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公开(公告)号：EP0735995B1
公开(公告)日：1999-07-28
申请号：EP95905332.3
申请日：1994-12-09
发明人： ARDITO, Susan, Chmura , ASHJIAN, Henri , DEGNAN, Thomas, Francis, Jr. , HELTON, Terry, Eugene , LE, Quang, Ngoc , QUINONES, Augusto, Rodolfo
CPC分类号： C07C2/66 , C07C2529/08 , C07C15/24
摘要： Long chain alkyl substituted naphthalenes are produced by the alkylation of naphthalene with an olefin or other alkylating agent possessing at least 6 carbon atoms, usually 12 to 20 carbon atoms, in the presence of an alkylation catalyst comprising a zeolite having rare earths associated with less than 50 % of the exchangeable sites of the zeolite. The zeolite is usually a large pore size zeolite such as zeolite USY. The partial exchange with rare earths increases the selectivity of the catalyst for the production of long chain mono-alkyl substituted naphthalenes in preference to more highly substituted products.
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公开(公告)号：EP0735995A1
公开(公告)日：1996-10-09
申请号：EP95905332.0
申请日：1994-12-09
发明人： ARDITO, Susan, Chmura , ASHJIAN, Henri , DEGNAN, Thomas, Francis, Jr. , HELTON, Terry, Eugene , LE, Quang, Ngoc , QUINONES, Augusto, Rodolfo
CPC分类号： C07C2/66 , C07C2529/08 , C07C15/24
摘要： Long chain alkyl substituted naphthalenes are produced by the alkylation of naphthalene with an olefin or other alkylating agent possessing at least 6 carbon atoms, usually 12 to 20 carbon atoms, in the presence of an alkylation catalyst comprising a zeolite having rare earths associated with less than 50 % of the exchangeable sites of the zeolite. The zeolite is usually a large pore size zeolite such as zeolite USY. The partial exchange with rare earths increases the selectivity of the catalyst for the production of long chain mono-alkyl substituted naphthalenes in preference to more highly substituted products.
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