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公开(公告)号：EP2990113A1
公开(公告)日：2016-03-02
申请号：EP14788232.8
申请日：2014-04-22
申请人： Maruzen Petrochemical Co., Ltd. , NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
IPC分类号： B01J31/26 , B01J37/02 , C07B61/00 , C07D317/36 , C07D317/38
CPC分类号： B01J31/0268 , B01J21/08 , B01J27/08 , B01J27/16 , B01J27/182 , B01J31/0267 , B01J31/0269 , B01J31/069 , B01J31/26 , B01J35/1019 , B01J35/1023 , B01J35/1061 , B01J2231/341 , C07D317/36 , C07D317/38
摘要： Provided are : a method for easily producing a heterogeneous catalyst having excellent catalytic activity at a low cost, said heterogeneous catalyst being used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide and carbon dioxide; a catalyst which is obtained by this production method; and a method for synthesizing a cyclic carbonate with use of this catalyst.
A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b):
(a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group, by subjecting to a reaction a silane compound having a haloalkyl group or a haloaryl group and a silica gel having an amount of adsorbed water of 1% by mass or less and
(b) a step of obtaining a catalyst for cyclic carbonate synthesis, by subjecting to a reaction the catalyst precursor obtained in step (a) and a tertiary phosphine, in which the molar ratio of the halogen content to the phosphorus content, namely [halogen]/[phosphorus] is from 0.8 to 1.6.摘要翻译： 本发明提供一种以低成本容易地制造具有优异催化活性的非均相催化剂的方法，所述非均相催化剂用于通过使环氧化物和二氧化碳进行反应来合成环状碳酸酯的目的; 通过该制造方法得到的催化剂; 以及使用该催化剂合成环状碳酸酯的方法。 一种生产用于通过使环氧化物与二氧化碳反应来合成环状碳酸酯的目的的催化剂的方法，所述方法包括以下步骤（a）和（b）：（a）获得 通过使具有卤代烷基或卤代芳基的硅烷化合物与吸附水量为1质量％以下的硅胶进行反应，从而得到具有卤代烷基或卤代芳基的催化剂前体，和（b）工序 通过使步骤（a）中获得的催化剂前体与叔膦反应，其中卤素含量与磷含量的摩尔比，即[卤素] / [磷] 是从0.8到1.6。
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公开(公告)号：EP2990114A1
公开(公告)日：2016-03-02
申请号：EP14788234.4
申请日：2014-04-22
申请人： National Institute of Advanced Industrial Science and Technology , Maruzen Petrochemical Co., Ltd.
发明人： TAKAHASHI, Toshikazu , YASUDA, Hiroyuki , SAKAKURA, Toshiyasu , YAMAMOTO, Shouji , NANIKI, Takashi , FURUKAWA, Takuro
IPC分类号： B01J31/26 , B01J37/02 , C07D317/36 , C07D317/38 , C07B61/00
CPC分类号： C07D317/38 , B01J21/08 , B01J27/08 , B01J27/182 , B01J31/0231 , B01J31/0267 , B01J31/0268 , B01J31/0269 , B01J31/0271 , B01J31/069 , B01J35/1019 , B01J35/1023 , B01J35/1061 , B01J2231/341 , C07D317/36
摘要： Provided are: a method for easily producing a heterogeneous catalyst having excellent catalytic activity at a low cost, said heterogeneous catalyst being used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide and carbon dioxide; a catalyst which is obtained by this production method; and a method for synthesizing a cyclic carbonate with use of this catalyst.
