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公开(公告)号：EP0792251B1
公开(公告)日：2001-04-04
申请号：EP95941529.0
申请日：1995-11-16
发明人： ABICHANDANI, Jeevan, Sahib , BECK, Jeffrey, Scott , BUNDENS, Robert, Glenn , BRECKENRIDGE, Lloyd, Lee , OLSON, David, Harold , REISCHMAN, Paul, Thomas , STERN, David, Lawrence , VENKAT, Chaya, Rao
IPC分类号： C07C5/22
CPC分类号： C07C15/08 , B01J29/44 , B01J29/65 , B01J29/70 , B01J2229/12 , B01J2229/42 , C07C4/18 , C07C5/2708 , C07C15/00 , C07C15/067 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/04
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公开(公告)号：EP0792251A1
公开(公告)日：1997-09-03
申请号：EP95941529.0
申请日：1995-11-16
发明人： ABICHANDANI, Jeevan, Sahib , BECK, Jeffrey, Scott , BUNDENS, Robert, Glenn , BRECKENRIDGE, Lloyd, Lee , OLSON, David, Harold , REISCHMAN, Paul, Thomas , STERN, David, Lawrence , VENKAT, Chaya, Rao
CPC分类号： C07C15/08 , B01J29/44 , B01J29/65 , B01J29/70 , B01J2229/12 , B01J2229/42 , C07C4/18 , C07C5/2708 , C07C15/00 , C07C15/067 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/04
摘要： A mixture of aromatic hydrocarbons, comprising ethylbenzene and at least one xylene, is isomerized using a two component catalyst system to convert the ethylbenzene to compounds that may be removed from the aromatic hydrocarbon stream and to produce a product stream wherein the para-xylene concentration is approximately equal to the equilibrium ratio of the para-isomer. The first catalyst comprises an intermediate pore size zeolite that is effective for ethylbenzene conversion. The first catalyst is preferably silica-bound. The second catalyst comprises an intermediate pore size zeolite, which further has a small crystal size and which is effective to catalyze xylene isomerization. Each of the catalysts of this invention may contain one or more hydrogenation/dehydrogenation component.
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3.发明公开
公开(公告)号：EP0832056A1
公开(公告)日：1998-04-01
申请号：EP95922871.0
申请日：1995-06-06
发明人： AGASKAR, Pradyot, Adwaitanand , GRASSELLI, Robert, Karl , MICHAELS, James, Nathaniel , REISCHMAN, Paul, Thomas , STERN, David, Lawrence , TSIKOYIANNIS, John, George
CPC分类号： C07C5/42 , C07C2523/42 , C07C2523/44 , C07C11/02
摘要： A process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes is provided. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is passed into a reactor containing both an equilibrium dehydrogenation catalyst and a reducible metal oxide, whereby the alkane is dehydrogenated and the hydrogen produced is simultaneously and selectively conbusted in oxidation/reduction (REDOX) reaction with the reducible metal oxide. This particular mode of operation is termed a same reactor, REDOX mode. The equilibrium dehydrogenation catalyst may comprise platinum and the reducible metal oxide may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.
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4.发明授权
公开(公告)号：EP0832056B1
公开(公告)日：2001-05-16
申请号：EP95922871.9
申请日：1995-06-06
发明人： AGASKAR, Pradyot, Adwaitanand , GRASSELLI, Robert, Karl , MICHAELS, James, Nathaniel , REISCHMAN, Paul, Thomas , STERN, David Lawrence, , TSIKOYIANNIS, John George,
CPC分类号： C07C5/42 , C07C2523/42 , C07C2523/44 , C07C11/02
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5.发明公开
公开(公告)号：EP0835235A1
公开(公告)日：1998-04-15
申请号：EP95922081.0
申请日：1995-05-17
发明人： AGASKAR, Pradyot, Adwaitanand , GRASSELLI, Robert, Karl , MICHAELS, James, Nathaniel , REISCHMAN, Paul, Thomas , STERN, David, Lawrence , TSIKOYIANNIS, John, George
IPC分类号： C07C5
CPC分类号： C07C5/3337 , C07C2529/44 , C07C11/02
摘要： A process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes is provided. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilibrium dehydrogenation catalyst in a first reactor (110) and the effluent, along with oxygen is then passed into the second reactor (120) containing a metal oxide catalyst which serves to selectively catalyze the combustion of hydrogen. The equilibrium dehydrogenation catalyst may comprise platinum and the selective metal oxide combustion catalyst may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.
摘要翻译： 提供了烷烃净催化氧化脱氢生产烯烃的方法。 该方法包括将烷烃同时平衡脱氢成烯烃和形成的氢的燃烧，以进一步驱使产物烯烃进行平衡脱氢反应。 在本反应中，烷烃原料在第一反应器（110）中经平衡脱氢催化剂脱氢，然后流出物与氧气一起进入含有金属氧化物催化剂的第二反应器（120），所述金属氧化物催化剂用于选择性催化 氢燃烧。 平衡脱氢催化剂可以包含铂，并且选择性金属氧化物燃烧催化剂可以包含铋，锑，铟或钼或其混合物。
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6.发明公开
公开(公告)号：EP0832055A1
公开(公告)日：1998-04-01
申请号：EP95920511.0
申请日：1995-05-17
发明人： AGASKAR, Pradyot, Adwaitanand , GRASSELLI, Robert, Karl , MICHAELS, James, Nathaniel , REISCHMAN, Paul, Thomas , STERN, David, Lawrence , TSIKOYIANNIS, John, George
IPC分类号： C07C5
CPC分类号： C07C5/3335 , C07C5/3337 , C07C5/42 , C07C2529/44 , C07C11/02
摘要： There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilibrium dehydrogenation catalyst in a first reactor, and the effluent from the first reactor is then passed into a second reactor containing a reducible metal oxide which serves to selectively combust hydrogen in an oxidation/reduction (REDOX) reaction. This particular mode of operation is termed a separate reactor, REDOX mode.
摘要翻译： 提供了用于烷烃净催化氧化脱氢生产烯烃的方法。 该方法包括将烷烃同时平衡脱氢成烯烃和形成的氢的燃烧，以进一步驱使产物烯烃进行平衡脱氢反应。 在本反应中，烷烃原料在第一反应器中通过平衡脱氢催化剂脱氢，然后来自第一反应器的流出物通入含有可还原金属氧化物的第二反应器中，所述可还原金属氧化物用于选择性氧化氧化/还原 （REDOX）反应。 这种特定的操作模式被称为单独的反应器，即REDOX模式。
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