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    Preparation process of cinnamate esters
    3.
    发明公开
    Preparation process of cinnamate esters 失效
    。TE。。。。。。。

    公开(公告)号：EP0177354A3

    公开(公告)日：1986-06-11

    申请号：EP85307086

    申请日：1985-10-03

    申请人： MITSUI TOATSU CHEMICALS, Inc.

    发明人： Takaki, Usaji ,  Sudo, Isamu ,  Matsuhisa, Toshio ,  Hara, Isao

    IPC分类号： C07C67/38 ,  C07C69/618 ,  C07C69/65

    CPC分类号： C07C67/38 ,  C07C69/52

    摘要： A cinnamate ester is prepared by reacting carbon monoxide, oxygen, and its corresponding styrene compound and alcohol in the presence of a catalyst which contains, as essential components,
    (a) a platinum goup metal or a compound thereof; (b) a copper or iron compound; and (c) a compound of at least one metal selected from Groups 4A, 5A, 7A, εA(the iron group only), 1B(exclusive of copper) and 2B. E.g. a catalyst of palladium chloride, copper"chloride and basic zinc carbonate was used to produce methyl cinnamate in 75% yield. In the absence of the zinc carbonate the yield was 2%. (Example 17 and comparative example 1.)

    Process for the preparation of cinnamate ester
    4.
    发明公开
    Process for the preparation of cinnamate ester 失效
    Herstellungsverfahren vonZimtsäureestern。

    公开(公告)号：EP0186349A1

    公开(公告)日：1986-07-02

    申请号：EP85308841.7

    申请日：1985-12-04

    申请人： MITSUI TOATSU CHEMICALS, Inc.

    发明人： Takaki, Usaji ,  Matsuhisa, Toshio ,  Sudo, Isamu

    IPC分类号： C07C67/38 ,  C07C69/618

    CPC分类号： C07C67/38 ,  C07C69/618

    摘要： A process for preparing a corresponding cinnamate ester by the rection of a styrene compound, carbon monoxide, an alcohol and oxygen by using a main catalyst composed of (a) a platinum group metal or a compound thereof and (b) a copper or iron compound and in the presence of a promoter, wherein the concentration of the metal of the component (a) is controlled at 5.5 x 10 -4 gram atom/liter or below in the liquid reaction mixture and further the ratio of the component (b) to the metal of the component (a) is maintained at 50 moles/gram atom or above so as to carry out the reaction.

    摘要翻译： 通过使用由（a）铂族金属或其化合物组成的主催化剂和（b）铜或铁化合物的主催化剂，通过苯乙烯化合物，一氧化碳，醇和氧的反应来制备相应的肉桂酸酯的方法 并且在助催化剂的存在下，其中组分（a）的金属浓度在液体反应混合物中控制在5.5×10 -4克原子/升或更低，而且组分 （b）成分（a）的金属保持在50摩尔/克原子以上，进行反应。

    Preparation process of cinnamate esters
    5.
    发明公开
    Preparation process of cinnamate esters 失效
    肉桂酸酯的制备工艺

    公开(公告)号：EP0177354A2

    公开(公告)日：1986-04-09

    申请号：EP85307086.0

    申请日：1985-10-03

    申请人： MITSUI TOATSU CHEMICALS, Inc.

    发明人： Takaki, Usaji ,  Sudo, Isamu ,  Matsuhisa, Toshio ,  Hara, Isao

    IPC分类号： C07C67/38 ,  C07C69/618 ,  C07C69/65

    CPC分类号： C07C67/38 ,  C07C69/52

    摘要： A cinnamate ester is prepared by reacting carbon monoxide, oxygen, and its corresponding styrene compound and alcohol in the presence of a catalyst which contains, as essential components,

    (a) a platinum goup metal or a compound thereof;
    (b) a copper or iron compound; and
    (c) a compound of at least one metal selected from

    Groups 4A, 5A, 7A, εA(the iron group only), 1B(exclusive of copper) and 2B.
    E.g. a catalyst of palladium chloride, copper"chloride and basic zinc carbonate was used to produce methyl cinnamate in 75% yield. In the absence of the zinc carbonate the yield was 2%.
    (Example 17 and comparative example 1.)

    摘要翻译： 肉桂酸酯是通过使一氧化碳，氧气及其相应的苯乙烯化合物和醇在催化剂存在下反应制备的，所述催化剂含有（a）铂族金属或其化合物作为基本组分; （b）铜或铁化合物; 和（c）至少一种选自4A，5A，7A，εA族（仅含铁基），1B（不含铜）和2B的化合物。 例如。 使用氯化钯，氯化铜和碱式碳酸锌的催化剂以75％的收率制备肉桂酸甲酯，在不存在碳酸锌的情况下，收率为2％（实施例17和比较例1）

    Preparation of cinnamate esters
    7.
    发明公开
    Preparation of cinnamate esters 失效
    Herstellung vonZimtsäureestern。

    公开(公告)号：EP0242072A1

    公开(公告)日：1987-10-21

    申请号：EP87302670.2

    申请日：1987-03-27

    申请人： MITSUI TOATSU CHEMICALS, Inc.

    发明人： Takaki, Usaji ,  Yamamoto, Yoshihiro ,  Matsuhisa, Toshio ,  Sudo, Isamu ,  Aoki, Shinobu Mitsui Toatsu Kosugaya

    IPC分类号： C07C69/618 ,  C07C67/38 ,  B01J27/32

    CPC分类号： C07C69/618 ,  Y02P20/584

    摘要： Disclosed herein is a process for preparing a corresponding cinnamate ester by reacting a styrene compound, carbon monoxide, an alcohol and oxygen by the use of (l) metallic palladium or a compound thereof, (2) a copper compound, (3) a compound of at least one metal selected from Groups 4A, 5A, 7A, 8A (the iron group only) and 2B in the Periodic Table and (4) a halogen compound as a catalyst which comprises treating the catalyst components recovered from the reaction liquid after completion of the reaction with an oxidizing agent in the presence of an organic acid to regenerate their catalytic activity, using the resulting catalyst components again in the reaction as a catalyst and repeating the foregoing procedure.
    The regenerated catalyst is recovered in catalytic activity to the extent of that of a fresh catalyst and thus gives a high reaction performance in the subsequent reaction. Thus, the catalyst contain­ing expensive metal can be used circulatively.

    摘要翻译： 本文公开了一种通过使用（1）金属钯或其化合物使苯乙烯化合物，一氧化碳，醇和氧反应制备相应的肉桂酸酯的方法，（2）铜化合物，（3）化合物 的选自4A，5A，7A，8A（仅铁族）和2B中的至少一种金属，以及（4）作为催化剂的卤素化合物，其包括处理在完成后从反应液中回收的催化剂组分 在有机酸存在下与氧化剂反应以再生其催化活性，在反应中再次使用所得催化剂组分作为催化剂，并重复上述步骤。 再生催化剂的催化活性回收到新鲜催化剂的催化活性，因此在随后的反应中得到高的反应性能。 因此，可以循环使用含有贵金属的催化剂。