A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b):
(a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group, by subjecting to a reaction a silane compound having a haloalkyl group or a haloaryl group and a silica gel having an average pore diameter of from 3.5 to 50 nm, and
(b) a step of obtaining a catalyst for cyclic carbonate synthesis, by subjecting to a reaction the catalyst precursor obtained in step (a) and a tertiary phosphine, in which the molar ratio of the halogen content to the phosphorus content, namely [halogen]/[phosphorus] is from 0.8 to 1.6.摘要翻译： 本发明提供一种以低成本容易地制造具有优异催化活性的非均相催化剂的方法，所述非均相催化剂用于通过使环氧化物和二氧化碳进行反应来合成环状碳酸酯的目的; 通过该制造方法得到的催化剂; 以及使用该催化剂合成环状碳酸酯的方法。 一种生产用于通过使环氧化物与二氧化碳反应来合成环状碳酸酯的目的的催化剂的方法，所述方法包括以下步骤（a）和（b）：（a）获得 通过使具有卤代烷基或卤代芳基的硅烷化合物与平均孔径为3.5-50nm的硅胶进行反应，以及（b）将具有卤代烷基或卤代芳基的催化剂前体 通过使步骤（a）中得到的催化剂前体与叔膦反应，得到用于环状碳酸酯合成的催化剂，其中卤素含量与磷含量的摩尔比即[卤素] / [磷]为 从0.8到1.6。
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公开(公告)号：EP2990112A1
公开(公告)日：2016-03-02
申请号：EP14788563.6
申请日：2014-04-22
申请人： Maruzen Petrochemical Co., Ltd. , National Institute of Advanced Industrial Science and Technology
IPC分类号： B01J31/24 , B01J37/22 , C07D317/36 , C07D317/38 , C07B61/00
CPC分类号： C07F9/5414 , B01J21/08 , B01J27/08 , B01J27/182 , B01J31/0268 , B01J31/0269 , B01J31/0274 , B01J31/0275 , B01J31/069 , B01J35/1019 , B01J35/1023 , B01J35/1061 , B01J2231/341 , C07D317/36 , C07D317/38
摘要： The present invention provides a method for easily and inexpensively producing a heterogeneous catalyst used to synthesize a cyclic carbonate by reacting an epoxide with carbon dioxide and having excellent catalyst activity; a catalyst obtained using said manufacturing method; and a method for synthesizing a cyclic carbonate using said catalyst.
A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b):
(a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group by reacting a silane compound with a silica gel in the presence of xylene, the silane compound having a haloalkyl group or a haloaryl group and
(b) a step of obtaining a catalyst for synthesizing a cyclic carbonate by reacting the catalyst precursor obtained in step (a) with a tertiary phosphine.摘要翻译： 本发明提供了用于容易地且廉价地生产用于通过使用二氧化碳和具有优异的催化剂活性的环氧化物来合成的环状碳酸酯的非均相催化剂的方法; 使用所述的制造方法获得的催化剂; 和用于合成使用所述催化剂的环状碳酸酯的方法。 并用于通过使环氧化物与二氧化碳的反应合成的环状碳酸酯，所述方法包括以下步骤（a）和（b）的目的，一种用于制备催化剂的方法：（1）a。获得的步骤 具有卤代烷基或由在二甲苯的存在下反应用硅胶硅烷化合物的卤代芳基催化剂前体，具有卤代烷基或卤代芳基和（b）获得一个催化剂用于合成环状的工序的硅烷化合物 反应通过在与叔膦步骤（a）中获得的催化剂前体酯。
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公开(公告)号：EP2990113B1
公开(公告)日：2020-03-25
申请号：EP14788232.8
申请日：2014-04-22
申请人： Maruzen Petrochemical Co., Ltd. , NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
IPC分类号： B01J31/26 , B01J37/02 , C07B61/00 , C07D317/36 , C07D317/38
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公开(公告)号：EP3023418B1
公开(公告)日：2018-07-11
申请号：EP14827134.9
申请日：2014-07-18
申请人： National Institute of Advanced Industrial Science and Technology , Maruzen Petrochemical Co., Ltd.
发明人： TAKAHASHI, Toshikazu , YASUDA, Hiroyuki , YAMAMOTO, Shouji , NANIKI, Takashi , HAYASHI, Yasunori , HARUNA, Takeshi , FURUKAWA, Takuro
IPC分类号： C07D317/36 , B01J31/02 , C07D317/38
CPC分类号： C07D317/38 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0269 , B01J2231/341 , C07D317/36 , Y02P20/142
摘要： Provided is a method for producing a cyclic carbonate obtained by reacting epoxide and carbon dioxide, the method being capable of efficiently producing a cyclic carbonate at a high conversion rate and a high yield, in which degradation of the catalyst over time is suppressed and catalytic activity hardly decreases. A method for producing a cyclic carbonate by reacting epoxide and carbon dioxide in the presence of a quaternary onium salt selected from the group consisting of a quaternary ammonium salt having a halogenated anion as a counter ion and a quaternary phosphonium salt having a halogenated anion as a counter ion, or in the presence of a solid catalyst obtained by immobilizing the quaternary onium salt onto a carrier, wherein an organohalogen compound containing at least one halogen atom in one molecule is added to the reaction system.
