuki ,  Imai, Masao ,  Fujii, Kenichi

IPC分类号： C07C323/12 ,  C08F20/38 ,  G02B1/04

CPC分类号： C08F20/38 ,  C07C323/12 ,  C07C327/28 ,  C07C333/04 ,  C07D333/22 ,  G02B1/041 ,  C08L33/14

摘要： A sulfur-containing O-(meth)acrylate compound of the following formula (1) is useful as a starting material for a resin composition used in optical applications such as a lens;
wherein R represents hydrogen atom or methyl group; 1 represents an integer from 1 to 3; B is -CH〈,
when B is -CH〈, n is 2; m is 1 or 2; A is selected from the following groups:

wherein m represents 1 or 2; each ring may be substituted by one or more alkyl, alkylthio or alkoxy groups having 1 or 2 carbon atoms; p and q are 0 or 1, while m is 1 when p is 1; when B is
n is 1; m is 2 or 3; A is selected from the following groups:

        -(CH 2 ) r -S-(CH 2 ) r -,



        -(CH 2 ) r -S-S-(CH 2 ) r -,



        -(CH 2 ) r -S-(CH 2 ) s -S-(CH 2 ) r -

and
wherein r and s are an integer from 1 to 3; when B is
n is 1; m is 2; A is selected from the following groups:

        -(CH 2 ) r -S-(CH 2 ) r - ,



        -(CH 2 ) r -S-S-(CH 2 ) r -

and

        -(CH 2 ) r -S-(CH 2 ) s -S-(CH 2 ) r -

wherein r and s are an integer from 1 to 3.

摘要翻译： 下式（1）的含硫O-（甲基）丙烯酸酯化合物可用作用于光学应用如透镜的树脂组合物的起始材料; 其中R表示氢原子或甲基; 1表示1〜3的整数， 当B是-CH 2，并且n是2时，B是-CH 2，-CH 2， m为1或2; A选自以下基团： 其中m表示1或2; 每个环可以被一个或多个具有1或2个碳原子的烷基，烷硫基或烷氧基取代; p和q为0或1，而当p为1时，m为1; 当B为时，n为1; m为2或3; A选自以下基团： - （CH 2）r S-（CH 2）r - ， - （CH 2）r SS-（CH 2）r - ， - （CH 2）r S-（CH 2）s S-（CH 2） CHEM>其中r和s为1至3的整数; 当B为时，n为1; m为2; A选自以下基团： - （CH 2）r S-（CH 2）r - ， - （CH 2）r SS-（CH 2）r - 和 - （CH 2）r S-（CH 2）s S-（CH 2） s为1〜3的整数。

公开(公告)号：EP0586091A3

公开(公告)日：1995-02-22

申请号：EP93306038.6

申请日：1993-07-30

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Kobayashi, Seiichi ,  Kanemura, Yoshinobu ,  Sasagawa, Katsuyoshi

IPC分类号： G02B1/04 ,  C08G18/38 ,  C08G18/76

CPC分类号： C08G18/7628 ,  C08G18/3876 ,  G02B1/041 ,  C08L75/00

摘要： The present invention discloses a composition for high refractive index plastic lens consisting of a monomer mixture wherein a particular aliphatic thiol compound is added to a polyisocyanate represented by general formula (1) :

wherein each X represents a hydrogen atom or a methyl group ; each R represents a chlorine atom, a bromine atom, a methyl group or an ethyl group ; m represents an integer of 0-4 ; and n represents an integer of 2-4, and a polythiol of formula (2) :

and a high refractive index plastic lens made of a urethane-containing resin obtained by polymerizing said composition.