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公开(公告)号：EP3023418A1
公开(公告)日：2016-05-25
申请号：EP14827134.9
申请日：2014-07-18
申请人： National Institute of Advanced Industrial Science and Technology , Maruzen Petrochemical Co., Ltd.
发明人： TAKAHASHI, Toshikazu , YASUDA, Hiroyuki , YAMAMOTO, Shouji , NANIKI, Takashi , HAYASHI, Yasunori , HARUNA, Takeshi , FURUKAWA, Takuro
IPC分类号： C07D317/36 , B01J31/02 , C07D317/38
CPC分类号： C07D317/38 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0269 , B01J2231/341 , C07D317/36 , Y02P20/142
摘要： Provided is a method for producing a cyclic carbonate obtained by reacting epoxide and carbon dioxide, the method being capable of efficiently producing a cyclic carbonate at a high conversion rate and a high yield, in which degradation of the catalyst over time is suppressed and catalytic activity hardly decreases.
A method for producing a cyclic carbonate by reacting epoxide and carbon dioxide in the presence of a quaternary onium salt selected from the group consisting of a quaternary ammonium salt having a halogenated anion as a counter ion and a quaternary phosphonium salt having a halogenated anion as a counter ion, or in the presence of a solid catalyst obtained by immobilizing the quaternary onium salt onto a carrier, wherein an organohalogen compound containing at least one halogen atom in one molecule is added to the reaction system.摘要翻译： 提供一种通过使环氧化物和二氧化碳反应得到的环状碳酸酯的制造方法，其能够以高转化率和高收率有效地制造环状碳酸酯，其中催化剂随时间的降低被抑制，催化活性 几乎没有减少。 一种环氧化物和二氧化碳在季铵盐的存在下，通过使季铵盐选自具有卤化阴离子作为抗衡离子的季铵盐和具有卤代阴离子的季鏻盐作为 或在通过将季铵盐固定在载体上得到的固体催化剂的存在下，其中在一个分子中含有至少一个卤素原子的有机卤素化合物加入到反应体系中。
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公开(公告)号：EP2990112B1
公开(公告)日：2020-03-25
申请号：EP14788563.6
申请日：2014-04-22
申请人： Maruzen Petrochemical Co., Ltd. , National Institute of Advanced Industrial Science and Technology
IPC分类号： B01J31/26 , B01J37/02 , C07B61/00 , C07D317/36 , C07D317/38
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公开(公告)号：EP3023419B1
公开(公告)日：2018-01-31
申请号：EP14825786.8
申请日：2014-07-18
申请人： Maruzen Petrochemical Co., Ltd. , National Institute of Advanced Industrial Science and Technology
发明人： NANIKI, Takashi , HAYASHI, Yasunori , SAWADA, Goro , FURUKAWA, Takuro , HARUNA, Takeshi , TAKAHASHI, Toshikazu , YASUDA, Hiroyuki , YAMAMOTO, Shouji
IPC分类号： C07D317/38 , B01J31/02 , B01J27/08
CPC分类号： C07D317/38 , B01J27/08 , B01J31/0231 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0269 , B01J31/0271 , B01J2231/341 , B01J2531/90
摘要： Provided is a method for continuously producing a cyclic carbonate, by which generation of a glycol in a reaction for synthesizing a cyclic carbonate is suppressed, and a cyclic carbonate having a high purity can be efficiently obtained even by simple purification. A method for continuously producing a cyclic carbonate, including filling a catalyst in a fixed-bed tube reactor, and continuously feeding carbon dioxide and an epoxide to the fixed-bed tube reactor to thereby bringing the carbon dioxide and the epoxide into contact with the catalyst, while continuously withdrawing the reaction liquid in the fixed-bed tube reactor, wherein the method includes a pre-treatment step in which a pre-treatment liquid containing a cyclic carbonate is brought into contact with the catalyst before feeding the carbon dioxide and the epoxide to the fixed-bed tube reactor, and the generated glycol is removed out of the system.
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公开(公告)号：EP3023419A1
公开(公告)日：2016-05-25
申请号：EP14825786.8
申请日：2014-07-18
申请人： Maruzen Petrochemical Co., Ltd. , National Institute of Advanced Industrial Science and Technology
发明人： NANIKI, Takashi , HAYASHI, Yasunori , SAWADA, Goro , FURUKAWA, Takuro , HARUNA, Takeshi , TAKAHASHI, Toshikazu , YASUDA, Hiroyuki , YAMAMOTO, Shouji
IPC分类号： C07D317/38 , B01J31/02
CPC分类号： C07D317/38 , B01J27/08 , B01J31/0231 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0269 , B01J31/0271 , B01J2231/341 , B01J2531/90
摘要： Provided is a method for continuously producing a cyclic carbonate, by which generation of a glycol in a reaction for synthesizing a cyclic carbonate is suppressed, and a cyclic carbonate having a high purity can be efficiently obtained even by simple purification.
A method for continuously producing a cyclic carbonate, including filling a catalyst in a fixed-bed tube reactor, and continuously feeding carbon dioxide and an epoxide to the fixed-bed tube reactor to thereby bringing the carbon dioxide and the epoxide into contact with the catalyst, while continuously withdrawing the reaction liquid in the fixed-bed tube reactor, wherein the method includes a pre-treatment step in which a pre-treatment liquid containing a cyclic carbonate is brought into contact with the catalyst before feeding the carbon dioxide and the epoxide to the fixed-bed tube reactor, and the generated glycol is removed out of the system.-
公开(公告)号：EP2248819A1
公开(公告)日：2010-11-10
申请号：EP09717502.0
申请日：2009-03-05
发明人： ONOZAWA, Shun-ya , FUKAYA, Norihisa , SAITOU, Kaori , SAKAKURA, Toshiyasu , YASUDA, Hiroyuki , TAKAGI, Yukio , UEDA, Masae
CPC分类号： C07F17/02 , B01J31/1633 , B01J31/1815 , B01J31/189 , B01J31/2404 , B01J31/2409 , C01B33/00 , C01P2006/12 , C01P2006/16 , C07F7/0818 , C07F7/1844 , C07F9/5009 , C07F9/5022 , C07F9/5027 , C07F9/5726 , Y02P20/588 , Y10T428/31663
摘要： The invention has an object to obtain an organic inorganic composite material having high activity and high selectivity, and suitable as a catalyst material having small elution of an active metal from a carrier, and further to obtain an organosilicon compound suitable for the preparation of the composite material. The composite material is an organic inorganic composite material comprising an organosilicon compound having at least two groups containing reactive silicon at a molecular end, bonded to one silicon atom constituting the organosilicon compound, and an inorganic oxide material, the organosilicon compound and the inorganic oxide material being bonded to each other through a plurality of groups containing reactive silicon of the organosilicon compound. The organosilicon compound is represented by the following general formula (1) or (2). Formula (1) wherein symbols are the same as defined in claim 17. Formula (2) wherein symbols are the same as defined in claim 18.
摘要翻译： 本发明的目的是获得具有高活性和高选择性的有机无机复合材料，并且适合作为从载体中洗脱活性金属的催化剂材料，并且还可获得适于制备复合材料的有机硅化合物 材料。 该复合材料是含有具有至少两个在分子末端含有反应性硅的基团的有机硅化合物的有机无机复合材料，与构成有机硅化合物的一个硅原子键合，无机氧化物材料，有机硅化合物和无机氧化物材料 通过含有机硅化合物的反应性硅的多个基团彼此键合。 有机硅化合物由以下通式（1）或（2）表示。 式（1）其中符号与权利要求17中定义相同。式（2）其中符号与权利要求18中定义的相同。
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